Corrosion Behavior of Ni3(Si,Ti) + 2Mo in Hydrochloric Acid Solution

Gadang Priyotomo, Pius Sebleku


DOI: https://doi.org/10.12777/ijse.6.1.39-42

Abstract


The corrosion behavior of Ni3(Si,Ti) + 2Mo intermetallic compound (L12 and (L12 + Niss) mixture region) has been investigated using an immersion test, polarization method and surface analytical method (scanning electron microscope and energy-dispersive X-Ray spectrometry) in 0.5 kmol/m3 hydrochloric acid (HCl) solution at 303 K.  In addition, the results obtained were compared to those of the L12 single-phase Ni3(Si,Ti) intermetallic compound and C 276 alloy.  It was found that Ni3(Si,Ti) + 2Mo had the preferential dissolution of L12 with a lower Mo concentration compared to (L12 + Niss) mixture region.  From the immersion test and polarization curves, Ni3(Si,Ti) + 2Mo and C276 showed the lowest corrosion resistance and the highest corrosion resistance in the solution, respectively.  From this work, It implied that unlike C276, Ni3(Si,Ti) +2Mo intermetallic compound was difficult to form a stable passive film in HCl solution as well as Ni3(Si,Ti) in the same solution.


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References


Kaneno,Y., Myoki, T., and Takasugi, T.(2008). Tensile Properties of L12 Intermetallic Foils Fabricated by Cold Rolling. INTERNATIONAL JOURNAL MATERIALS RESEARCH, 99 : 1229–1236.(3)

Kaneno, Y., and Takasugi, T. (2007). The Effect of Nb and Cr Addition on Mechanical and Chemical Properties of Cold-Rolled Ni3(Si,Ti) Intermetallic Foils. MATERIALS SCIENCE FORUM, 561–565(1) : 411–414.(4)

Kaneno, Y., Fujimoto, Y., Yoshida, M. and Takasugi, T. (2011). Alloying Effect on Microstructure and Mechanical Properties of Thermomechanically Processed. INTERNATIONAL JOURNAL OF MATERIALS RESEARCH, 102 : 5.(5)

Priyotomo.G, Okitsu, K., Iwase, A., Kaneno, Y., Nishimura, R. and Takasugi, T. (2011). The Corrosion Behavior of Intermetallic Compounds Ni3(Si,Ti) and Ni3(Si,Ti) + 2Mo in Acidic Solutions. Applied Surface Science, 257 : 8268-8274.(9)

Priyotomo.G and Kaneno, Y. (2013). Corrosion Behavior of Ni3(Si,Ti) in Hydrochloric Acid Solutions. INTERNATIONAL JOURNAL OF SCIENCE AND ENGINEERING, 5(1) : 31-34.(10)

Priyotomo, G., Wagle, S., Okitsu, K., Iwase, A., Kaneno, Y., Nishimura, R. and Takasugi, T. (2012). The Corrosion Behavior of Ni3(Si,Ti) Intermetallic Compounds with Al, Cr, and Mo in Various Acidic Solutions. CORROSION SCIENCE, 60 : 10-17.(11)

Takasugi, T., Nagashima, M., and Izumi, O.(1990). Strengthening and Ductilization of Ni3Si by the Addition of Ti. ACTA METALLURGICA ET MATERIALIA, 38 :747-755.(1)

Takasugi, T and Yoshida, M. (1991). Mechanical Properties of Ni3(Si,Ti) Polycrystals Alloyed with Substitutional additions. JOURNAL OF MATERIALS SCIENCE, 26 : 3517-3525.(2)

Takasugi, T., Nakayama, T. and Hanada, S. (1993a). Enviromental Embrittlement of Ni3(Si,Ti) Single Crystals. MATERIALS TRANSACTIONS JIM, 34 : 775–785.(6)

Takasugi, T., Hono, K., Suzuki, S., Hanada, S. and Sakurai, T. (1993b). Enviromental Embrittlement and Grain Boundary Segregation of Boron in Ni3(Si,Ti) and Co3Ti Alloys. SCRIPTA METALLURGICA ET MATERIALA, 29 : 1587–1591.(7)

Takasugi, T., Ma, C.L, and Hanada, S. (1995). Environmental Embrittlement and Grain Boundary Segregation of Boron and Carbon in Ni3(Si,Ti) Alloys. MATERIALS SCIENCE AND ENGINEERING, A 192/193 : 407–412.(8)




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