Adsorption Desorption of Chromium (III) Ion on Cellulose from Wood Powder

Risfidian Mohadi, Nurlisa Hidayati, Aldes Lesbani


DOI: https://doi.org/10.12777/ijse.7.1.77-80

Abstract


This study of adsorption desorption of chromium ion on cellulose from wood powder has been carried out systematically and also wood powder was used as adsorbent control in this research. Adsorption process was studied through investigation of adsorption time and variation of chromium ion in the adsorption. Desorption process was investigated using several desorption reagents such as hydrochloric acid, ammonium acetate, sodium EDTA, and water. Data of adsorption time of chromium ion on cellulose and wood powder was calculated to obtain adsorption rate constant of chromium ion. Then the data of variation concentration of chromium was formulated to obtain adsorption capacity of chromium ion on cellulose and wood powder. The results showed that adsorption rate constant of chromium on cellulose is 0.007 min-1 and 0.002 min-1 for wood powder. Adsorption capacity of chromium ion on cellulose is higher than on wood powder while 76.92 mol/g for cellulose and 55.56 mol/g for wood powder. The results of desorption using various desorption shows sodium EDTA is appropriate reagent for desorption of chromium ion on both cellulose and wood powder.

Keywords - adsorption, cellulose, chromium, desorption.


Keywords


adsorption, cellulose, chromium, desorption.

Full Text:

FULL TEXT PDF

References


Shriver. A, Inorganic Chemistry, 4th ed, Chichester,U.K, Oxford University Press, 2006, ch.18, pp.434.

Cox.P.A., Inorganic Chemistry, 2nd ed, London, Bios Scientific Publishers, 2004, section H, pp. 215-220.

Nachtigall. P, Delgado. M.R, Nachtigallova. D, and Arean. C.O, The nature of cationic Adsorption Sites in Alkaline Zeolites-Single, Dual and Multiple Cation Sites, Physical Chemistry Chemical Physics, vol. 14, pp. 1552-1569, 2012.

Gupta. S.S, and Bhattacharyya. K.G, Adsorption of Heavy Metals on Kaolinite and Montmorillonite: A Review, Physical Chemistry Chemical Physics, vol. 14, pp. 6698-6723, 2012.

Walcarius. A, and Mercier. L, Mesoporous Organosilica Adsorbents: Nanoengineered Materials For Removal of Organic and Inorganic Pollutants, Journal Material Chemistry, vol. 20, pp. 4478-4511, 2010.

Lesbani. A, Narsito, and Santosa. S.J, Adsorption Desorption of Zinc(II) on Chitin and Chitosan, Majalah Sriwijaya, vol. 35, pp. 1-6, 2002.

Lesbani. A, and Yusuf. S, Interaction of Copper(II) and Cadmium(II) on Peat From Indralaya South Sumatera, Jurnal Ilmiah MIPA, vol. 6, pp. 49-52, 2003.

Risfidian M. Nurlisa H., Ivan W., “Adsorption Study of Cu(II), Cd(II), and Cr(VI) on Humin From Peat Soil.” In Proceeding of the International Seminar on Chemistry 2008, Jatinangor, 2008, pp 117.

Chen. X.H, Gosset. T, and Thévenot. D.R, Batch Copper Ion Binding and Exchange Properties of Peat, Water Research, vol.24, pp. 1463-1471, 1990.

Low. K.S, Lee. C.K, and Mak. S.M, Sorption of Copper and Lead by Citric Acid Modified Wood, Wood Science Technology, vol. 38, pp. 629-640, 2004.

O’Connell. D.W, Birkinshaw. C, and O’Dwyer. T.F, Heavy Metal Adsorbents Prepared From The Modification of Cellulose: A Review, Bioresource Technology, vol. 99, pp. 6709-6724, 2008.

Mark. J.E, Physical Properties of Polymers Handbook, 2nd ed, USA, Springer, ch. 7, pp. 611-618, 2007.

Stuart. B.H, Infrared Spectroscopy: Fundamentals and Applications, Chichester, John Wiley & Sons, Ltd, ch. 8, pp. 167-183, 2004.

Santosa. S.J, Narsito. andLesbani. A, The Determination of Active site, Capacity, Energy and Rate Constant on the Adsorption of Zn(II) and Cd(II) on Chitin, Journal of Ion Exchange, vol. 14, pp. 89-92, 2003.

Masel. R.I, Principles of Adsorption and Reaction on Solid Surfaces, John Wiley & Sons, Inc, USA, 1996, pp. 240-244.

O’Connell. D.W, Birkinshaw. C, and O’Dwyer. T.F, A Chelating Cellulose Adsorbent For the Removal of Cu(II) From Aqueous Solutions, Journal Applied. Polymer Science, vol. 99, pp. 2888-2897, 2006.

Lesbani. A, The Role of Cationic Exchange and Complex Formation on Adsorption Using Portunus pelagicus Linn as Adsorbent, Gadjah Mada University, Master thesis, ch. 4, 2001.




Published by Department of Chemical Engineering University of Diponegoro Semarang
Google Scholar

IJSE  by http://ejournal.undip.ac.id/index.php/ijse is licensed under Creative Commons Attribution 3.0 License.