Analysis of Sodium, Potassium and Calcium using a Portable Liquid Electrode Plasma Optical Emission Spectrometer

Eko Hidayanto, Takashi Yamamoto, Jun Kawai


Elements of sodium (Na), potassium (K) and calcium (Ca) in beverage samples and river water were analyzed with portable liquid electrode plasma - optical emission spectrometer (LEP-OES). The degree of reproducibility for emission intensities and individual variety of a disposal sample chip were investigated, and measuring conditions for quantitative analysis and the precision was discussed. The sensitivity for Na was higher than those for K and Ca by one or two orders of magnitude. Several ppm of Na and K, and several hundred of Ca in aqueous samples could be quantitatively analyzed with 2-30% of deviation without internal standard. The applied voltage was predominant factor for accurate quantitative analysis, and 800 V was found to be the best voltage estimation for quantitative analysis of alkaline metals contents.

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