DOI: https://doi.org/10.14710/teknik.v42i3.36031

Sintesis Karbon Aktif Limbah Lumpur Aktif Industri Gula sebagai Adsorben Limbah Logam Berat Cu(II)

*Adhi Setiawan scopus  -  Politeknik Perkapalan Negeri Surabaya, Indonesia
Muhammad Iqbal Ali Bawafi  -  Program Studi Teknik Pengolahan Limbah, Politeknik Perkapalan Negeri Surabaya (PPNS), Indonesia
Tarikh Azis Ramadani  -  Program Studi Teknik Pengolahan Limbah, Politeknik Perkapalan Negeri Surabaya (PPNS), Indonesia
Indri Santiasih  -  Program Studi Magister Terapan Teknik Keselamatan dan Resiko, Politeknik Perkapalan Negeri Surabaya (PPNS), Indonesia
Open Access Copyright (c) 2021 TEKNIK

Citation Format:
Abstract

Penelitian ini bertujuan melakukan sintesis karbon aktif dari limbah lumpur aktif unit Sludge Drying Bed (SDB) industri gula sebagai adsorben dan efektifitasnya dalam menurunkan kandungan logam berat Cu(II). Proses karbonasi lumpur aktif dilakukan pada suhu 600oC dilanjutkan dengan aktifasi menggunakan asam sulfat 20%. Hasil penelitian menunjukkan bahwa karbon aktif memiliki kadar air, kadar zat yang menguap, dan daya serap I2 telah memenuhi SNI. Hasil SEM menunjukkan bahwa morfologi partikel berbentuk granular dengan ukuran rata-rata partikel sebesar 134,3 μm. Luas permukaan spesifik partikel karbon aktif sebesar 1013,63 m2/g. Pengujian karbon aktif untuk adsorpsi logam Cu(II) menunjukkan bahwa peningkatan waktu kontak adsorpsi akan meningkatkan efisiensi penyisihan Cu(II). Peningkatan konsentrasi awal Cu(II) menyebabkan kecenderungan penurunan efisiensi penyisihan Cu(II). Efisiensi penyisihan maksimum Cu(II) diperoleh pada kondisi waktu kontak 40 menit dan konsentrasi awal Cu(II) 12,5 mg/L dengan nilai sebesar 86,32%. Isoterm Adsorpsi karbon aktif mengikuti persamaan Freunlich. Kinetika adsorpsi karbon aktif pada konsentrasi awal Cu(II) sebesar 6,125 dan 12,5 mg/L mengikuti pseudo orde dua sedangkan pada konsentrasi awal Cu(II) sebesar 25 dan 50 mg/L mengikuti pseudo orde satu.

Fulltext View|Download
Keywords: adsorpsi; isoterm adsorpsi; karbon aktif limbah lumpur; kinetika adsorpsi

Article Metrics:

Article Info
Section: Artikel
Language : ID
Recent articles
Review: Aplikasi Material Komposit Berbasis Kitosan sebagai Bahan Kemasan Makanan Optimasi Operasi Danau Rawa Pening dengan Program Dinamik untuk Pemanfaatan Sumber Daya Air yang Optimal Deteksi Kavitasi Pompa Sentrifugal Menggunakan Metode Decision Trees Berbasis Sinyal Getaran Front Matter Back Matter More recent articles
Most cited articles
PENGENALAN TEKNOLOGI RADAR UNTUK PEMETAAN SPASIAL DI KAWASAN TROPIS KELEMBAGAAN IMPLEMENTASI PROGRAM KREDIT MIKRO PERUMAHAN DI KOTA SEMARANG KAJIAN STABILITAS TUMPUKAN BATU DALAM AIR PERSEPSI INTEGRASI TATA GUNA LAHAN PADA KAWASAN WATERFRONT DEVELOPMENT (Studi Kasus: Kanal Banjir Barat Semarang) KONSEP WATERFRONT PADA PERMUKIMAN ETNIS KALI SEMARANG More cited articles
  1. Al Qodah, Z., & Shawabkah, R. (2009). Production and Characterization of Granular Activated Carbon from Activated Sludge. Brazillian Journal of Chemical Engineering, 26(1), 1–10
  2. Azizian, S. (2004). Kinetic Models of Sorption: A Theoretical Analysis. Journal of Colloid and Interface Science, 276(1), 47–52
  3. Calisto, V., Ferreira, C.I.A., Santos, S.M., Gil, M.V., Otero, M., & Esteves, V.I. (2014). Production of Adsorbents by Pyrolysis of Paper Mill Sludge and Application on the Removal of Citalopram from Water. Bioresource Technology, 166, 335–344
  4. Gong, K., Li, X., Liu, H., Cheng, X, Sun, D, Shao, Q., Dong, M., Liu, C., Wu, S., Ding, T., Qiu, B., & Guo, Z. (2019). Residue Metals and Instrinsic Moisture In Excess Sludge Influenced Pore Formation in the Excess Sludge Derived Activated Carbon. Carbon, 156, 320–328
  5. Gong, M., Zhu, W., Xu, Z.R, Zhang, H.W., & Yang, H.P. (2014). Influence of Sludge Properties on The Direct Gasification of Dewatered Sewage Sludge in Supercritical Water. Renewable Energy, 66, 605–611
  6. Guan, Q.,, Gao, K., Ning, P., Mia, R., & He, L. (2020). Value-Added Utilization of Paper Sludge: Preparing Activated Carbon for Efficient Adsorption of Cr(VI) and Further Hydrogenation of Furfural. Science of the Total Environment, 741, 140265
  7. Hadi, P., Xu, M., Ning, C., Sze Ki Lin, C., & McKay, G. (2015). A Critical Review on Preparation, Characterization and Utilization of Sludge-Derived Activated Carbons for Wastewater Treatment. Chemical Engineering Journal, 260, 895–906
  8. Ho, Y.S. & Mckay, G. (1998). Kinetic Models for the Sorption of Dye From Aqueous Solution by Wood. Transactions of the Institution of Chemical Engineers, 76, 183–191
  9. Kumar, A., & Jena, H.M. (2015). High Surface Area Microporous Activated Carbons Prepared From Fox Nut (Euryale Ferox) Shell by Zinc Chloride Activation. Applied Surface Science, 356, 753-761
  10. Li, Y.H., Chang, F.M., Huang, B., Song, Y.P., Zhao, H.Y., & Wang, K.J. (2020). Activated Carbon Preparation from Pyrolysis Char of Sewage Sludge and Its Adsorption Performance for Organic Compounds in Sewage. Fuel, 266, 1–11
  11. Manara, P., & Zabaniotou, A. (2012). Towards Sewage Sludge Based Biofuels via Thermochemical Conversion–A Review. Renewable and Sustainable Energy Reviews, 16(5), 2566–2582
  12. Martini, S., Afroze, S., & Roni, K.A. (2020). Modified Eucalyptus Bark as a Sorbent for Simultaneous Removal of COD, Oil, and Cr(III) From Industrial Wastewater. Alexandria Engineering Journal, 59(3), 1637–1648
  13. Méndez, A., Gascó, G., Freitas, M.M.A., Siebielec, G., Stuczynski, T., & Figueiredo, J.L. (2005) Preparation of carbon-based adsorbents from pyrolysis and air activation of sewage sludges, Chemical Engineering Journal, 108, 169–177
  14. Monsalvo, V.M., Mohedano, A.F., & Rodriguez, J.J. (2012). Adsorption of 4-Chlorophenol by Inexpensive Sewage Sludge-Based Adsorbents. Chemical Engineering Research and Design, 90(11), 1807–1814
  15. Noer, A.A., Awitdrus, A., & Usman, M. (2014). Pembuatan Karbon Aktif dari Pelepah Kelapa Sawit Menggunakan Aktivator H2O Sebagai Adsorben. Jurnal Online mahasiswa (JOM), 1(2), 42–47
  16. Ren, S. (2004). Assessing Wastewater Toxicity to Activated Sludge: Recent Research and Developments. Environment International, 30(8), 1151–1164
  17. Rio, S., Coq, L.Le., Faur, C., Lecomte, D., & Cloirec, P.Le. (2006). Preparation of Adsorbents from Sewage Sludge by Steam Activation for Industrial Emission Treatment. Process Safety and Environmental Protection, 84(4), 258-264
  18. Ros, A, Lillo-Rodenas, M.A, Fuente, E., Montes-Morán, M.A., Martín, M.J., & Linares-Solano, A. (2006). High Surface Area Materials Prepared from Sewage Sludge-Based Precursors. Chemosphere, 65(1), 132–140
  19. Salas-Enríquez, B.G., Torres-Huerta, A.M., Dominguez-Crespo, M.A., Diaz-Garcia, L., & Negrete-Rodigues, M.L.X. (2016). Activated Carbon Production from the Guadua Amplexifolia Using a Combination of Physical and Chemical Activation. Journal of Thermal Analysis & Calorimetry, 124, 1383–1398
  20. Sani, S. (2011). Pembuatan Karbon Aktif Dari Tanah Gambut. Jurnal Teknik Kimia, 5(2), 400–406
  21. Sen, T. K., Afroze, S., & Ang, H.M. (2011). Equilibrium, Kinetics And Mechanism of Removal of Methylene Blue From Aqueous Solution by Adsorption Onto Pine Cone Biomass of Pinus Radiata. Water, Air, & Soil Pollution, 218, 499–515
  22. Shanin, S.A., Mossad, M., & Fouad, M. (2019). Evaluation of Copper Removal Efficiency Using Water Treatment Sludge. Water Science and Engineering, 12(1), 37–44
  23. Soleimani, M., & Kaghazchi, T. (2008). Adsorption of Gold Ions from Industrial Wastewater Using Activated Carbon Derived from Hard Shell of Apricot Stones–An Agricultural Waste. Bioresource Technology, 99, 5374–5383
  24. Song, Q., Zhao, H.Y., Jia, J.W., Zhang, F., Wang, Z.P., Lv, W., Yang, Li., Zhang, W., Zhang, Yi., & Shu, X. (2019). Characterization of the Products Obtained by PyRolysis of Oil Sludge with Steel Slag in a Continuous Pyrolysis-Magnetic Separation Reactor. Fuel, 255, 1–12
  25. Tahad, A. & Sanjaya, A.A. (2017). Isoterm Freundlich, Model Kinetika dan Penentuan Laju Reaksi Adsorpsi Besi dengan Arang Aktif dari Ampas Kopi. Jurnal Chemurgy, 1(2), 13–21
  26. Venugopal V., & Mohanty, K. 2011. Biosorptive uptake of Cr (VI) from aqueous solutions by Parthenium Hysterophorus Weed : Equilibrium, Kinetics, and Thermodynamic Studies. Chemical Engineering Journal, 174(1), 151-158
  27. Werther, J., & Ogada, T. (1999). Sewage Sludge Combustion. Progress in Energy Combustion Science, 25(1), 55–116
  28. Wu, C., Li, L., Zhou, H., Ai, J., Zhang, H., Tau, J., Wang, D., Zhang, W. (2021). Effects of Chemical Modification on Physicochemical Properties and Adsorption Behavior of Sludge-Based Activated Carbon. Journal of Environmental Sciences, 100, 340–351
  29. Yang, X., Liu, L., Tan, W., Qiu, G., & Liu, F. (2018). High-Performance Cu2+ Adsorption of Birnessite Using Electrochemically Controlled Redox Reactions. Journal of Hazardous Materials, 345, 107–115
  30. Yi, Z., Yao, J., Zhu, M., Chen, H., Wang, F., & Liu, X. (2016). Kinetics, Equilibrium, and Thermodynamics Investigation on the Adsorption of Lead(II) by Coal‑Based Activated Carbon, Springerplus, 5, 1–12
  31. Zare, H., Heydarzade, H., Rahimnejad, M., Tardast, A., Seyfi, M., & Peyghambarzadeh, S.M. (2015). Dried Activated Sludge As an Appropriate Biosorbent for Removal of Copper (II) Ions. Arabian Journal of Chemistry, 8, 858–864

Last update:

No citation recorded.

Last update: 2025-04-03 10:10:41

No citation recorded.