Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide

*Rodiansono Rodiansono  -  Department of Chemistry, Lambung Mangkurat University, Jl. A. Yani Km 36.0 Banjarbaru South Kalimantan,, Indonesia
Shimazu Shogo  -  Graduate School of Engineering, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522,, Japan
Received: 21 Dec 2012; Published: 19 Jun 2013.
Open Access
Citation Format:
Rodiansono 4290
Abstract
Effective production of hexitols (sorbitol and mannitol) was achieved from sugars by means of nickel nanoparticles supported on aluminium hydroxide (NiNPs/AlOH) catalyst. NiNPs/AlOH catalyst was prepared by a simple and benign environmentally procedure using less amount of sodium hydroxide. ICP-AES and XRD analyses confirmed that the NiNPs/AlOH catalysts comprised a large amount of remained aluminium hydroxide (i.e. bayerite and gibbsite). The presence of aluminium hydroxide caused a high dispersion Ni metal species. The average Ni crystallite sizes that derived from the Scherrer`s equation for former R-Ni and NiNPs/AlOH were 8.6 nm and 4.1 nm, respectively. The catalyst exhibited high activity and selectivity both hydrogenolysis of disaccharides (sucrose and cellobiose) and monosaccharides (glucose, fructose, and xylose) at 403 K for 24 h. The NiNPs/AlOH catalyst was found to be reusable for at least five consecutive runs without any significant loss of activity and selectivity. © 2013 BCREC UNDIP. All rights reserved

Received: 21st December 2012; Revised: 7th February 2013; Accepted: 10th February 2013

[How to Cite: Rodiansono, R., Shimazu, S. (2013). Effective Production of Sorbitol and Mannitol from Sug-ars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide. Bulletin of Chemical Reaction Engineering & Catalysis, 8 (1): 40-46. (doi:10.9767/bcrec.8.1.4290.40-46)]

[Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.1.4290.40-46]

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Keywords: supported-nickel nanoparticles; hydrogenation; sugar; sorbitol; mannitol

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  1. Istadi, I, Anggoro, D.D., Amin, N.A.S., Ling, D.H.W. (2011). Catalyst Deactivation Simulation Through Carbon Deposition in Carbon Dioxide Reforming over Ni/CaO-Al2O3 Catalyst, Bull. Chem. React. Eng. Catal. 6(2): 129-136

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