Studies on Sono-Chemical Biodiesel Production Using Smoke Deposited Nano MgO Catalyst

P. Sivakumar  -  Department of Chemical Engineering, Anna University, Chennai-600 025, Tamilnadu,, India
S. Sankaranarayanan  -  Department of Chemical Engineering, Anna University, Chennai-600 025, Tamilnadu,, India
S. Renganathan  -  Department of Chemical Engineering, Anna University, Chennai-600 025, Tamilnadu,, India
*P. Sivakumar  -  Department of Petroleum Engineering and Technology, JCT College of Engineering and Technology, Coimbatore-641 105, Tamilnadu,, India
Received: 18 Mar 2013; Published: 1 Dec 2013.
Open Access
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Abstract
The comprehensive study of smoke deposited nano sized MgO as a catalyst for biodiesel production was investigated. The transesterification reaction was studied under constant ultrasonic mixing for different parameters like catalyst quantity, methanol oil molar ratio, reaction temperature and reaction time. An excellent result of conversion was obtained at 1.5 wt% catalyst; 5:1 methanol oil molar ratio at 55°C, a conversion of 98.7% was achieved after 45 min. The conversion was three to five times higher than those are reported for laboratory MgO in literature. This was mainly due to the enhancement of surface area of the catalyst and the activity of ultrasonic waves. Catalyst is easily recovered and reused up to eight times with easy regeneration steps.  © 2013 BCREC UNDIP. All rights reserved

Received: 18th March 2013; Revised: 20th August 2013; Accepted: 9th September 2013

[How to Cite: Sivakumar, P., Sankaranarayanan, S., Renganathan, S., Sivakumar, P. (2013). Studies on Sono-Chemical Biodiesel Production Using Smoke Deposited Nano MgO Catalyst. Bulletin of Chemical Re-action Engineering & Catalysis, 8 (2): 89-96.(doi:10.9767/bcrec.8.2.4628.89-96)]

[Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.2.4628.89-96]

Keywords: Nano MgO; Transesterification; Sonication; Recovery; Regeneration

Article Metrics:

  1. Sharma, Y.C., Singh, B., Upadhyay, S.N. (2008). Advancements in development and characterization of biodiesel: a review. Fuel, 87: 2355-2373
  2. Meher, L.C., Vidya, S.D., Naik, S.N. (2006). Tech-nical aspects of biodiesel production by trans-esterification: a review. Renew. Sust. Energy Rev., 10: 248-268
  3. Noureddini, H., Zhu, D. (1997). Kinetics of trans-esterification of soybean oil. J. Am. Oil Chem. Soc., 74: 1457-1463
  4. Freedman, B., Butterileld, R.O., Pryde, E.H., (1986). Transesterification kinetics of soybean oil. J. Am. Oil Chem. Soc., 63: 1375-1380
  5. Singh, A.K., Fernando, S.D. (2008). Transesterifi-cation of soybean oil using heterogeneous cata-lysts. Energy Fuel, 22: 2067-2069
  6. Liu, X., He, H., Wang, Y., Zhu, S. (2007). Trans-esterification of soybean oil to biodiesel using SrO as a solid base catalyst. Catal. Commun., 8: 1107-1111
  7. Dossin, T.F., Reyniers, M.F., Marin, G.B. (2006). Kinetics of heterogeneously MgO catalyzed trans-esterification. Appl. Catal. B: Enviro., 61: 35-45
  8. Kiss, A.A., Omota. F., Dimian, A.C., Rothenberg, G. (2006). The heterogeneous advantage: biodiesel by catalytic reactive distillation. Topics in Catal., 40: 141-150
  9. Watkins, R.S., Lee, A.F., Wilson, K. (2004). Li-CaO catalyzed triglyceride transesterification for biodiesel applications, Green Chem., 6: 335-340
  10. Kim, H., Kang, B., Kim, M.J., Park, Y.M., Kim, D., Lee, J., Lee, K. (2004). Transesterification of vegetable oil to biodiesel using heterogeneous base catalyst. Catal. Today, 93-95: 315-320
  11. Leclercq, E., Finniels, A., Moreau, C. (2001). Transesterification of rapeseed oil in the presenceof basic zeolites and related solid catalysts. J. Am. Oil Chem. Soc., 78: 1161-1167
  12. Arzamendi, G., Arguiñarena, E., Campo, I., Za-bala, S., Gandia, L.M. (2008). Alkaline and alka-line-earth Metals compounds as catalysts for the methanolysis of sunflower oil. Catal. Today, 133-135: 305-313
  13. Ohring, J. ed. (1992). The Material Science of Thin Films. San Diego, Academic-Press
  14. Dorado, M.P., Ballesteros, E., Lopez, F.J., Mittel-bach, M. (2004). Optimization of alkali-catalyzed transesterification of Brassica carinata oil for bio-diesel production. Energy Fuel, 18: 77-83
  15. Hartman, L., Lago, R.O. (1973). Rapid prepara-tion of fatty methyl esters from lipids. Lab. Pract., 22: 475-6
  16. Srivastava, A., Prasad, R. (2000). Triglycerides-based diesel fuels. Renew. Sust. Energy Rev. 4: 111-133
  17. Fangruil, M.A., Hanna, M.A. (1999). Biodiesel production: a review. 70: 1-15
  18. Rodriguez, J.A., Maiti, A. (2000). Adsorption and decomposition of H2S on MgO(100), NiMgO(100), and ZnO(0001) surfaces: a first-principles density functional study. J. Phys. Chem. B. 104: 3630-3638
  19. Rodriguez, J.A., Jirsak, T., Chaturvedi, S. (1999). Reaction of H2S with MgO(100) and Cu/MgO (100) surfaces: Band-gap size and chemical reactivity. J. Chem. Phys. 111: 8077-8087
  20. Rodriguez, J.A., Jirsak, T., Kim, J.Y., Larese, J.Z., Maiti, A. Interaction of NO and NO2 with MgO (100): photoemission and density-functional stud-ies. Chem. Phys. Lett. 330: 475-483
  21. Soave, R., Pacchioni, G. (2000). New bonding mode of CO on stepped MgO surfaces from den-sity functional cluster model calculations. Chem. Phys. Lett., 320: 345-351
  22. Knothe, G., Kenar, J.A. (2004). Determination of fatty acid profile by H1NMR spectroscopy. Eur. J. Lipid Sci. Tech., 106: 88-96
  23. Gelbard, G., Bres, O., Vargas, R.M., Vielfaure, F., Schuchardt, U.F. (1995). H1 Nuclear Magnetic Resonance determination of the yield of the trans-esterification of rapeseed oil with methanol. J. Am. Oil Chem. Soc. 72: 1239-1241
  24. Cullity, B.D. (1978). Elements of X-ray diffraction. Philippines Addison, Wesely Publishing Company Inc
  25. Rao, K.V., Sunandana, C.S. (2008). Structure and microstructure of combustion synthesized MgO nanoparticles and nanocrystalline MgO thin films synthesized by solution growth route. J. Mater. Sci. 43: 146-154
  26. Naoyuki, T. (2007). Simple and rapid synthesis of MgO with nano-cube shape by means of a domes-tic microwave oven. Solid State Sci., 9: 722-724
  27. Aramendia, M.A., Borau, V., Jimenez, C., Mari-nas, J.M., Ruiz, J.R., Urbando, F.J. (2003). Influ-ence of the preparation method on the structural and surface properties of various magnesium ox-ides and their catalytic activity in the Meerwein–Ponndorf–Verley reaction. Appl. Catal. A 244: 207-215
  28. Murugesan, A., Umarani, C., Chinnusamy, T.R., Krishnan, M., Subramanian, R., Neduzchezhain, N. (2009). Production and analysis of biodiesel from non edible oils-reviews. Renew. Sustain. En-ergy Rev. 13: 825-834
  29. Eevera, T., Rajendiran, K., Saradha, S. (2009). Biodiesel production process optimization and characterization to assess the suitability of the product for varied environmental condition. Re-new. Energy, 34: 762-765
  30. Yan, S., Kim, M., Salley, S.O., Ng, K.Y.S. (2009). Oil transesterification over calcium oxides modi-fied with lanthanum. Appl. Catal. A: Gen., 360: 163-170
  31. Sivakumar, P., Sindhanaiselvan, S., Gandhi, N.N., Devi, S.S., Renganathan, S. (2013). Optimi-zation and kinetic studies on biodiesel production from underutilized Ceiba pentandra oil. Fuel, 103: 693-698
  32. Predojevic, Z.J. (2008). The production of biodiesel from waste frying oils: A comparison of different purification steps. Fuel, 87: 3522-3528
  33. Miao, X., Wu, Q. (2006). Biodiesel production from heterotrophic microalgal oil. Bioresour. Technol., 97: 841-846

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