BibTex Citation Data :
@article{BCREC4759, author = {Sonali Sengupta and Jayanta Basu and Debarpita Ghosal}, title = {Oxidation of Catechol using Titanium Silicate (TS-1) Catalyst: Modeling and Optimization}, journal = {Bulletin of Chemical Reaction Engineering & Catalysis}, volume = {8}, number = {2}, year = {2013}, keywords = {Catechol; oxidation; TS-1; box-behnken design; kinetic study}, abstract = {The oxidation of catechol was studied in an eco-friendly process with commercial titanium silicate-1 (TS-1) catalyst and hydrogen peroxide as oxidant in absence of all mass transfer effects. The process was opti-mized by Box-Behnken design in terms of three independent process variables such as reaction tempera-ture, moles of hydrogen peroxide per mole of catechol and catalyst amount whose optimum values of the process variables were found to be 60 °C, 13.2 and 1.24 g respectively for maximum conversion of 75.8 %. The effects of different process parameters such as mole ratio of hydrogen peroxide to catechol, catalyst par-ticle size, catalyst amount, temperature and reaction time were studied. A pseudo first order kinetic model was fitted with the experimental rate data. The apparent activation energy for the reaction was found to be 11.37 kJ/mole. © 2013 BCREC UNDIP. All rights reserved Received: 22nd April 2013; Revised: 25th October 2013; Accepted: 1st November 2013 [ How to Cite : Sengupta, S., Ghosal, D., Basu, J.K. (2013). Oxidation of Catechol using Titanium Silicate (TS-1) Catalyst: Modeling and Optimization. Bulletin of Chemical Reaction Engineering & Catalysis , 8 (2): 167-177. (doi:10.9767/bcrec.8.2.4759.167-177)] [ Permalink/DOI : http://dx.doi.org/10.9767/bcrec.8.2.4759.167-177 ] }, issn = {1978-2993}, pages = {167--177} doi = {10.9767/bcrec.8.2.4759.167-177}, url = {https://ejournal.undip.ac.id/index.php/bcrec/article/view/4759} }
Refworks Citation Data :
Received: 22nd April 2013; Revised: 25th October 2013; Accepted: 1st November 2013
[How to Cite: Sengupta, S., Ghosal, D., Basu, J.K. (2013). Oxidation of Catechol using Titanium Silicate (TS-1) Catalyst: Modeling and Optimization. Bulletin of Chemical Reaction Engineering & Catalysis, 8 (2): 167-177. (doi:10.9767/bcrec.8.2.4759.167-177)]
[Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.2.4759.167-177]
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