Application of Cement Clinker as Ni-Catalyst Support for Glycerol Dry Reforming

Hua Chyn Lee  -  Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuh, Malaysia
Kah Weng Siew  -  Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuh, Malaysia
Jolius Gimbun  -  Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuh, Malaysia
*Chin Kui Cheng  -  Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuh, Malaysia
Received: 30 May 2013; Published: 1 Dec 2013.
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Abstract
The increase in biodiesel production inevitably yield plethora of glycerol. Therefore, glycerol has been touted as the most promising source for bio-syngas (mixture of H2 and CO) production. Significantly, coking on nickel-based catalysts has been identified as a major deactivation factor in reforming technology. Indeed, coke-resistant catalyst development is essential to enhance syngas production. The current work develops cement clinker (comprised of 62.0% calcium oxide)-supported nickel catalyst (with metal loadings of 5, 10, 15 and 20 wt%) for glycerol dry reforming (CO2). Physicochemical characterization of the catalysts was performed using XRD, XRF, BET, TGA and FESEM-EDS techniques. Subsequently, reaction studies were conducted in a 7-mm ID fixed-bed stainless steel reactor at 1023 K with various CO2 partial pressures at constant weight-hourly space velocity (WHSV) of 7.2×104 ml gcat-1 h-1. Gas compositions were determined using Agilent 3000 micro-gas chromatography (GC) and Lancom III gas analyzer. Results obtained showed an increment of BET surface area up to 32-fold with Ni loading which was corroborated by FESEM images. Syngas (H2 and CO) ratios of less than 2 were being produced at 1023 K. A closer scrutiny to the transient profile revealed that the presence of CO2 higher or lower than CGR 1:1 promotes the Boudouard reaction. © 2013 BCREC UNDIP. All rights reserved

Received: 30th May 2013; Revised: 27th August 2013; Accepted: 11st September 2013

[How to Cite: Lee, H.C., Siew, W.K., Cheng, C.K. (2013). Preparation Application of Cement Clinker as Ni-Catalyst Support for Glycerol Dry Reforming. Bulletin of Chemical Reaction Engineering & Catalysis, 8 (2): 137-144. (doi:10.9767/bcrec.8.2.5023.137-144)]

[Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.2.5023.137-144]

Keywords: Bio-syngas; cement clinker; glycerol; dry reforming

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Section: Original Research Articles
Language: EN
In 2013: BCREC Volume 8 Issue 2 Year 2013 (SCOPUS Indexed, December 2013)
Statistics: 944 901
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  9. Kurdowski, W. (2002). Role of Delayed Release of Sulphates from Clinker in DEF. Cement and Concrete Research 32: 401-407
  10. Tsakiridis, P.E., Agatzini-Leonardaou, S., Oustadakis, P., Katsioti, M., Mauridou, E. (2005). Examination of The Jarosite-Alunite Precipitate Addition in The Raw Meal for The Production of Portland Cement Clinker. Cement and Concrete Research 35: 2066-2073
  11. Taylor, H.F.W (1997). Cement Chemistry, London: Thomas Telford Publishing. 89
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  15. Gross, S. (1997). The Mineralogy of The Hatrurim Formation, Israel. Geol. Survey Israel Bull., 70: 80
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  18. Sinyoung, S., Songsiriritthigul, P., Suwimol, A., Kajitvichyanukul, P. (2011). Chromium Behavior during Cement-Production Processes: A Clinkerization, Hydration, and Leaching study. Journal of Hazardous Materials 191: 296-305
  19. Estellé, J., Salagre, P., Cesteros, Y., Serra, M., Medina, F., Sueiras, J.E. (2003). Comparative Study of The Morphology and Surface Properties of Nickel Oxide Prepared from Different Precursors. Solid State Ionics 156: 233-243
  20. Loaiza-Gil, A., Villarroel, M., Balbuena, J.F., Lacruz, M.A., Gonzalez-Cortés. (2008). Thermal Decomposition Study of Silica-supported Nickel Catalyst Synthesized by The Ammonia Method. Journal of Molecular Catalysis A: Chemical 281: 207-213
  21. Gabrovšek, R., Vuk, T., Kaučič, V. (2006). Evaluation of the Hydration of Portland Cement Containing Various Carbonates by Means of Thermal Analysis. Acta Chim. Slov. 53: 159-165

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