skip to main content

Synthesis of Poly(N-vinyl-2-pyrrolidone-co-methyl methacrylate) by Maghnite-H+ a Non-toxic Catalyst

*Mohamed Benadda  -  Laboratoire de Chimie des Polymères, Département de Chimie, Faculté des Sciences, Université d'Oran Es-Sènia BP N° 1524 El M'Naouar, 31000 Oran,, Algeria
Mohamed Issam Ferrahi  -  Laboratoire de Chimie des Polymères, Département de Chimie, Faculté des Sciences, Université d'Oran Es-Sènia BP N° 1524 El M'Naouar, 31000 Oran,, Algeria
Mohamed Belbachir  -  Laboratoire de Chimie des Polymères, Département de Chimie, Faculté des Sciences, Université d'Oran Es-Sènia BP N° 1524 El M'Naouar, 31000 Oran,, Algeria

Citation Format:
Cover Image
Abstract

In the present work poly (N-vinyl-2-pyrrolidone-co-methyl methacrylate) copolymers were prepared successfully and cleanly by a one step process via cationic copolymerization of N-vinyl-2-pyrrolidone (NVP) with methyl methacrylate (MMA), in heterogeneous phase using “Maghnite-H+” (Mag-H+) as catalyst in bulk, Maghnite is a montmorillonite sheet silicate clay exchanged with protons to produce Maghnite-H+. Temperature is varied between 20 and 80 °C. The effects of reaction temperature, amount of Mag-H+ on the yield and the intrinsic viscosity (η) were investigated. A typical reaction product of poly (NVP-co- MMA) was analyzed by infra red spectroscopy (FTIR) and 1H-NMR, 13C-NMR spectroscopy as well as by viscosimetry. © 2014 BCREC UNDIP. All rights reserved

Received: 24th November 2013; Revised: 30th June 2014; Accepted: 8th July 2014

How to Cite: Benadda, M., Ferrahi, M.I., Belbachir, M. (2014). Synthesis of Poly(N-vinyl-2-pyrrolidone-co-methyl methacrylate) by Maghnite-H+ a Non-toxic Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 9 (3): 201-206. (doi: 10.9767/bcrec.9.3.5743.201-206)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.9.3.5743.201-206

Fulltext View|Download

Article Metrics:

  1. Gjaerde, A. C. (1997). The new method of determining characteristics of elements for overvoltage protection of low-voltage system, IEEE Transaction on Dielectrics and Electrical Insulation, 4: 674-680
  2. Dissado, L. A., Mazzanti, G., Montanari, G. C. (1997). Influence of electro-mechanical stress on electrical properties of dielectric polymers, IEEE Transaction on Dielectrics and Electrical Insulation, 4: 496-505
  3. Gressus, C. L., Blaise, G. (1992). Thermal step method for space charge measurements under applied dc field, IEEE Transactions on Electrical Insulation, 27: 472-481
  4. Ajithkumar, M. P., Yashoda, M. P., Prasannakumar, S. (2012). Copolymerization of N-Vinyl pyrrolidone with methyl methacrylate by Ti(III)-DMG redox initiator. Turk. J. Chem., 36: 397-409
  5. Jin, S., Liu, M., Chen, S.,Gao, C. (2008). Synthesis, characterization and the rapid response property of the temperature responsive PVP-g-PNIPAM hydrogel, Eur. Polym. J., 44: 2162-2170
  6. Pakuro, N., Yakimansky, A., Chibirova, F.,Arest-Yakubovich, A.(2009).Thermo and pH-sensitivity of aqueous poly (N-vinylpyrrolidone) solutions in the presence of organic acids. Polymer, 50: 148-153
  7. Jin, S., Liu, M., Zhang, F., Chen, S., Niu, A. (2006). Synthesis and characterization of pH-sensitivity semi-IPN hydrogel based on hydrogen bond between poly(N-vinyl pyrrolidone) and poly (acrylic acid), Polymer, 47: 1526-1532
  8. El-Hag Ali, A., Shawky, HA., Abd El Rehim, HA., Hegazy, E. A. (2003). Hydrogels of poly- vinylpyrrolidone (PVP) and poly (acrylic acid) (PAA) synthesized by photoinduced crosslink- ing of homopolymers, Eur. Polym. J., 39: 2337–2344
  9. Jansen, J., Melchels, F.P.W., Grijpma, D.W., Feijen, J. (2009). Fumaric acid monoethyl ester-functionalized poly(D,L-lactide)/N-vinyl-2-pyrrolidone resins for the preparation of tissue engineering scaffolds by stereolithography, Biomacromolecules, 10: 214-20
  10. Bichuch, N.A., Ganyukhina, T.G., Semchikov, Y.D.(2003). Synthesis of poly(vinylacetate–methyl methacrylate) copolymer microspheres using suspension polymerization, J. Appl. Chem, 76: 607-609
  11. Jalili, K., Abbasi, F., Nasiri, M.,Ghasemi, M., Haddadi, E.(2009). Preparation and Characterization of Expandable St/MMA Copolymers Produced by Suspension Polymerization, J. Cellular Plastics, 45: 197-224
  12. Horak, D., Benes, M.J. (2000). Macroporouspoly(vinylpyrrolidone–co–ethylene dimethacrylate) beads by suspension polymerization, React. Func. Polym., 45: 189-195
  13. Belbachir, M., Bensaoula, A. (2006). Composition and method for catalysis using bentonites, US Patent, No7, 094-823 B2
  14. Yahiaoui, A., Belbachir, M., Hachemaoui, A. (2003). Cationic polymerization of 1,2-epoxypropane by an acid exchanged montmorillonite clay in the presence of ethylene glycol, International Journal of Molecular Sciences, 4: 572-585
  15. Harrane, A., Meghabar, R., Belbachir, M. (2002). A Protons Exchanged Montmorillonite Clay as an Efficient Catalyst for the Reaction of Isobutylene Polymerization, Int. J. Mol. Sci, 3: 790-800
  16. Harrane, A., Meghabar, R., Belbachir M. (2006). Kinetics of the ring opening polymerization of e-caprolactone catalyzed by proton exchanged montmorillonite clay, React. Funct. Polym, 66: 1696-1702
  17. Harrane, A., Naar, N., Belbachir, M. (2007). Ring opening polymerization of oxetane by the use of a montmorillonite clay as catalyst, Material Letters, 61: 3555-3558
  18. Ayat, M., Harrane, A., Belbachir, M. (2008). Maghnite-H+ a solid catalyst for the cationic Polymerization of α-methylstyrene, J. Appl. Polym. Sci., 109: 1476-1479
  19. Ferrahi, M.I., Belbachir, M.(2005).Synthesis of cyclic polyesters of poly (oxybutyleneoxymaleoyl), Journal of Polymer Research,12:167–171
  20. Ferrahi, M. I.,Belbachir M.(2004). Preparation of poly(oxybutyleneoxymaleoyl) catalyzed by a proton exchanged montmorillonite clay, Molecules, 9: 968-977
  21. Brown, D.R. (1994). Geol Carpathica Ser Clays, 45: 45
  22. Laszlo, P. (1987) Preparative Chemistry Using Supported Reagents, Academic Press: San Diego
  23. Namouchia, F., Smaoui, H., Fourati, N., Zerrouki, C., Guermazi, H., Bonnet, J.J. (2009). Investigation on electrical properties of ther- mally aged PMMA by combined use of FTIR and impedance spectroscopies, Journal of Al- loys and Compounds, 469: 197-202
  24. Brar, A.S., Kumar, R. (2002). Microstructure analysis of N-vinyl-2-pyrrolidone/vinyl acetate copolymers by NMR spectroscopy, Polymer. Int, 51: 519-529
  25. Kothandaraman, H., Sangeetha, D.(2001). Effect of the catalyst on the copolymers of styrene with methyl methacrylate by Ziegler-Natta polymerization, European Polymer Journal, 37: 485-495
  26. Brar, A.S., Kumar, R., Kaur, M. (2003). N-vinyl-2-pyrrolidone and methacrylonitrile copolymers: nuclear magnetic resonance characterization, Journal of Molecular Structure, 650: 85-92

Last update:

No citation recorded.

Last update:

No citation recorded.