Synthesis of CaOZnO Nanoparticles Catalyst and Its Application in Transesterification of Refined Palm Oil

Cicik Herlina Yulianti  -  Department of Electrical Engineering, Faculty of Technology, Universitas Islam Lamongan, East Java,, Indonesia
Ratna Ediati  -  Laboratory of Material Chemistry and Energy, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya,, Indonesia
Djoko Hartanto  -  Laboratory of Material Chemistry and Energy, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya,, Indonesia
Tri Esti Purbaningtias  -  Diploma of Analytical Chemistry, Faculty of Mathematics and Natural Sciences, Islamic University of Indonesia, Yogyakarta,, Indonesia
Yoshifumi Chisaki  -  Department of Computer Science, Kumamoto University, 2-39-1 Kurokami, Kumamoto, 860-8555,, Japan
Aishah Abdul Jalil  -  Institute of Hydrogen Economy, Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM, Johor Bahru,, Malaysia
Che Ku Nor Liana Che Ku Hitam  -  Institute of Hydrogen Economy, Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM, Johor Bahru,, Malaysia
*Didik Prasetyoko  -  Laboratory of Material Chemistry and Energy, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya,, Indonesia
Received: 1 Jan 2014; Published: 1 Aug 2014.
Open Access
Citation Format:
graphical 5998
Abstract

The CaOZnO nanoparticle catalysts with Ca to Zn atomic ratios of 0.08 and 0.25 have been successfully synthesized by co-precipitation method. The catalyst was characterized by X-ray Diffraction (XRD) analysis provided with Rietica and Maud software, Scanning Electron Microscopy (SEM) and Fourier Transform Infrared spectroscopy (FT-IR), and its properties was compared with bare CaO and ZnO catalysts. The phase composition estimated by Rietica software revealed that the CaO catalyst consists of CaO and CaCO3 phases. The estimation of the particle size by Maud software, showed that the particle size of all catalysts increased by the following order: ZnO. © 2014 BCREC UNDIP. All rights reserved

Received: 1st January 2014; Revised: 10th March 2014; Accepted: 18th March 2014

[How to Cite: Yulianti, C.H., Ediati, R., Hartanto, D., Purbaningtias, T.E., Chisaki, Y., Jalil, A.A., Hitam, C.K.N.L.C.K., Prasetyoko, D., (2014). Synthesis of CaOZnO Nanoparticles Catalyst and Its Application in Transesterification of Refined Palm Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 9 (2): 100-110. (doi:10.9767/bcrec.9.2.5998.100-110)]


[Permalink/DOI: http://dx.doi.org/10.9767/bcrec.9.2.5998.100-110]

Keywords: CaOZnO coprecipitation; transesterification; refined palm oil; yield of methyl ester; TON-TOF
Funding: JICA PREDICT – ITS Batch 2 and Directorate General of Higher Education Indonesia

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Article Info
Section: Original Research Articles
Language: EN
In 2014: BCREC Volume 9 Issue 2 Year 2014 (SCOPUS Indexed, August 2014)
Statistics: 1965 2535
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  5. Liu, X., He, H., Wang, Y., Zhu, S., Piao, X. (2008). Transesterification of Soybean Oil to Biodiesel Using CaO as a Solid Base Catalyst. Fuel, 27(2): 216-221
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  7. Alba-Rubio, A. C., Santamaria-Gonzalez, J., Josefa M. (2010). Heterogeneous Transesteri-fication Processes by Using CaO Supported on Zinc Oxide as Basic Catalysts. Catalysis T-day, 149: 281-287
  8. Ngamcharussrivichai, C., Totarat, P., Bunyakiat, K. (2008). Ca and Zn Mixed Oxide as a Heterogeneous Base Catalyst for Transesterification of Palm Kernel Oil. Applied Catalysis A: General, 341: 77-85
  9. Wang, H., Wang, M., Liu, S., Zhao, N., Wei, W., Sun, Y. (2006). Influence of Preparation Methods on the Structure and Performance of CaO–ZrO2 Catalyst for the Synthesis of Dimethyl Carbonate via Transesterification. Journal of Molecular Catalysis A: Chemical, 258: 308-312
  10. Cho, Y.B., Seo, G., Chang, D.R. (2009). Transesterification of Tributyrin with Methanol over Calcium oxide Catalysts Prepared from Various Precursors. Fuel Processing Technology, 90: 1252-1258
  11. Yan, S., Mohan, S., DiMaggio, C., Kim, M., Simon Ng, K.Y., Salley, S.O. (2010). Long Term Activity of Modified ZnO Nanoparticles for Transesterification. Fuel, 89: 2844-2852
  12. Kanade, K.G., Kale, B.B., Aiyer, R.C., Das, B.K. (2006). Effect of Solvents on the Synthesis of Nano-Size Zinc Oxide and Its Properties. Materials Research Bulletin, 41: 590-600
  13. Albuquerque, M.C.G., Jimenez, U.I., Santamaria, G.J. (2008). CaO Supported on Mesoporous Silicas as Basic Catalysts for Transesterification Reactions. Applied Catalysis A: General, 334: 35-43
  14. El-Shobaky, G.A., Mostafa A.A. (2003). Solid-Solid Interactions in Fe2O3/MgO System Doped with Aluminium and Zinc Oxides. Thermochimica Acta, 408: 75-84
  15. Palomino, A.G.P. (2006). Room Temperature Synthesis and Characterization of Highly Monodisperse Transition Metal-Doped ZnO Nanocrystals. University of Puerto Rico
  16. Ma, F., Hanna, M.A. (1999). Biodiesel Production: A Review. Bioresource Technology, 70: 1-15
  17. Taufiq-Yap, Y.H., Lee, H.V., Hussein, M.Z., Yunus, R. (2011). Calcium-Based Mixed Oxide Catalysts for Methanolysis of Jatropha Curcas Oil to Biodiesel. Biomass Bioenergy, 35: 827-834

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