Preparation and Characterization of Lithium Zirconium Silicate for CO2 Capture

T.S. Bhosale  -  Chemical Engineering and Process Development Division, National Chemical Laboratory, Pune 411 008,, India
*A. G. Gaikwad  -  Chemical Engineering and Process Development Division, National Chemical Laboratory, Pune 411 008,, India
Received: 27 Mar 2014; Published: 28 Oct 2014.
Open Access
Citation Format:
Cover Image
Abstract

The samples of lithium zirconium silicate were prepared by precipitation, template and sol-gel meth-ods. The samples were prepared with several mol ratios of Li:Zr:Si. The preparation of lithium zirco-nium silicate samples by precipitation method were carried out by using the lithium nitrate, zirconyl nitrate, zirconium(IV) oxypropoxide and tetramethylorthosilicate (TEOS) as precursors. The samples of lithium zirconium silicate were prepared by using cetyltrimethyl-ammonium bromide (C-TAB) and tetramethyl ammonium hydroxide (TMAOH) by template method. The samples of lithium zirconium silicate were characterized by XRD, TEM, SEM, 29Si-MAS NMR and FTIR. The surface area, alkalinity / acidity of the samples of lithium zirconium silicate were measured. The TGA analysis of lithium zirco-nium silicate samples was done. The CO2 captured by the samples of lithium zirconium silicate was es-timated. The captured CO2 by the samples of lithium zirconium silicate was found to be in the range 3.3 to 8.6 wt%. © 2014 BCREC UNDIP. All rights reserved

Received: 27th March 2014; Revised: 31st July 2014; Accepted: 2nd August 2014

How to Cite: Bhosale, T.S. , Gaikwad, A.G. (2014). Preparation and Characterization of Lithium Zirconium Silicate for CO2 Capture. Bulletin of Chemical Reaction Engineering & Catalysis, 9(3): 249-262. (doi:10.9767/bcrec.9.3.6646.249-262)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.9.3.6646.249-262

Keywords: Lithium zirconium silicate; Preparation method; sol gel method, template method; characterization; CO2 capture;

Article Metrics:

  1. Ganesh, M., Hemalatha, P., Peng, M. M., Jang, H.T. (2013). One pot synthesis Li Zr doped porous silica nano-particle for low temperature CO2 adsorption. Arabian Journal of Chemistry. (In press)
  2. Radfarnia, H. R., Iliuta, M. C. (2011). Surfactant- template/ ultrasound- assisted method for the preparation of porous nanoparticle lithium zirconium. Industrial and Engineering Chemistry Research. 50: 9295-9305
  3. Yi, K. B., Eriksen, D. Q. (2006). Low temperature liquid state synthesis of lithium zirconium and its characteristics as a CO2 sorbent. Separation Science Technology. 41: 283-296
  4. Pfeiffer, H., Bosch, P., Bulbulian, S. (2000). Sol-gel synthesis of Li2ZrSi6O15 powders. Journal of Material Chemistry. 10: 1255-1258
  5. Angel, J. D., Aguilera, A. F., Galindo, I. R., Martinez, M., Viveros, T. (2012). Synthesis and characterization of alumina-zirconia powders obtained by sol-gel method: Effect of solvent and water addition rate. Material Science and Application. 3:650-657
  6. Vives. S., Guizard, C., Cot, L., Oberlin, C. (1999). Sol-gel/ co-precipitation method for the preparation and characterization of zirconium- tungsten composite powders. Journal of Material Science. 34:3127-3135
  7. Ferreira, P., Ferreira, A.,Rocha, J., Soares, M. R. (2001). Synthesis and characterization of zirconium silicates. Chemistry of Materials. 13: 355-363
  8. Bensitel, M., Moravek, V., Lamotte, J., Saur, O., Lavalley, J. E. (1987). Infrared study of alcohols adsorption on zirconium oxide: reactivity of alkoxy species towards CO2. Spectrochimica Acta. 43A: 1487-1491
  9. Bretado, M. E., Velderrain, V. G., Gutiérrez, D. L., Collins-Martínez, V., Ortiz, A. L. (2005). A new synthesis route to Li4SiO4 as CO2 catalytic/ sorbent. Catalysis Today. 107-108: 863-867
  10. Yamaguchi, T., Niitsuma, T., Nair, B. N., Nakagawa, K. (2007). Lithium silicate based membranes for high temperature CO2 separation. Journal of Membrane Science. 294:16-21
  11. Shan, S.Y., Li, S .M., Jia, Q. M., Jiang, L. H., Wang, Y. M., Peng, J. H. (2013). Impregnation precipitation preparation and kinetic analysis of Li4SiO4 – based sorbents with fast CO2 adsorption rate. Industrial and Engineering Chemistry Research. 52: 6941-6945
  12. Ishida, H., Tadanaga, K., Hayashi. A., Tatsumisago, M. (2013). Synthesis of monodispersed lithium silicate particle using the sol-gel method. Journal of Sol-Gel Science and Technology. 65:1,41-45
  13. Xiang-qun, L., Hua-jun, G., Li-ming, L., Xin-hai, L., Zhi-xing. W., Hui. O., Kai-xiong, X. (2011). Effects of calcination temperature on properties of Li2SiO3 for precursor of Li2FeSiO4. Transactions of Nonferrous Metals Society of China. 21: 529-534
  14. Zhao, Q., Bao, X. H., Han, X. W., Liu, X. M., Tan, D. L., Lin, L.W., Guo, X. W., Li, G., Wang, X. S. (2000). Studies on the crystallization process of titanium silicate- 1 (TS-1) synthesized using tetrapropylammonium bromide as a template. Materials Chemistry and Physics. 66: 41-50
  15. Andrews, L. (1968). Infrared spectrum, structure, vibrational potential function, and bonding in the lithium superoxide molecule LiO2. Journal of Chemical Physics. 48: 4288-4298
  16. Gang, L., Xinwen, G., Xiangsheng, W., Qi, Z., Xinhe, B., Xiuwen, H., Liwu, L. (1999). Synthesis of titanium silicate in different template system and their catalytic performance. Applied Catalysis. 185: 11-18
  17. Balmer, M. L., Bunker, B. C., Wang, L. Q., Peden, C. H. F., Su, Y. (1997). Solid-state 29Si MAS NMR study of titanosilicates. Journal of Physical Chemistry B. 101: 9170-9179
  18. Mägi, M., Lippman, E., Samoson, A. (1984). Solid- state high-resolution silicon-29 chemical shifts in silicates. Journal of Physical Chemistry. 88: 1518-1522
  19. Casanovas, J., Illas, F., Pacchioni , G. (2000). Ab inito calculations of 29Si solid state NMR chemical shifts of silane and silanol group in silica. Chemical Physics Letters. 326: 523-529
  20. Schneider, J., Mastelaro, V. R., Panepucci, H., Zanotto, E. D. (2000). 29Si MAS-NMR Studies of Qn structural units in metasilicate glasses and their nucleating ability. Journal of Non-Crystalline solids. 273: 8-18
  21. Powder diffraction file no. 73-0593 & 12-0250, JCPDS-ICCD (1999)
  22. Powder diffraction file no. 76-1150 & 75-2157, JCPDS-ICCD (1999)
  23. Powder diffraction file no. 47-0638, JCPDS-ICCD (1999)
  24. Powder diffraction file no. 86-0551, JCPDS-ICCD (1999)
  25. Powder diffraction file no. 83-1517, JCPDS-ICCD (1999)
  26. Powder diffraction file no. 81-2376 & 81-2375, JCPDS-ICCD (1999)
  27. Powder diffraction file no. 83-1413 & 82-1575, JCPDS-ICCD (1999)
  28. Powder diffraction file no. 83-0943 & 83-0944, JCPDS-ICCD (1999)
  29. Powder diffraction file no. 36-0049, JCPDS-ICCD (1999)
  30. Powder diffraction file no. 80-1470, JCPDS-ICCD (1999)
  31. Powder diffraction file no. 03-0630, JCPDS-ICCD (1999)
  32. Smith, J. S., Thrower, P. A., Vannice, M. A. (1981). Characterization of Ni/TiO2 catalysts by TEM, X-ray diffraction, and chemisorptions techniques. Journal of Catalysis. 68: 270-285
  33. Nakamoto, K. (2009). Infrared and Raman spectra of inorganic and coordination compounds, Part A, 6th edition. Wiley, United State

Last update: 2021-03-04 20:23:47

No citation recorded.

Last update: 2021-03-04 20:23:48

No citation recorded.