Mesoporous Silica from Rice Husk Ash

V.R. Shelke  -  Department of Chemical Eengineering, Anuradha Engineering College, Chikhli-443201, India
*S.S. Bhagade  -  Department of Chemical Eengineering, Anuradha Engineering College, Chikhli-443201
S.A. Mandavgane  -  Department of Chemical Eengineering, Anuradha Engineering College, Chikhli-443201, India
Received: 20 Jan 2011; Published: 20 Jan 2011.
Open Access
Citation Format:
Abstract

Mesoporous silica is used as a raw material in several areas: in preparation of catalysts, in inks, as a concrete hardening accelerator, as a component of detergents and soaps, as a refractory constituent etc. Sodium silicate is produced by reacting rice hull ash (RHA) with aqueous NaOH and silica is precipitated from the sodium silicate by acidification. In the present work, conversion of about 90% of silica contained in RHA into sodium silicate was achieved in an open system at temperatures of about 100 °C. The results showed that silica obtained from RHA is mesoporous, has a large surface area and small particle size. Rice Husk is usually mixed with coal and this mixture is used for firing boilers. The RHA therefore, usually contains carbon particles. Activated carbon embedded on silica has been prepared using the carbon already present in RHA. This carbon shows good adsorption capacity. ©2010 BCREC UNDIP. All rights reserved

(Received: 25th April 2010, Revised: 17th June 2010, Accepted: 24th June 2010)

[How to Cite: V.R. Shelke, S.S. Bhagade, S.A. Mandavgane. (2010). Mesoporous Silica from Rice Husk Ash. Bulletin of Chemical Reaction Engineering and Catalysis, 5 (2): 63-67. doi:10.9767/bcrec.5.2.793.63-67]

[DOI: http://dx.doi.org/10.9767/bcrec.5.2.793.63-67 ]

Keywords: Sodium silicate; Rice husk ash; Activated Carbon

Article Metrics:

  1. S. Chandrasekar, K. G. Satyanarayana, P.M. Pramada, P. Raghavan, and T.N. Gupta, (2003), Processing, Properties and Applications of Reactive Silica from Rice Husk — an Overview. Journal of Materials Science, 38, p. 3159-3168
  2. C. Real, M. Alcala, J. Criado, (1996), Preparation of Silica from Rice Husks. Journal of American Ceramic Society. 79, p. 2012-2016
  3. C. S. Prasad, K. N. Maiti, and R. Venugopal. (2001). Effect of RHA in White Ware Compositions. Ceramics International, 27, p. 629-635
  4. J. C. Saha, K. Diksit, and M. Bandyopadhyay. (2001). Comparative Studies for Selection of Technologies for Arsenic Removal From Drinking Water. Paper presented at BUET-UNU International Workshop on Technologies for Arsenic Removal from Drinking Water, Bangladesh.UNDP Sustainable Development Networking Program, Technical Session II, May 5th
  5. S. Siriwandena, H. Ismail, and U. S. Ishakiaku. (2001). A Comparison of White Rice Husk Ash and Silica as Filler in Ethylene-propylene-diene Terpolymer Vulcanizates. Polymer International, 50, p. 707-713
  6. _____, (2003). Rice Husk Ash Market. Report, http:.//www.dti.gov.UK/renewables/Publication/pdfs/exp 129.pdf
  7. H.S. Mukunda, S. Dasappa, P. J. Paul, N. K. S. Rajan, D.N. Subbukrishna. (2003), A Novel Process And Apparatus For The Manufacture Of Precipitated Silica From Rice Husk Ash. Indian Patent No. 216477, 18th Feb, 2003
  8. G.C. Isaia, A.L.G. Gastaldini, and R. Moraes. (2003). Physical and pozzolanic action of mineral additions on mechanical strength of high performance concrete. Cement and Concrete Composites. 25, p. 69-76
  9. E. L. Foletto, M. M. Castoldi, L. H. Oliveira, R.Hoffmann , and S.L. Jahn. (2009). Conversion Of Rice Husk Ash Into Zeolitic Materials. Latin American Applied Research. 39, p. 75-78
  10. D.K. Stefens. (2000). Precipitated silicas, silica gels with and free of deposited carbon from caustic biomass ash solutions and processes. US Patent 6114280
  11. N. Thuadaij, and A. Nuntiya. (2008). Preparation of Nanosilica Powder from Rice HuskAsh by Precipitation Method. Chiang Mai Journal of Science. 35(1), p. 206-211

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