DOI: https://doi.org/10.14710/jkli.22.3.359-368

Literature Review: Penggunaan Bahan Berbasis Limbah Sebagai Adsorben untuk Degradasi Zat Warna pada Air Limbah

Departemen Teknik Sipil, Fakultas Teknik, Universitas Indonesia, Kampus Baru UI Depok, Jawa Barat 16424, Indonesia

Open Access Copyright 2023 Jurnal Kesehatan Lingkungan Indonesia under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

Latar belakang: Penggunaan adsorben bahan limbah dari limbah pertanian, industri maupun bahan alam menjadi alternatif baru dalam pengolahan air limbah yang mengandung zat warna. Limbah ini dapat menyebabkan berbagai masalah kesehatan bagi makhluk hidup mulai dari alergi, cidera permanen, asma, bahkan kanker. Tujuan review artikel ini adalah untuk memberikan informasi tren penelitian penggunaan adsorben dari bahan limbah dalam penyisihan zat warna serta informasi mengenai komposisi bahan, dan pengaplikasiannya sebagai potensi alternatif baru bahan adsorben dalam pengolahan limbah.

Metode: Metode dalam penulisan review artikel ini dengan metode PRISMA 2020 menggunakan  PRISMA checklist melalui 27 identifikator yang telah disediakan. Seleksi artikel dilakukan dengan beberapa kriteria dari tahun publikasi, kata kunci, klasifikasi bahan adsorben, serta artikel tentang adsorpsi secara umum sebagai pendukung. Artikel jurnal terpilih dan sesuai dengan kebutuhan sebanyak 28 artikel kemudian dilakukan pengkajian serta pembahasan lebih lanjut.

Hasil: Hasil review artikel yang dikaji sebanyak 50% artikel yang memanfaatkan limbah pertanian sebagai adsorben, 18% artikel memanfaatkan limbah industri, dan 32% artikel memanfaatkan bahan alam. Pengkajian dilakukan menyeluruh mengenai metode pembuatan adsorben, komposisi bahan adsorben, kemampuan adsorpsi, studi kinetika dan studi isotherm adsorpsi. Hasil kajian menunjukkan kemampuan adsorben bahan limbah sangat baik dengan efisiensi tertinggi hingga 99,95%. Metode pembuatan adsorben yang paling umum digunakan dengan aktivasi fisika. Model isotherm yang digunakan sebagian besar adalah Langmuir dengan kinetika adsorpsi pseudo orde kedua.

Simpulan: Potensi pemanfaatan adsorben dari bahan limbah sangat besar, ditinjau dari persentase efisiensinya dan kelimpahan bahan baku. Dalam proses adsorpsinya dipengaruhi oleh kandungan bahan, luas permukaan, dan metode pembuatan adsorben.

 

ABSTRACT

Title: Literature Review:  The Use of Waste Materials as Adsorbent for Degradation Dyes in Wastewater

Background: Industrial, agricultural, and natural dyes can now be treated with adsorbents. This wastewater can cause allergies, serious wounds, asthma, and cancer. This article review discusses current research trends in using waste materials as dye removal adsorbents and their composition and possible usage as new, alternative adsorbents in the waste treatment sector.

Method: This article review used PRISMA 2020 with 27 identifiers and the checklist. Articles were selected by year, keywords, adsorbent material categorization, and adsorption in general. Following 28 article requirements, selected journal articles were researched and discussed.

Result: The analysis of the articles found that 32% of the articles used natural materials, 18% of the articles used industrial waste, and 50% of the articles used agricultural waste as an adsorbent. The process for creating adsorbents, the make-up of adsorbent materials, adsorption capacity, kinetic studies, and adsorption isotherm studies were all thoroughly evaluated. The study's findings demonstrate that waste materials have excellent adsorbent properties, with the highest efficiency reaching up to 99.95%. Physical activation is the most widely used adsorbent preparation technique. Most of the isotherm models in use have pseudo-second order adsorption kinetics and are Langmuir.

Conclusion: Given the percentage of efficiency and the abundance of raw materials, there is a very large potential for using adsorbents made from waste materials. The adsorbent's surface area, material composition, and manufacturing process all have an impact on the adsorption process.

 

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Keywords: Zat Warna; Adsorpsi; Limbah Pertanian; Limbah Industri; Bahan alam

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Section: Research Articles
Language : ID
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  1. Katheresan V, Kansedo J, Lau SY. Efficiency of various recent wastewater dye removal methods: A review. Journal of Environmental Chemical Engineering. 2018 Aug;6(4):4676–97. https://doi.org/10.1016/j.jece.2018.06.060
  2. Aljbour SH, Al-Harahsheh AM, Aliedeh MA, Al-Zboon K, Al-Harahsheh S. Phosphate removal from aqueous solutions by using natural Jordanian zeolitic tuff. Adsorption Science & Technology. 2017 May;35(3–4):284–99. https://doi.org/10.1177/0263617416675176
  3. Gupta VK, Suhas. Application of low-cost adsorbents for dye removal – A review. Journal of Environmental Management. 2009 Jun;90(8):2313–42. https://doi.org/10.1016/j.jenvman.2008.11.017
  4. AL-Jobouri IS, Dhahir SA, AL-Saade KA. Congo red Adsorption on Bentonite and Modified Bentonite. 2013;18
  5. Jalil AA, Triwahyono S, Adam SH, Rahim ND, Aziz MAA, Hairom NHH, et al. Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud. Journal of Hazardous Materials. 2010 Sep;181(1–3):755–62. https://doi.org/10.1016/j.jhazmat.2010.05.078
  6. Ruhmawati T, Budiasyah T, Setiawan R. Efisiensi Penyisihan Kadar Amoniak Limbah Cair Rumah Sakit dengan Proses Adsorpsi Karbon Aktif Bijih Plastik. Jurnal Kesehatan Lingkungan Indonesia. 2020 Oct 1;19(2):82–8. https://doi.org/10.14710/jkli.19.2.82-88
  7. Yagub MT, Sen TK, Afroze S, Ang HM. Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science. 2014 Jul;209:172–84. https://doi.org/10.1016/j.cis.2014.04.002
  8. Fatimah Rahmayani, Siswarni MZ. Pemanfaatan Limbah Batang Jagung Sebagai Alternatif Pada Pengurangan Kadar Klorin Dalam Air Olahan (Treated Water). J Teknik Kimia. 2013 Jun 19;2(2):1–5. https://doi.org/10.32734/jtk.v2i2.1427
  9. Anastopoulos I, Ahmed MJ, Hummadi EH. Eucalyptus-based materials as adsorbents for heavy metals and dyes removal from (waste)waters. Journal of Molecular Liquids. 2022 Jun;356:118864. https://doi.org/10.1016/j.molliq.2022.118864
  10. Momina, Mohammad S, Suzylawati I. Study of the adsorption/desorption of MB dye solution using bentonite adsorbent coating. Journal of Water Process Engineering. 2020 Apr;34:101155. https://doi.org/10.1016/j.jwpe.2020.101155
  11. Ulfindrayani IF, Ikhlas N, A’yuni Q, Fanani N, Gaol BL, Lestari D. Pengaruh Ekstraksi SiO2 dari Lumpur Lapindo Terhadap Daya Adsorpsinya pada Larutan Metil Orange. CHEESA. 2019 Dec 18;2(2):50. https://doi.org/10.25273/cheesa.v2i2.5108
  12. Utomo WP, Santoso E, Yuhaneka G, Triantini AI, Fatqi MR, Huda MF, et al. Studi Adsorpsi Zat Warna Naphthol Yellow S Pada Limbah Cair Menggunakan Karbon Aktif dari Ampas Tebu. Jurnal Kimia. 2019 Jan 16;13(1):104. https://doi.org/10.24843/JCHEM.2019.v13.i01.p16
  13. Fatimah I, Sahroni I, Dahlyani MSE, Oktaviyani AMN, Nurillahi R. Surfactant-modified Salacca zalacca skin as adsorbent for removal of methylene blue and Batik’s wastewater. Materials Today: Proceedings. 2021;44:3211–6. https://doi.org/10.1016/j.matpr.2020.11.440
  14. Aprilia Lestari V, Bagus Priambodo T. Kajian Komposisi Lignin dan Selulosa dari Limbah Kayu Sisa Dekortikasi Rami dan Cangkang Kulit Kopi Untuk Proses Gasifikasi Downdraft. JEnLing. 2020 Nov 25;16(1):1–8. https://doi.org/10.29122/jel.v16i1.4572
  15. Lubis S, Sheilatina S, Nika S, Putra V. Adsorption of Naphthol Blue Black Dye onto Acid Activated Titania Pillared Bentonite: Equilibrium Study. Orient J Chem. 2016 Aug 25;32(4):1789–97. https://doi.org/10.13005/ojc/320407
  16. Fadhil OH, Eisa MY. Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material. jcoeng. 2019 Apr 1;25(4):55–69. https://doi.org/10.31026/j.eng.2019.04.05
  17. Zuorro A, Lavecchia R, Medici F, Piga L. Spent Tea Leaves as a Potential Low-cost Adsorbent for the Removal of Azo Dyes from Wastewater. In Florence: Associazione italiana di ingegneria chimica; 2013. https://doi.org/10.4028/www.scientific.net/AMR.803.26
  18. Tripelo Fladinir A, Prasetyo Suseno H, Sunarsih* S. Efektivitas Karbon Aktif Tempurung Kemiri Dalam Menurunkan Kadar Warna Naftol Merah Limbah Cair Industri Batik. Jurtek. 2022 Jun 19;15(1):30–7. https://doi.org/10.34151/jurtek.v15i1.3985
  19. Adebayo MA, Adebomi JI, Abe TO, Areo FI. Removal of aqueous Congo red and malachite green using ackee apple seed–bentonite composite. Colloid and Interface Science Communications. 2020 Sep;38:100311. https://doi.org/10.1016/j.colcom.2020.100311
  20. Amran F, Zaini MAA. Sodium hydroxide-activated Casuarina empty fruit: Isotherm, kinetics and thermodynamics of methylene blue and congo red adsorption. Environmental Technology & Innovation. 2021 Aug;23:101727. https://doi.org/10.1016/j.eti.2021.101727
  21. Ghosh GC, Chakraborty TK, Zaman S, Nahar MN, Kabir AHME. Removal of Methyl Orange Dye from Aqueous Solution by a Low-Cost Activated Carbon Prepared from Mahagoni (Swietenia mahagoni) Bark. Pollution [Internet]. 2020 Jan [cited 2022 Jul 2];6(1). Available from: https://doi.org/10.22059/poll.2019.289061.679
  22. Khan TA, Nazir M. Enhanced adsorptive removal of a model acid dye bromothymol blue from aqueous solution using magnetic chitosan-bamboo sawdust composite: Batch and column studies. Environ Prog Sustainable Energy. 2015 Aug 9;34(5):1444–54. https://doi.org/10.1002/ep.12147
  23. Rahadi B, Haji ATS, Universitas Brawijaya, Robbaniyah I, Universitas Brawijaya. Analisis Penurunan Konsentrasi Methyl Orange Dengan Biosorben Kulit Pisang Cavendish (Musa Acuminata Cv. Cavendish). JSAL. 2019 Aug 31;6(2):29–35. https://doi.org/10.21776/ub.jsal.2019.006.02.5
  24. Shah SS, Sharma T, Dar BA, Bamezai RK. Adsorptive removal of methyl orange dye from aqueous solution using populous leaves: Insights from kinetics, thermodynamics and computational studies. Environmental Chemistry and Ecotoxicology. 2021;3:172–81. https://doi.org/10.1016/j.enceco.2021.05.002
  25. Uddin MK, Nasar A. Walnut shell powder as a low-cost adsorbent for methylene blue dye: isotherm, kinetics, thermodynamic, desorption and response surface methodology examinations. Sci Rep. 2020 Dec;10(1):7983. https://doi.org/10.1038/s41598-020-64745-3
  26. Al-Zawahreh K, Barral MT, Al-Degs Y, Paradelo R. Competitive removal of textile dyes from solution by pine bark-compost in batch and fixed bed column experiments. Environmental Technology & Innovation. 2022 Aug;27:102421. https://doi.org/10.1016/j.eti.2022.102421
  27. Taufiq A, Hidayat P, Hidayat A. Modified coal fly ash as low cost adsorbent for removal reactive dyes from batik industry. Ma’mun S, Tamura H, Purnomo MRA, editors. MATEC Web Conf. 2018;154:01037. https://doi.org/10.1051/matecconf/201815401037
  28. Pethkar PA, Nalawade PM, Pethkar AV. Kinetics Study of Methyl Orange Adsorption from Aqueous Solutions using Fly Ash Granules as Low Cost Adsorbent. 2020;79:5. https://doi.org/10.56042/jsir.v79i7.40505
  29. Potgieter JH, Pardesi C, Pearson S. A kinetic and thermodynamic investigation into the removal of methyl orange from wastewater utilizing fly ash in different process configurations. Environ Geochem Health. 2021 Jul;43(7):2539–50. https://doi.org/10.1007/s10653-020-00567-6
  30. Filho AV, Kulman RX, Janner NN, Tholozan LV, de Almeida ARF, da Rosa GS. Optimization of cationic dye removal using a high surface area-activated carbon from water treatment sludge. Bull Mater Sci. 2021 Dec;44(1):41. https://doi.org/10.1007/s12034-020-02333-x
  31. Laib S, Yazid HR, Sadaoui Z. Comparative Study on Removal of Textile Dyes in Aqueous Medium by Adsorption Using Modified Drinking Water Treatment Sludge. Arabian Journal for Science and Engineering. 2021;14. https://doi.org/10.1007/s13369-021-05950-8
  32. Atirza V, Soewondo P, Program Studi Teknik Lingkungan, FTSL, Institut Teknologi Bandung. Penyisihan Zat Warna Napthol Pada Limbah Cair Batik Dengan Metode Adsorpsi Menggunakan Adsorben Tanah Liat Dan Regenerasinya. j.tl. 2018 Apr 1;24(1):93–106. https://doi.org/10.5614/j.tl.2018.24.1.7
  33. Bentahar S, Dbik A, Khomri ME, Messaoudi NE, Lacherai A. Removal of a cationic dye from aqueous solution by natural clay. Groundwater for Sustainable Development. 2018 Mar;6:255–62. https://doi.org/10.1016/j.gsd.2018.02.002
  34. Imandiani S, Indira C, Johan A, Budiyono. Utilization of Natural Zeolite from Ponorogo and Purworejo for Naphthol Substance Adsorption. Hadiyanto, Sudarno, Maryono, editors. E3S Web Conf. 2018;31:05002. https://doi.org/10.1051/e3sconf/20183105002
  35. Kamarudin NHN, Setiabudi HD, Abdul Jalil A, Adam SH, Muhamad Salleh NF. Utilization of Lapindo Volcanic Mud for Enhanced Sono-sorption Removal of Acid Orange 52. Bull Chem React Eng Catal. 2019 Apr 15;14(1):189. https://doi.org/10.9767/bcrec.14.1.3326.189-195
  36. Salamah S, Wahyuni ET. The characterization of Merapi volcanic ash as adsorbent for dyes removal from batik wastewater. IOP Conf Ser: Mater Sci Eng. 2018 Oct 9;403:012007. https://doi.org/10.1088/1757-899X/403/1/012007
  37. Martins AE, Pereira MS, Jorgetto AO, Martines MAU, Silva RIV, Saeki MJ, et al. The reactive surface of Castor leaf [Ricinus communis L.] powder as a green adsorbent for the removal of heavy metals from natural river water. Applied Surface Science. 2013 Jul;276:24–30. https://doi.org/10.1016/j.apsusc.2013.02.096
  38. Khalilzadeh Shirazi E, Metzger JW, Fischer K, Hassani AH. Design and cost analysis of batch adsorber systems for removal of dyes from contaminated groundwater using natural low-cost adsorbents. Int J Ind Chem. 2020 Jun;11(2):101–10. https://doi.org/10.1007/s40090-020-00205-1

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