Effect of the Amount of Carbon in the Fe3O4@ZnO-C Nanocomposites on Its Structure and Magnetic Properties

Astuti Astuti; Syukri Arief; Devi Pebrina

doi:10.14710/jksa.25.10.362-367

DOI: https://doi.org/10.14710/jksa.25.10.362-367

Effect of the Amount of Carbon in the Fe3O4@ZnO-C Nanocomposites on Its Structure and Magnetic Properties

Astuti Astuti¹

, Syukri Arief²

, Devi Pebrina¹

¹Department of Physics, Faculty of Sciences and Mathematics, Andalas University, Padang, Indonesia

²Department of Chemistry, Faculty of Sciences and Mathematics, Andalas University, Padang, Indonesia

Received: 28 Sep 2022; Revised: 23 Nov 2022; Accepted: 23 Dec 2022; Published: 25 Dec 2022.

BibTex Citation Data :

@article{JKSA49246,
    author = {Astuti Astuti and Syukri Arief and Devi Pebrina},
    title = {Effect of the Amount of Carbon in the Fe3O4@ZnO-C Nanocomposites on Its Structure and Magnetic Properties},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {25},
    number = {10},
    year = {2022},
    keywords = {Fe3O4@ZnO nanocomposite; coprecipitation; magnetic properties; carbons},
    abstract = {Synthesis and characterization of structure magnetic properties of Fe 3 O 4 @ZnO- C nanocomposite have been done through the precipitation method. This study aimed to discover the effect of concentrations/thickness of carbon layer on crystal structure and magnetic properties of Fe 3 O 4 @ZnO-C nanocomposites. Fe 3 O 4  and Fe 3 O 4 @ZnO were the samples used in the study, and variations in the amount of carbon were 0.2, 0.1, and 0.05 g. Nanocomposites were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and vibrating sample magnetometer (VSM). Based on the results of XRD, it has been found that the crystal structure for Fe 3 O 4  was cubic, while ZnO was hexagonal wurtzite. The addition of carbons to Fe 3 O 4 @ZnO caused a broadening of the diffraction peaks and a decrease in the degree of crystallinity. The bonds formed on Fe 3 O 4 @ZnO-C nanocomposites, i.e. Fe-O bonds indicated the formation of Fe 3 O 4 , Zn-O bonds showed the formation of ZnO and C-O, C-H, and O-H bonds revealed the presence of a carbon layer originated from glucose. The VSM results showed that the magnetic saturation decreased with increasing carbon mass. Overall, the carbon-coated nanocomposite material with a carbon mass variation of 0.2, 0.1, and 0.05 g showed superparamagnetic properties with a magnetic saturation of 18.23 emu/g, 19.33 emu/g and 22.05 emu/g, while for the coercive field of 92.29 Oe, 92.90 Oe and 89.60 Oe, respectively. Based on these characterization results, Fe 3 O 4 @ZnO-C nanocomposite materials can potentially be developed as biomedical materials, such as the materials for photothermal therapy for cancer cells.},
   issn = {2597-9914},   pages = {362--367}  doi = {10.14710/jksa.25.10.362-367},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/49246}
}

Citation Format:

Abstract

Synthesis and characterization of structure magnetic properties of Fe₃O₄@ZnO- C nanocomposite have been done through the precipitation method. This study aimed to discover the effect of concentrations/thickness of carbon layer on crystal structure and magnetic properties of Fe₃O₄@ZnO-C nanocomposites. Fe₃O₄ and Fe₃O₄@ZnO were the samples used in the study, and variations in the amount of carbon were 0.2, 0.1, and 0.05 g. Nanocomposites were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and vibrating sample magnetometer (VSM). Based on the results of XRD, it has been found that the crystal structure for Fe₃O₄was cubic, while ZnO was hexagonal wurtzite. The addition of carbons to Fe₃O₄@ZnO caused a broadening of the diffraction peaks and a decrease in the degree of crystallinity. The bonds formed on Fe₃O₄@ZnO-C nanocomposites, i.e. Fe-O bonds indicated the formation of Fe₃O₄, Zn-O bonds showed the formation of ZnO and C-O, C-H, and O-H bonds revealed the presence of a carbon layer originated from glucose. The VSM results showed that the magnetic saturation decreased with increasing carbon mass. Overall, the carbon-coated nanocomposite material with a carbon mass variation of 0.2, 0.1, and 0.05 g showed superparamagnetic properties with a magnetic saturation of 18.23 emu/g, 19.33 emu/g and 22.05 emu/g, while for the coercive field of 92.29 Oe, 92.90 Oe and 89.60 Oe, respectively. Based on these characterization results, Fe₃O₄@ZnO-C nanocomposite materials can potentially be developed as biomedical materials, such as the materials for photothermal therapy for cancer cells.

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Keywords: Fe3O4@ZnO nanocomposite; coprecipitation; magnetic properties; carbons

Funding: Universitas Andalas

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Section: Research Articles

Language : EN

In Vol 25, No 10 (2022): Volume 25 Issue 10 Year 2022

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