DOI: https://doi.org/10.14710/jksa.25.10.362-367

Effect of the Amount of Carbon in the Fe3O4@ZnO-C Nanocomposites on Its Structure and Magnetic Properties

1Department of Physics, Faculty of Sciences and Mathematics, Andalas University, Padang, Indonesia

2Department of Chemistry, Faculty of Sciences and Mathematics, Andalas University, Padang, Indonesia

Received: 28 Sep 2022; Revised: 23 Nov 2022; Accepted: 23 Dec 2022; Published: 25 Dec 2022.
Open Access Copyright 2022 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Synthesis and characterization of structure magnetic properties of Fe3O4@ZnO- C nanocomposite have been done through the precipitation method. This study aimed to discover the effect of concentrations/thickness of carbon layer on crystal structure and magnetic properties of Fe3O4@ZnO-C nanocomposites. Fe3O4 and Fe3O4@ZnO were the samples used in the study, and variations in the amount of carbon were 0.2, 0.1, and 0.05 g. Nanocomposites were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and vibrating sample magnetometer (VSM). Based on the results of XRD, it has been found that the crystal structure for Fe3O4 was cubic, while ZnO was hexagonal wurtzite. The addition of carbons to Fe3O4@ZnO caused a broadening of the diffraction peaks and a decrease in the degree of crystallinity. The bonds formed on Fe3O4@ZnO-C nanocomposites, i.e. Fe-O bonds indicated the formation of Fe3O4, Zn-O bonds showed the formation of ZnO and C-O, C-H, and O-H bonds revealed the presence of a carbon layer originated from glucose. The VSM results showed that the magnetic saturation decreased with increasing carbon mass. Overall, the carbon-coated nanocomposite material with a carbon mass variation of 0.2, 0.1, and 0.05 g showed superparamagnetic properties with a magnetic saturation of 18.23 emu/g, 19.33 emu/g and 22.05 emu/g, while for the coercive field of 92.29 Oe, 92.90 Oe and 89.60 Oe, respectively. Based on these characterization results, Fe3O4@ZnO-C nanocomposite materials can potentially be developed as biomedical materials, such as the materials for photothermal therapy for cancer cells.
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Keywords: Fe3O4@ZnO nanocomposite; coprecipitation; magnetic properties; carbons
Funding: Universitas Andalas

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Section: Research Articles
Language : EN
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  3. Ganeshlenin Kandasamy, Dipak Maity, Recent advances in superparamagnetic iron oxide nanoparticles (SPIONs) for in vitro and in vivo cancer nanotheranostics, International Journal of Pharmaceutics, 496, 2, (2015), 191-218 https://doi.org/10.1016/j.ijpharm.2015.10.058
  4. Juan Pellico, Connor M. Ellis, Jason J. Davis, Nanoparticle-based paramagnetic contrast agents for magnetic resonance imaging, Contrast Media & Molecular Imaging, 2019, 1845637, (2019), https://doi.org/10.1155/2019/1845637
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  6. Xinyu Zhao, Qi Yu, Jun Yuan, Nitish V. Thakor, Mei Chee Tan, Biodegradable rare earth fluorochloride nanocrystals for phototheranostics, RSC Advances, 10, 26, (2020), 15387-15393 https://doi.org/10.1039/D0RA00760A
  7. V. Madhubala, T. Kalaivani, Phyto and hydrothermal synthesis of Fe3O4@ZnO core-shell nanoparticles using Azadirachta indica and its cytotoxicity studies, Applied Surface Science, 449, (2018), 584-590 https://doi.org/10.1016/j.apsusc.2017.12.105
  8. Jagriti Gupta, P. A. Hassan, K. C. Barick, Core-shell Fe3O4@ ZnO nanoparticles for magnetic hyperthermia and bio-imaging applications, AIP Advances, 11, 2, (2021), 025207 https://doi.org/10.1063/9.0000135
  9. Xiaoli Liu, Hui Jiang, Jing Ye, Chunqiu Zhao, Shengping Gao, Changyu Wu, Changhui Li, Jincheng Li, Xuemei Wang, Nitrogen‐doped carbon quantum dot stabilized magnetic iron oxide nanoprobe for fluorescence, magnetic resonance, and computed tomography triple‐modal in vivo bioimaging, Advanced Functional Materials, 26, 47, (2016), 8694-8706 https://doi.org/10.1002/adfm.201603084
  10. Roberto Gonzalez-Rodriguez, Elizabeth Campbell, Anton Naumov, Multifunctional graphene oxide/iron oxide nanoparticles for magnetic targeted drug delivery dual magnetic resonance/fluorescence imaging and cancer sensing, PLoS ONE, 14, 6, (2019), e0217072 https://doi.org/10.1371/journal.pone.0217072
  11. Ilana Perelshtein, Nina Perkas, Shai Rahimipour, Aharon Gedanken, Bifunctional Carbon Dots—Magnetic and Fluorescent Hybrid Nanoparticles for Diagnostic Applications, Nanomaterials, 10, 7, (2020), 1384 https://doi.org/10.3390/nano10071384
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  14. Yong Hu, Ruizhi Wang, Shige Wang, Ling Ding, Jingchao Li, Yu Luo, Xiaolin Wang, Mingwu Shen, Xiangyang Shi, Multifunctional Fe3O4@ Au core/shell nanostars: a unique platform for multimode imaging and photothermal therapy of tumors, Scientific Reports, 6, 1, (2016), 1-12 https://doi.org/10.1038/srep28325
  15. Vu Minh Thanh, Nguyen Thi Huong, Dao The Nam, Nguyen Dinh Tien Dung, Minh-Tri Nguyen-Le, Synthesis of Ternary Fe3O4/ZnO/Chitosan Magnetic Nanoparticles via an Ultrasound-Assisted Coprecipitation Process for Antibacterial Applications, Journal of Nanomaterials, 2020, 8875471, (2020), https://doi.org/10.1155/2020/8875471
  16. Alexey Maximenko, Joanna Depciuch, Natalia Łopuszyńska, Malgorzata Stec, Żaneta Światkowska-Warkocka, Vadim Bayev, Piotr M. Zieliński, Jaroslaw Baran, Julia Fedotova, Władysław P. Węglarz, Fe3O4@SiO2@Au nanoparticles for MRI-guided chemo/NIR photothermal therapy of cancer cells, RSC Advances, 10, 44, (2020), 26508-26520 https://doi.org/10.1039/D0RA03699D
  17. M. Reaz, Ariful Haque, D. M. Cornelison, A. Wanekaya, R. Delong, K. Ghosh, Magneto-luminescent zinc/iron oxide core-shell nanoparticles with tunable magnetic properties, Physica E: Low-dimensional Systems and Nanostructures, 123, (2020), 114090 https://doi.org/10.1016/j.physe.2020.114090
  18. Sadang Husain, Suryajaya Suryajaya, Ninis Hadi Haryanti, Tetti Novalina Manik, Rodiansono Rodiansono, Sepfina Monica Hutasoit, Agus Riyanto, Sudarningsih Sudarningsih, Potensi Nanokomposit Fe3O4@C dari Bijih Besi Sebagai Pendeteksi Kadar Glukosa, Positron, 9, 2, (2019), 44-52
  19. Syamsul Bahtiar, Ahmad Taufiq, Sunaryono Sunaryono, Preparasi dan Karakteristik Struktur Nanokomposit Fe3O4/ZnO dengan Menggunakan Metode Kopresipitasi, Seminar Nasional Fisika dan Pembelajarannya, 2017
  20. Mohamed L. Salem, Ali Gemeay, Soha Gomaa, Maha A. Aldubayan, Lobna Assy, Superparamagnetic graphene oxide/magnetite nanocomposite delivery system for doxorubicin-induced distinguished tumor cell cycle arrest and apoptosis, Journal of Nanoparticle Research, 22, 8, (2020), 1-12 https://doi.org/10.1007/s11051-020-04932-5
  21. Z. Sabouri, S. Labbaf, F. Karimzadeh, A. Baharlou-Houreh, T. V. McFarlane, M. H. Nasr Esfahani, Fe3O4/bioactive glass nanostructure: a promising therapeutic platform for osteosarcoma treatment, Biomedical Materials, 16, 3, (2021), 035016 https://doi.org/10.1088/1748-605X/aba7d5

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