Performance of Various Organic Solvents as Reaction Media in Plant Oil Lipolysis with Plant Lipase

License URL: http://creativecommons.org/licenses/by-nc-sa/4.0
Fatty acids are intermediate substances in synthesis of oleochemical products. Enzymatic technology of fatty acids production (also known as lipolysis) is now developing as potential substitution for the conventional production of fatty acid, i.e. thermal hydrolysis of triglyceride. It offers more economical process condition, low energy consumption, and minimal product degradation compared to the conventional process. This research aims to evaluate performance of various organic solvents as reaction media in lipolysis with plant latex lipase. Organic solvents observed were chloroform, n-hexane, diethyl ether, benzene, acetone, ethanol, methanol, n-heptane, and isooctane. Analysis of each organic solvent effect on lipolysis was described based on solvents properties. Conversion of lipolysis with organic solvents is 0,10-1,25 times fold compared to conversion of non-solvent lipolysis. We suggest that dielectric constant and viscosity are the two main organic solvent properties affecting lipase performance in lipolysis. Overall, n-hexane, n-heptane, and isooctane are recommended to be used as reaction media in lipolysis with plant lipase because their effects to degree of lipolysis are positive.
Keywords: lipolysis; lipase; organic solvent; frangipani
Article Metrics:
Last update: 2021-03-01 14:43:36
Last update: 2021-03-01 14:43:37
License URL: http://creativecommons.org/licenses/by-nc-sa/4.0
The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Reaktor journal and Department of Chemical Engineering Diponegoro University as the journal publisher. Copyright encompasses exclusive rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any form or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc., will be allowed only with a written permission from Reaktor journal and Department of Chemical Engineering Diponegoro University.