skip to main content

Adsorpsi Alkil Benzena Sulfonat Menggunakan Zeolit Termodifikasi Cetyltrimethylammonium

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 1 Apr 2017.
Open Access Copyright 2017 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0/.

Citation Format:
Abstract
Dalam penelitian ini dilakukan modifikasi zeolit alam teraktivasi NH4Cl (H-Zeolit) dengan surfaktan CTAB (Cetyltrimethylammonium Bromide) berbagai konsentrasi yaitu sebesar 0,25 mM (ZMS-1), 1 mM (ZMS-2), dan 100 mM (ZMS-3) sebagai adsorben senyawa ABS (Alkil Benzena Sulfonat). Karakterisasi dilakukan terhadap H-Zeolit dan ZMS menggunakan spektrofotometer FTIR. Parameter utama dalam penelitian ini adalah variasi konsentrasi ABS (50, 75, dan 100 ppm) dan waktu kontak (15, 30, 45, 60, 75, dan 90 menit). Konsentrasi ABS yang teradsorpsi dianalisis dengan spektrofotometer UV-Vis menggunakan metode MBAS (Methylene Blue Active Substance). Hasil spektra FTIR zeolit alam termodifikasi surfaktan (ZMS) menunjukkan puncak pada bilangan gelombang 2931,80 cm-1; 2854,65 cm-1 dan 1404,18 cm-1  yang mengindikasikan keberadaan gugus CTAB pada zeolit. Konsentrasi maksimum dan waktu optimum ABS yang dapat dijerap oleh per 0,1 gram ZMS adalah 50 ppm dalam 25 mL pada waktu 60 menit dengan persen adsorpsi sebesar 84,04% untuk H-Zeolit ; 96,42% untuk ZMS-1; 96,48% untuk ZMS-2; dan 97,29% untuk ZMS-3. Performa ZMS cenderung meningkat dengan konsentrasi CTAB pada zeolit.
Fulltext View|Download
Keywords: ZMS (Zeolit Modifikasi Surfaktan); Adsorpsi; Alkil Benzena Sulfonat

Article Metrics:

  1. Roberto Leyva-Ramos, Effect of temperature and ph on the adsorption of an anionic detergent on activated carbon, Journal of Chemical Technology & Biotechnology, 45, 3, (1989) 231-240 10.1002/jctb.280450308
  2. Silvio R. Taffarel, Jorge Rubio, Adsorption of sodium dodecyl benzene sulfonate from aqueous solution using a modified natural zeolite with CTAB, Minerals Engineering, 23, 10, (2010) 771-779 http://dx.doi.org/10.1016/j.mineng.2010.05.018
  3. Zhuo Guan, Xiang-Yu Tang, Taku Nishimura, Yu-Ming Huang, Brian J. Reid, Adsorption of linear alkylbenzene sulfonates on carboxyl modified multi-walled carbon nanotubes, Journal of Hazardous Materials, 322, (2017) 205-214 http://dx.doi.org/10.1016/j.jhazmat.2016.02.067
  4. Maulidah, Studi adsorpsi ABS (Alkyl Benzene Sulphonate) dari limbah rumah tangga Desa Ngadirgo menggunakan arang tempurung kelapa (coconut shells), in: Jurusan Kimia, Universitas Islam Negeri Walisongo, Semarang, 2015
  5. Selli Renata Sari, Kajian Adsorpsi Linear Alkilbenzena Sulfonat (Las) Menggunakan Magnetit, in: Jurusan Kimia, Universitas Negeri Semarang, Semarang, 2015
  6. Housheng Xia, Chun-Hui Zhou, Dongshen Tong, Junjun Chen, Weihua Yu, Shaomin Liu, Preparation and catalysis in epoxidation of allyl chloride of zeolitic titanosilicate-1/smectitic clay minerals, Applied Clay Science, 53, 2, (2011) 279-287 http://dx.doi.org/10.1016/j.clay.2011.04.014
  7. Di Zhang, Chun-Hui Zhou, Chun-Xiang Lin, Dong-Shen Tong, Wei-Hua Yu, Synthesis of clay minerals, Applied Clay Science, 50, 1, (2010) 1-11 http://dx.doi.org/10.1016/j.clay.2010.06.019
  8. Chun Hui Zhou, An overview on strategies towards clay-based designer catalysts for green and sustainable catalysis, Applied Clay Science, 53, 2, (2011) 87-96 http://dx.doi.org/10.1016/j.clay.2011.04.016
  9. Sriatun, Dimas Buntarto, Adi Darmawan, Pengaruh Penambahan Surfaktan Hexadecyltrimethylammonium (HDTMA) pada Zeolit Alam Terdealuminasi terhadap Kemampuan Mengadsorpsi Fenol, Jurnal Kimia Sains Dan Aplikasi, 11, 1, (2008) 20-24
  10. Huijuan Wei, Sujuan Xie, Kefeng Liu, Wenjie Xin, Xiujie Li, Shanhe Liu, Shunming Gu, Shenglin Liu, Longya Xu, CTAB modification of MCM-49 zeolite containing HMI and its acylation of anisole, Chinese Journal of Catalysis, 36, 10, (2015) 1766-1776 http://dx.doi.org/10.1016/S1872-2067(15)60887-7
  11. Jailson A. Araújo, Fernanda T. Cruz, Ivana H. Cruz, Dilson Cardoso, Encapsulation of polymers in CTA-MCM-41 via microemulsion, Microporous and Mesoporous Materials, 180, (2013) 14-21 http://dx.doi.org/10.1016/j.micromeso.2013.05.010
  12. Ahmet Gürses, Kübra Güneş, Ferda Mindivan, Mehtap Ejder Korucu, Metin Açıkyıldız, Çetin Doğar, The investigation of electrokinetic behaviour of micro-particles produced by CTA+ ions and Na-montmorillonite, Applied Surface Science, 318, (2014) 79-84 http://dx.doi.org/10.1016/j.apsusc.2014.01.036
  13. Pratap Chutia, Shigeru Kato, Toshinori Kojima, Shigeo Satokawa, Adsorption of As(V) on surfactant-modified natural zeolites, Journal of Hazardous Materials, 162, 1, (2009) 204-211 http://dx.doi.org/10.1016/j.jhazmat.2008.05.024
  14. Dita Setiawati, Lia Destiarti, Nelly Wahyuni, Pemanfaatan Zeolit A Termodifikasi Hexadecyltrimethylammonium (HDTMA) Sebagai Adsorben Fosfat, Jurnal Kimia Khatulistiwa, 4, 2, (2015)
  15. He Hongping, Frost L. Ray, Zhu Jianxi, Infrared study of HDTMA+ intercalated montmorillonite, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60, 12, (2004) 2853-2859 http://dx.doi.org/10.1016/j.saa.2003.09.028
  16. Zhaohui Li, Wei-Teh Jiang, Hanlie Hong, An FTIR investigation of hexadecyltrimethylammonium intercalation into rectorite, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71, 4, (2008) 1525-1534 http://dx.doi.org/10.1016/j.saa.2008.05.015

Last update:

  1. Synthesis of Chitosan-Alginate Beads and Its Application for Alkyl Benzene Sulfonates (ABS) Adsorption

    N P S Ayuni, I N Sukarta, P A Wulandari. IOP Conference Series: Materials Science and Engineering, 1115 (1), 2021. doi: 10.1088/1757-899X/1115/1/012077
  2. The influence of high energy milling to the adsorption of Cd(II) and Zn(II) ions on activated zeolite

    P Pardoyo, Y Astuti, G Herinnayah, S Suhartana, P J Wibawa. Journal of Physics: Conference Series, 1524 (1), 2020. doi: 10.1088/1742-6596/1524/1/012080
  3. Polyaniline Modified Natural Zeolite as Adsorbent for Chromium(III) Metal Ion

    Rina Nurianingsih, Sriatun Sriatun, Adi Darmawan. Jurnal Kimia Sains dan Aplikasi, 22 (6), 2019. doi: 10.14710/jksa.22.6.292-298

Last update: 2024-07-23 13:26:33

No citation recorded.