Decolorization of Artificial Waste Remazol Black B using Electrogenerated Reactive Spesies

Didik Setiyo Widodo; Linda Suyati; Gunawan Gunawan; Abdul Haris

doi:10.14710/jis.%v.%i.%Y.81-89

DOI: https://doi.org/10.14710/jis.%25v.%25i.%25Y.81-89

Decolorization of Artificial Waste Remazol Black B using Electrogenerated Reactive Spesies

Didik Setiyo Widodo

, Linda Suyati

, Gunawan Gunawan

, Abdul Haris

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 31 Jan 2018.

BibTex Citation Data :

@article{JKSA17944,
    author = {Didik Widodo and Linda Suyati and Gunawan Gunawan and Abdul Haris},
    title = {Decolorization of Artificial Waste Remazol Black B using Electrogenerated Reactive Spesies},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {21},
    number = {1},
    year = {2018},
    keywords = {Electrolysis, decolorization, remazol black B (reactive balck 5), electrogenerated reactive species},
    abstract = {Electrolysis method (electrodecolorization) coupled with  ● OH radicals and chlorine generation has been performed in decolorizing of artificial waste of remazol black B (reactive black 5). The electrodecolorization as one of advanced oxidation process (AOP) shows its determinant potential in overcoming environmental problems due to dye contained waste as well as its green in desaign and efficiency. The project aim was to decolorize the RBB solution completely and effectively. The mission was completed by designing decolorizing reactor working with electrolytic system in tandem with electrogeneration of reactive species from HCl and NaCl electrolyte. Lead oxide, PbO 2  was choosen as anode. The efficiency of decolorization process was comparated with those of Na 2 SO 4  as electrolyte. Data of UV-Vis spectrometry, atomic absorption spectrophotometry and COD showed that the performance of electrolysis design was significantly enhanced with the reactive species generation process. Electrolysis of 100 mL sample of 200 mgL -1  RBB with reactive species generation was rearched almost two-fold faster in decolorizing the dye solution rather than in Na 2 SO 4  one. The design rearchs more than 99 % in decoloriziation percentages, reducing COD more than 96 % indicating the potential and effectiveness of electroremediation process.},
   issn = {2597-9914},   pages = {29--33}  doi = {10.14710/jis.%v.%i.%Y.81-89},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/17944}
}

Citation Format:

Abstract

Electrolysis method (electrodecolorization) coupled with ^●OH radicals and chlorine generation has been performed in decolorizing of artificial waste of remazol black B (reactive black 5). The electrodecolorization as one of advanced oxidation process (AOP) shows its determinant potential in overcoming environmental problems due to dye contained waste as well as its green in desaign and efficiency. The project aim was to decolorize the RBB solution completely and effectively. The mission was completed by designing decolorizing reactor working with electrolytic system in tandem with electrogeneration of reactive species from HCl and NaCl electrolyte. Lead oxide, PbO₂ was choosen as anode. The efficiency of decolorization process was comparated with those of Na₂SO₄ as electrolyte. Data of UV-Vis spectrometry, atomic absorption spectrophotometry and COD showed that the performance of electrolysis design was significantly enhanced with the reactive species generation process. Electrolysis of 100 mL sample of 200 mgL^-1 RBB with reactive species generation was rearched almost two-fold faster in decolorizing the dye solution rather than in Na₂SO₄ one. The design rearchs more than 99 % in decoloriziation percentages, reducing COD more than 96 % indicating the potential and effectiveness of electroremediation process.

Fulltext View|Download

Keywords: Electrolysis, decolorization, remazol black B (reactive balck 5), electrogenerated reactive species

Article Metrics:

Article Info

Section: Research Articles

Language : EN

In Vol 21, No 1 (2018): Volume 21 Issue 1 Year 2018

Recent articles

Improvement of Bioactivity with Nanoparticle Fabrication: Cytotoxic Test of Ethanol, N-Hexane and Ethyl Acetate Extract from Red Galangal Rhizome (Alpinia purpurata (Vieill.) K. Schum) in Bulk and Nanoparticle size using BSLT Method Antioxidant from Turmeric Fermentation Products (Curcuma longa) by Aspergillus Oryzae Antibacterial Activity of Cinnamic Acid - Chitosan Encapsulation More recent articles

Most cited articles

Polimerisasi Eugenol Dengan Katalis Asam Sulfat Pekat Dimerisasi Metilisoeugenol dengan Katalis HCl Sintesis Lempung Terpilar Titania Biolubrication Synthesis Made from Used Cooking Oil and Bayah Natural Zeolite Catalyst Studi Filogeni dan Uji Potensi Bioremediasi serta Enzim Termostabil Ekstraseluler Isolat Geobacillus sp. dari Sumber Air Panas Gedong Songo More cited articles

Titik Darmawanti, Suhartana Suhartana, Didik Setiyo Widodo, Pengolahan Limbah Cair Industri Batik dengan Metoda Elektrokoagulasi Menggunakan Besi Bekas Sebagai Elektroda, Jurnal Kimia Sains dan Aplikasi, 13, 1, (2010) 18-24
Sulistias Mustika, Abdul Haris, Nor Basid Adiwibawa Prasetya, Kajian Metode Elektrofotokatalisis, Elektrolisis dan Fotokatalisis pada Dekolorisasi Larutan Zat Warna Remazol Black B yang Mengandung Ion Logam Cu2+, Jurnal Kimia Sains dan Aplikasi, 16, 1, (2013) 17-22
Arthias Cita Febriyani, Rum Hastuti, Abdul Haris, Kajian Metode Elektrofotokatalisis, Elektrolisis dan Fotokatalisis pada Dekolorisasi Larutan Zat Warna Remazol Brilliant Orange 3R yang Mengandung Ion Logam Cu2+, Jurnal Kimia Sains dan Aplikasi, 15, 1, (2012) 7-12
MS Morsi, AA Al-Sarawy, WA Shehab El-Dein, Electrochemical degradation of some organic dyes by electrochemical oxidation on a Pb/PbO2 electrode, Desalination and Water Treatment, 26, 1-3, (2011) 301-308
Vinod Kumar Gupta, Rajeev Jain, Shaily Varshney, Electrochemical removal of the hazardous dye Reactofix Red 3 BFN from industrial effluents, Journal of Colloid and Interface Science, 312, 2, (2007) 292-296 http://dx.doi.org/10.1016/j.jcis.2007.03.054
Haiming Zou, Yan Wang, Azo dyes wastewater treatment and simultaneous electricity generation in a novel process of electrolysis cell combined with microbial fuel cell, Bioresource Technology, 235, (2017) 167-175 http://dx.doi.org/10.1016/j.biortech.2017.03.093
P D Riyanto, Elektrokimia dan aplikasinya, Graha Ilmu, Yogyakarta, 2013
Dayanne Chianca de Moura, Marco Antonio Quiroz, Djalma Ribeiro da Silva, Ricardo Salazar, Carlos Alberto Martínez-Huitle, Electrochemical degradation of Acid Blue 113 dye using TiO2-nanotubes decorated with PbO2 as anode, Environmental Nanotechnology, Monitoring & Management, 5, (2016) 13-20 http://dx.doi.org/10.1016/j.enmm.2015.11.001
Seong-Hoon Hong, Byung-Hyuk Kwon, Jea-Keun Lee, Il-Kyu Kim, Degradation of 2-chlorophenol by Fenton and photo-Fenton processes, Korean Journal of Chemical Engineering, 25, 1, (2008) 46-52 http://dx.doi.org/10.1007/s11814-008-0008-3
GP Gallios, I Voinovschi, A Voulgaropoulos, Effect of electrolytes on the electrochemical oxidation of synthetic dyes, in: Water Treatment Technologies for the Removal of High-Toxicity Pollutants, Springer, 2009, pp. 169-176
Abdoulaye Thiam, Enric Brillas, Francesc Centellas, Pere L. Cabot, Ignasi Sirés, Electrochemical reactivity of Ponceau 4R (food additive E124) in different electrolytes and batch cells, Electrochimica Acta, 173, (2015) 523-533 http://dx.doi.org/10.1016/j.electacta.2015.05.085
I. M. Banat, P. Nigam, G. McMullan, R. Marchant, D. Singh, The isolation of thermophilic bacterial cultures capable of textile dyes decolorization, Environment International, 23, 4, (1997) 547-551 http://dx.doi.org/10.1016/S0160-4120(97)00061-5
Nasser Abu Ghalwa, Mazen Hamada, Hazem M. Abu Shawish, Omar Shubair, Electrochemical degradation of linuron in aqueous solution using Pb/PbO2 and C/PbO2 electrodes, Arabian Journal of Chemistry, 9, (2016) S821-S828 http://dx.doi.org/10.1016/j.arabjc.2011.08.006
RB Alencar de Souza, LA Martins Ruotolo, Phenol electrooxidation in different supporting electrolytes using boron-doped diamond anodes, International Journal of Electrochemical Science, 8, 1, (2013) 643-657

Last update:

Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor
Muhamad Abduh Hasibuan, Didik Setiyo Widodo, Retno Ariadi Lusiana. Jurnal Kimia Sains dan Aplikasi, 21 (2), 2018. doi: 10.14710/jksa.21.2.59-63

Last update: 2024-12-26 22:30:42

No citation recorded.

As an article writer, the author has the right to use their articles for various purposes, including use by institutions that employ authors or institutions that provide funding for research. Author rights are granted without special permission.

Author who publishes a paper at JKSA has the broad right to use their work for teaching and scientific purposes without the need to ask permission, including: used for (i) teaching in the author's class or institution, (ii) presentation at meetings or conferences and distributing copies to participants ; (iii) training conducted by the author or author's institution; (iv) distribution to colleagues for research use; (v) use in the compilation of subsequent authors' works; (vi) inclusion in a thesis or dissertation; (vi) reuse of part of the article in another work (with citation); (vii) preparation of derivative works (with citation); (viii) voluntary posting on open websites operated by authors or author institutions for scientific purposes (follow the CC BY-SA License).

Authors and readers can copy and redistribute material in any media or format, and mix, modify, and build material for any purpose but they must provide appropriate credit (provide article citation or content), providing links to the license, and indicate if there are changes.

The authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations.

Reproduce any part of this journal, its storage in the database or its transmission by all forms or media is permitted does not need for written permission from JKSA. However, it should be cited as an honor in academic manners

JKSA and the Chemistry Department of Diponegoro University and the Editor make every effort to ensure that there are no data, opinions, or false or misleading statements published in JKSA. However, the content of the article is the sole and exclusive responsibility of each author.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should be signed originally and send to the Editor in the form of printed letters, scanned documents sent via email or fax.

Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id