Decolorization of Artificial Waste Remazol Black B using Electrogenerated Reactive Spesies

Didik Setiyo Widodo; Linda Suyati; Gunawan Gunawan; Abdul Haris

doi:10.14710/jis.%v.%i.%Y.81-89

DOI: https://doi.org/10.14710/jis.%25v.%25i.%25Y.81-89

Decolorization of Artificial Waste Remazol Black B using Electrogenerated Reactive Spesies

Didik Setiyo Widodo

, Linda Suyati

, Gunawan Gunawan

, Abdul Haris

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 31 Jan 2018.

BibTex Citation Data :

@article{JKSA17944,
    author = {Didik Widodo and Linda Suyati and Gunawan Gunawan and Abdul Haris},
    title = {Decolorization of Artificial Waste Remazol Black B using Electrogenerated Reactive Spesies},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {21},
    number = {1},
    year = {2018},
    keywords = {Electrolysis, decolorization, remazol black B (reactive balck 5), electrogenerated reactive species},
    abstract = {Electrolysis method (electrodecolorization) coupled with  ● OH radicals and chlorine generation has been performed in decolorizing of artificial waste of remazol black B (reactive black 5). The electrodecolorization as one of advanced oxidation process (AOP) shows its determinant potential in overcoming environmental problems due to dye contained waste as well as its green in desaign and efficiency. The project aim was to decolorize the RBB solution completely and effectively. The mission was completed by designing decolorizing reactor working with electrolytic system in tandem with electrogeneration of reactive species from HCl and NaCl electrolyte. Lead oxide, PbO 2  was choosen as anode. The efficiency of decolorization process was comparated with those of Na 2 SO 4  as electrolyte. Data of UV-Vis spectrometry, atomic absorption spectrophotometry and COD showed that the performance of electrolysis design was significantly enhanced with the reactive species generation process. Electrolysis of 100 mL sample of 200 mgL -1  RBB with reactive species generation was rearched almost two-fold faster in decolorizing the dye solution rather than in Na 2 SO 4  one. The design rearchs more than 99 % in decoloriziation percentages, reducing COD more than 96 % indicating the potential and effectiveness of electroremediation process.},
   issn = {2597-9914},   pages = {29--33}  doi = {10.14710/jis.%v.%i.%Y.81-89},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/17944}
}

Citation Format:

Abstract

Electrolysis method (electrodecolorization) coupled with ^●OH radicals and chlorine generation has been performed in decolorizing of artificial waste of remazol black B (reactive black 5). The electrodecolorization as one of advanced oxidation process (AOP) shows its determinant potential in overcoming environmental problems due to dye contained waste as well as its green in desaign and efficiency. The project aim was to decolorize the RBB solution completely and effectively. The mission was completed by designing decolorizing reactor working with electrolytic system in tandem with electrogeneration of reactive species from HCl and NaCl electrolyte. Lead oxide, PbO₂ was choosen as anode. The efficiency of decolorization process was comparated with those of Na₂SO₄ as electrolyte. Data of UV-Vis spectrometry, atomic absorption spectrophotometry and COD showed that the performance of electrolysis design was significantly enhanced with the reactive species generation process. Electrolysis of 100 mL sample of 200 mgL^-1 RBB with reactive species generation was rearched almost two-fold faster in decolorizing the dye solution rather than in Na₂SO₄ one. The design rearchs more than 99 % in decoloriziation percentages, reducing COD more than 96 % indicating the potential and effectiveness of electroremediation process.

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Keywords: Electrolysis, decolorization, remazol black B (reactive balck 5), electrogenerated reactive species

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Section: Research Articles

Language : EN

In Vol 21, No 1 (2018): Volume 21 Issue 1 Year 2018

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Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor
Muhamad Abduh Hasibuan, Didik Setiyo Widodo, Retno Ariadi Lusiana. Jurnal Kimia Sains dan Aplikasi, 21 (2), 2018. doi: 10.14710/jksa.21.2.59-63

Last update: 2024-04-20 01:19:10

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