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Decolorization of Artificial Waste Remazol Black B using Electrogenerated Reactive Spesies

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 31 Jan 2018.
Open Access Copyright 2018 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Electrolysis method (electrodecolorization) coupled with OH radicals and chlorine generation has been performed in decolorizing of artificial waste of remazol black B (reactive black 5). The electrodecolorization as one of advanced oxidation process (AOP) shows its determinant potential in overcoming environmental problems due to dye contained waste as well as its green in desaign and efficiency. The project aim was to decolorize the RBB solution completely and effectively. The mission was completed by designing decolorizing reactor working with electrolytic system in tandem with electrogeneration of reactive species from HCl and NaCl electrolyte. Lead oxide, PbO2 was choosen as anode. The efficiency of decolorization process was comparated with those of Na2SO4 as electrolyte. Data of UV-Vis spectrometry, atomic absorption spectrophotometry and COD showed that the performance of electrolysis design was significantly enhanced with the reactive species generation process. Electrolysis of 100 mL sample of 200 mgL-1 RBB with reactive species generation was rearched almost two-fold faster in decolorizing the dye solution rather than in Na2SO4 one. The design rearchs more than 99 % in decoloriziation percentages, reducing COD more than 96 % indicating the potential and effectiveness of electroremediation process.
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Keywords: Electrolysis, decolorization, remazol black B (reactive balck 5), electrogenerated reactive species

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  2. Sulistias Mustika, Abdul Haris, Nor Basid Adiwibawa Prasetya, Kajian Metode Elektrofotokatalisis, Elektrolisis dan Fotokatalisis pada Dekolorisasi Larutan Zat Warna Remazol Black B yang Mengandung Ion Logam Cu2+, Jurnal Kimia Sains dan Aplikasi, 16, 1, (2013) 17-22
  3. Arthias Cita Febriyani, Rum Hastuti, Abdul Haris, Kajian Metode Elektrofotokatalisis, Elektrolisis dan Fotokatalisis pada Dekolorisasi Larutan Zat Warna Remazol Brilliant Orange 3R yang Mengandung Ion Logam Cu2+, Jurnal Kimia Sains dan Aplikasi, 15, 1, (2012) 7-12
  4. MS Morsi, AA Al-Sarawy, WA Shehab El-Dein, Electrochemical degradation of some organic dyes by electrochemical oxidation on a Pb/PbO2 electrode, Desalination and Water Treatment, 26, 1-3, (2011) 301-308
  5. Vinod Kumar Gupta, Rajeev Jain, Shaily Varshney, Electrochemical removal of the hazardous dye Reactofix Red 3 BFN from industrial effluents, Journal of Colloid and Interface Science, 312, 2, (2007) 292-296 http://dx.doi.org/10.1016/j.jcis.2007.03.054
  6. Haiming Zou, Yan Wang, Azo dyes wastewater treatment and simultaneous electricity generation in a novel process of electrolysis cell combined with microbial fuel cell, Bioresource Technology, 235, (2017) 167-175 http://dx.doi.org/10.1016/j.biortech.2017.03.093
  7. P D Riyanto, Elektrokimia dan aplikasinya, Graha Ilmu, Yogyakarta, 2013
  8. Dayanne Chianca de Moura, Marco Antonio Quiroz, Djalma Ribeiro da Silva, Ricardo Salazar, Carlos Alberto Martínez-Huitle, Electrochemical degradation of Acid Blue 113 dye using TiO2-nanotubes decorated with PbO2 as anode, Environmental Nanotechnology, Monitoring & Management, 5, (2016) 13-20 http://dx.doi.org/10.1016/j.enmm.2015.11.001
  9. Seong-Hoon Hong, Byung-Hyuk Kwon, Jea-Keun Lee, Il-Kyu Kim, Degradation of 2-chlorophenol by Fenton and photo-Fenton processes, Korean Journal of Chemical Engineering, 25, 1, (2008) 46-52 http://dx.doi.org/10.1007/s11814-008-0008-3
  10. GP Gallios, I Voinovschi, A Voulgaropoulos, Effect of electrolytes on the electrochemical oxidation of synthetic dyes, in: Water Treatment Technologies for the Removal of High-Toxicity Pollutants, Springer, 2009, pp. 169-176
  11. Abdoulaye Thiam, Enric Brillas, Francesc Centellas, Pere L. Cabot, Ignasi Sirés, Electrochemical reactivity of Ponceau 4R (food additive E124) in different electrolytes and batch cells, Electrochimica Acta, 173, (2015) 523-533 http://dx.doi.org/10.1016/j.electacta.2015.05.085
  12. I. M. Banat, P. Nigam, G. McMullan, R. Marchant, D. Singh, The isolation of thermophilic bacterial cultures capable of textile dyes decolorization, Environment International, 23, 4, (1997) 547-551 http://dx.doi.org/10.1016/S0160-4120(97)00061-5
  13. Nasser Abu Ghalwa, Mazen Hamada, Hazem M. Abu Shawish, Omar Shubair, Electrochemical degradation of linuron in aqueous solution using Pb/PbO2 and C/PbO2 electrodes, Arabian Journal of Chemistry, 9, (2016) S821-S828 http://dx.doi.org/10.1016/j.arabjc.2011.08.006
  14. RB Alencar de Souza, LA Martins Ruotolo, Phenol electrooxidation in different supporting electrolytes using boron-doped diamond anodes, International Journal of Electrochemical Science, 8, 1, (2013) 643-657

Last update:

  1. Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor

    Muhamad Abduh Hasibuan, Didik Setiyo Widodo, Retno Ariadi Lusiana. Jurnal Kimia Sains dan Aplikasi, 21 (2), 2018. doi: 10.14710/jksa.21.2.59-63

Last update: 2024-11-22 07:45:06

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