Pembuatan Katalis Pd-Ce/γ –Al2O3 dan Uji Aktivitas terhadap Oksidasi Metana

Ahmad Suseno; Triyono Triyono; Bambang Setiaji

doi:10.14710/jksa.2.3.104-111

DOI: https://doi.org/10.14710/jksa.2.3.104-111

Pembuatan Katalis Pd-Ce/γ –Al2O3 dan Uji Aktivitas terhadap Oksidasi Metana

Ahmad Suseno¹

, Triyono Triyono²

, Bambang Setiaji²

¹Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

²Chemistry Department, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Indonesia

Published: 31 Aug 1999.

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Abstract

Effects of Ce addition on Pt/γ - Al₂O₃ catalysts preparation and their catalytic activity on oxidation of methane have been investigated. In this study, the catalysts were prepared by impregnating chloride salt solution of palladium and sulphate salt of cerium on γ-AI₂O₃ support. Characterization of catalysts was conducted by gas sorption method to determine surface area, pore radius and pore volume. The test of catalytic activity on oxidation of methane was carried out in a flow reactor system at a temperature range from 350°C to 600°C. Products of reaction were analysed by non-dispersive IR spectroscopy. It was observed that the surface area, pore radius and pore volume decrease with the addition of cerium. The results of oxidation process showed that Pd-Ce/γ-Al₂O₃ catalyst can be used for oxidation of methane up to 90.62% conversion

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Keywords: cerium; oxidation of methane; gas sorption method

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Section: Research Articles

Language : EN

In Vol 2, No 3 (1999): Volume 2 Issue 3 Year 1999

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Campbell, l.M., 1988,Catalysis at Surfaces, Chapman and Hall, London
Taylor, K.C., 1984, Automobile Catalytic Converters, General Motors Research laboratories, Warren, Michigan, p. 138-144
Williamson, V.B., Summer, J.C. and Scaparo, J.A., 1992, Automotive Catalyst Strategies for Future Emission systems, Allied-Signal Automotive Catalyst Co, Tulsa, Oklahoma
Bell, A.T., 1987, Supports and Metal-Support Interaction, in Hegedus, L. L.(ed), Catalyst Design: Progress and Perspectives, John Wiley & Sons, Inc, New York
Harrison, B., Diwell, A.F. and Hallett, C., Promoting Platinum Metals by Ceria, Platinum Metal Rev., 1988, 32, 2
Nunan, J.G., Silver, R.G. and Bredley ,S.A., 1992, Effect of Ce on Performance and Physicochemical Properties of Pt-Containing Automotive Emission Control Catalysts , in Catalytic Control of Air Pollution, Crucq. A. (Eds), Elsevier: New York, p. 83-86
Anwar, C., Holisoh dan Witono ,H., 1996, Impregnasi dan Sifat Permukaan Katalis Ni-Mo/γ-Al2O3, Lembaran Publikasi Lemigas, Vol.30, no. 3, PPTM, Jakarta
Kirszensztejn, P., Foltynowicz, Z. and Wachowski.L., 1991, Peculiar Pore Structure of Coke Coating Formed on Pt-Sn/γ-Alumina Catalysts, lnd. Eng. Chem.Res, 30, 2276-2279
Mikhail, R.S. and Robens, E., 1983, Microstructure and Thermal Analysis of Solid Surface, John Wiley and Sons, New York
Lowell,S. and Shields, J.E., 1984, Powder Surface Area and Porosity , Second edition, Chapman and Hall, New York
Thomas, J.M. and Lambert, R.M., 1980, Characterisation of Catalysts, John Wiley & Sons Ltd, Chichester
Bahri,S., 1995, Pengaruh Kandungan Logam Pt dan Temperatur Kalsinasi dalam Pembuatan Katalisator Pt/γ-Alumina terhadap Aktifitas Katalitik Reaksi Dehidrogenasi Sikloheksana, Tesis Pasca sarjana UGM, Yogyakarta
Salim, A., 1995, Modifikasi Zeolit Alam sebagai Pengemban Platinum untuk Katalis Oksidasi Langsung n-Pentana, Tesis Pasca Sarjana UGM, Yogyakarta
Joharmawan, R., 1997, Pembuatan, Karakterisasi dan Uji Aktivitas Pt-Zeolit dan Pd-Zeolit sebagai Katalis Oksidasi Hidrokarbon Ringan, Tesis Pasca Sarjana UGM, Yogyakarta
Beltramini, J.N. and Datta, R., 1991, Coke Deposition on Naphtha Reforming Catalysts: Influence of The Hydrocarbon Feed, React. Kinet. Catal. Lett., Vol. 44, No.2, 345-348

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