Pembuatan Katalis Pd-Ce/γ –Al2O3 dan Uji Aktivitas terhadap Oksidasi Metana

Ahmad Suseno; Triyono Triyono; Bambang Setiaji

doi:10.14710/jksa.2.3.104-111

DOI: https://doi.org/10.14710/jksa.2.3.104-111

Pembuatan Katalis Pd-Ce/γ –Al2O3 dan Uji Aktivitas terhadap Oksidasi Metana

Ahmad Suseno¹

, Triyono Triyono²

, Bambang Setiaji²

¹Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

²Chemistry Department, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Indonesia

Published: 31 Aug 1999.

Citation Format:

Abstract

Effects of Ce addition on Pt/γ - Al₂O₃ catalysts preparation and their catalytic activity on oxidation of methane have been investigated. In this study, the catalysts were prepared by impregnating chloride salt solution of palladium and sulphate salt of cerium on γ-AI₂O₃ support. Characterization of catalysts was conducted by gas sorption method to determine surface area, pore radius and pore volume. The test of catalytic activity on oxidation of methane was carried out in a flow reactor system at a temperature range from 350°C to 600°C. Products of reaction were analysed by non-dispersive IR spectroscopy. It was observed that the surface area, pore radius and pore volume decrease with the addition of cerium. The results of oxidation process showed that Pd-Ce/γ-Al₂O₃ catalyst can be used for oxidation of methane up to 90.62% conversion

Fulltext View|Download

Keywords: cerium; oxidation of methane; gas sorption method

Article Metrics:

Article Info

Section: Research Articles

Language : EN

In Vol 2, No 3 (1999): Volume 2 Issue 3 Year 1999

Recent articles

Uji Pengaruh Aktivitas Ekstrak Daun Cempaka (Mickelia champaca. L) terhadap Pengendalian Jamur Phytophthora infestans Pembuatan Katalis Pd-Ce/γ –Al2O3 dan Uji Aktivitas terhadap Oksidasi Metana Studi Salinitas Air terhadap Penyerapan Logam Berat Merkuri oleh Ikan Mujair (Tilapia mosambicca) More recent articles

Most cited articles

Pengelolaan Alat Bahan dan Laboratorium Kimia Conversion of Wood Waste to be a Source of Alternative Liquid Fuel Using Low Temperature Pyrolysis Method Asam Anakardat dari Kulit Biji Jambu Mete (Anacardium Occidentale L) yang Mempunyai Aktivitas Sitotoksik Hidrorengkah Fraksi Berat Minyak Bumi Menggunakan Katalis Lempung Terpilar Aluminium Berpengemban Nikel Activity of Actinomycetes Isolated from Mangrove Segara Anakan Cilacap toward Methicillin-resistant Staphylococcus aureus (MRSA) More cited articles

Campbell, l.M., 1988,Catalysis at Surfaces, Chapman and Hall, London
Taylor, K.C., 1984, Automobile Catalytic Converters, General Motors Research laboratories, Warren, Michigan, p. 138-144
Williamson, V.B., Summer, J.C. and Scaparo, J.A., 1992, Automotive Catalyst Strategies for Future Emission systems, Allied-Signal Automotive Catalyst Co, Tulsa, Oklahoma
Bell, A.T., 1987, Supports and Metal-Support Interaction, in Hegedus, L. L.(ed), Catalyst Design: Progress and Perspectives, John Wiley & Sons, Inc, New York
Harrison, B., Diwell, A.F. and Hallett, C., Promoting Platinum Metals by Ceria, Platinum Metal Rev., 1988, 32, 2
Nunan, J.G., Silver, R.G. and Bredley ,S.A., 1992, Effect of Ce on Performance and Physicochemical Properties of Pt-Containing Automotive Emission Control Catalysts , in Catalytic Control of Air Pollution, Crucq. A. (Eds), Elsevier: New York, p. 83-86
Anwar, C., Holisoh dan Witono ,H., 1996, Impregnasi dan Sifat Permukaan Katalis Ni-Mo/γ-Al2O3, Lembaran Publikasi Lemigas, Vol.30, no. 3, PPTM, Jakarta
Kirszensztejn, P., Foltynowicz, Z. and Wachowski.L., 1991, Peculiar Pore Structure of Coke Coating Formed on Pt-Sn/γ-Alumina Catalysts, lnd. Eng. Chem.Res, 30, 2276-2279
Mikhail, R.S. and Robens, E., 1983, Microstructure and Thermal Analysis of Solid Surface, John Wiley and Sons, New York
Lowell,S. and Shields, J.E., 1984, Powder Surface Area and Porosity , Second edition, Chapman and Hall, New York
Thomas, J.M. and Lambert, R.M., 1980, Characterisation of Catalysts, John Wiley & Sons Ltd, Chichester
Bahri,S., 1995, Pengaruh Kandungan Logam Pt dan Temperatur Kalsinasi dalam Pembuatan Katalisator Pt/γ-Alumina terhadap Aktifitas Katalitik Reaksi Dehidrogenasi Sikloheksana, Tesis Pasca sarjana UGM, Yogyakarta
Salim, A., 1995, Modifikasi Zeolit Alam sebagai Pengemban Platinum untuk Katalis Oksidasi Langsung n-Pentana, Tesis Pasca Sarjana UGM, Yogyakarta
Joharmawan, R., 1997, Pembuatan, Karakterisasi dan Uji Aktivitas Pt-Zeolit dan Pd-Zeolit sebagai Katalis Oksidasi Hidrokarbon Ringan, Tesis Pasca Sarjana UGM, Yogyakarta
Beltramini, J.N. and Datta, R., 1991, Coke Deposition on Naphtha Reforming Catalysts: Influence of The Hydrocarbon Feed, React. Kinet. Catal. Lett., Vol. 44, No.2, 345-348

Last update:

No citation recorded.

Last update: 2024-11-22 03:13:48

No citation recorded.

As an article writer, the author has the right to use their articles for various purposes, including use by institutions that employ authors or institutions that provide funding for research. Author rights are granted without special permission.

Author who publishes a paper at JKSA has the broad right to use their work for teaching and scientific purposes without the need to ask permission, including: used for (i) teaching in the author's class or institution, (ii) presentation at meetings or conferences and distributing copies to participants ; (iii) training conducted by the author or author's institution; (iv) distribution to colleagues for research use; (v) use in the compilation of subsequent authors' works; (vi) inclusion in a thesis or dissertation; (vi) reuse of part of the article in another work (with citation); (vii) preparation of derivative works (with citation); (viii) voluntary posting on open websites operated by authors or author institutions for scientific purposes (follow the CC BY-SA License).

Authors and readers can copy and redistribute material in any media or format, and mix, modify, and build material for any purpose but they must provide appropriate credit (provide article citation or content), providing links to the license, and indicate if there are changes.

The authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations.

Reproduce any part of this journal, its storage in the database or its transmission by all forms or media is permitted does not need for written permission from JKSA. However, it should be cited as an honor in academic manners

JKSA and the Chemistry Department of Diponegoro University and the Editor make every effort to ensure that there are no data, opinions, or false or misleading statements published in JKSA. However, the content of the article is the sole and exclusive responsibility of each author.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should be signed originally and send to the Editor in the form of printed letters, scanned documents sent via email or fax.

Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id