Potential Oxidative Treatment Using Pb-PbO2 Electrode in Electrodecolorizing Batik Wastewater

Didik Setiyo Widodo; Rahmad Nuryanto; Abdul Haris; Prihastuti Santini Laksmi Dewi; Lutfia Apipah

doi:10.14710/jksa.21.3.118-123

DOI: https://doi.org/10.14710/jksa.21.3.118-123

Potential Oxidative Treatment Using Pb-PbO2 Electrode in Electrodecolorizing Batik Wastewater

Didik Setiyo Widodo

, Rahmad Nuryanto

, Abdul Haris

, Prihastuti Santini Laksmi Dewi, Lutfia Apipah

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Received: 6 Jul 2018; Revised: 21 Jul 2018; Accepted: 22 Jul 2018; Published: 31 Jul 2018.

Citation Format:

Abstract

Electrodecolorization of batik wastewater has been done. Study was performed to remediate aquatic environment containing dyes of batik industry by electrolysis, decreasing COD and some metal ions as well. Research was conducted by electrolyzing sample from Buaran Pekalongan and Semarang using Pb and PbO₂ as electrodes at a constant applied potential. Solution after treating were analysed, zeolite sieving treatment, and final analysis by UV-Vis spectrophotometer for measuring decolorization percentages, atomic absorption spectrophotometerer (AAS) for evaluating metal ions of Cu²⁺, total Fe and Na⁺, and COD analysis. Results show that electrolysis of batik wastewater using PbO₂as anode effectively decolorize and decreasing COD values. Sample containing indigozol and remazol black B (RBB) were decolorized up to 100%. CODs were reduced to 98.6% and 95.4%, respectively. Zeolite treatment enhancing water quality by reducing ion concentration of Cu²⁺, total Fe ions and Na⁺.

Fulltext View|Download Email colleagues

Keywords: Batik wastewater; electrodecolorization; indigozol; PbO2 remazole black B

Article Metrics:

Article Info

Section: Research Articles

Language : EN

In Vol 21, No 3 (2018): Volume 21 Issue 3 Year 2018

Most cited articles

Isolasi Bakteri Termofilik Sumber Air Panas Gedongsongo dengan Media Pengaya Minimal YT (Yeast Tripton) serta Identifikasi Genotipik dan Fenotipik Konsentrasi Hambat Minimum (KHM) Kadar Sampel Alang-Alang (Imperata cylindrica) dalam Etanol Melalui Metode Difusi Cakram Pengaruh Perlakuan Asam dan Kalium Permanganat terhadap Karakter Zeolit Tasik Sintesis Bahan Hibrida Amino-Silika dari Abu Sekam Padi Melalui Proses Sol-Gel Mekanisme Transport Lantanum Melalui Membran Cair Berpendukung (SLM) dengan Senyawa Pengemban campuran Tributyl Phosphate (TBP) dan Di(2-Etyl-Hexyl) Phosporic Acid (D2EHPA) More cited articles

Margareth Elisa Karina Purba, Analisa Kadar Total Suspended Solid (TSS), Amonia (NH3), Sianida (CN-), dan Sulfida (S2-) pada Limbah Cair Bapedaldasu, Diploma-3 Kimia Analis, Universitas Sumatera Utara, Medan
C. Chompuchan, T. Satapanajaru, P. Suntornchot, P. Pengthamkeerati, Decolorization of Reactive Black 5 and Reactive Red 198 using nanoscale zerovalent iron, International Journal of Environmental Science and Engineering, 2, 3, (2010) 123-127
Didik Setiyo Widodo, Ismiyarto Ismiyarto, Fithri Noorikhlas, Elektroremediasi Perairan Tercemar: 3. Elektrodekolorisasi Larutan Remazol black B dengan Elektroda Timbal Dioksida/Karbon dan Analisis Larutan Sisa Dekolorisasi, Jurnal Kimia Sains dan Aplikasi, 12, 1, (2009) 6 http://dx.doi.org/10.14710/jksa.12.1.1-6
Jiangtao Kong, Shaoyuan Shi, Lingcai Kong, Xiuping Zhu, Jinren Ni, Preparation and characterization of PbO2 electrodes doped with different rare earth oxides, Electrochimica Acta, 53, 4, (2007) 2048-2054 https://doi.org/10.1016/j.electacta.2007.09.003
M. Ueda, A. Watanabe, T. Kameyama, Y. Matsumoto, M. Sekimoto, T. Shimamune, Performance characteristics of a new type of lead dioxide-coated titanium anode, Journal of Applied Electrochemistry, 25, 9, (1995) 817-822 http://dx.doi.org/10.1007/bf00233899
I. Sirés, C. T. J. Low, C. Ponce-de-León, F. C. Walsh, The characterisation of PbO2-coated electrodes prepared from aqueous methanesulfonic acid under controlled deposition conditions, Electrochimica Acta, 55, 6, (2010) 2163-2172 https://doi.org/10.1016/j.electacta.2009.11.051
H. Y. Peng, H. Y. Chen, W. S. Li, S. J. Hu, H. Li, J. M. Nan, Z. H. Xu, A study on the reversibility of Pb(II)/PbO2 conversion for the application of flow liquid battery, Journal of Power Sources, 168, 1, (2007) 105-109 https://doi.org/10.1016/j.jpowsour.2006.11.016
Weiqing Han, Yong Chen, Lianjun Wang, Xiuyun Sun, Jiansheng Li, Mechanism and kinetics of electrochemical degradation of isothiazolin-ones using Ti/SnO2–Sb/PbO2 anode, Desalination, 276, 1, (2011) 82-88 https://doi.org/10.1016/j.desal.2011.03.027
Ilyas Bachtiar, Didik Setiyo Widodo, Elektrodekolorisasi Limbah Cair Pabrik Tekstil di Wilayah Semarang dengan Elektroda PbO2/Pb, Jurnal Kimia Sains dan Aplikasi, 18, 3, (2015) 85-90 http://dx.doi.org/10.14710/jksa.18.3.85-90
Ina Triavia, Didik Setiyo Widodo, Abdul Haris, Elektrodekolorisasi Limbah Cair Zat Warna Batik di Kota Solo dengan Elektroda PbO2/Cu, Jurnal Kimia Sains dan Aplikasi, 19, 1, (2016) 4 http://dx.doi.org/10.14710/jksa.19.1.11-14
Kelly B. Payne, Tarek M. Abdel-Fattah, Adsorption of divalent lead ions by zeolites and activated carbon: effects of pH, temperature, and ionic strength, Journal of Environmental Science and Health, Part A: Toxic/Hazardous Substances and Environmental Engineering, 39, 9, (2004) 2275-2291 https://doi.org/10.1081/ESE-200026265
Abdur Rahman, Budi Hartono, Penyaringan Air Tanah dengan Zeolit Alami untuk Menurunkan Kadar Besi dan Mangan, Makara Kesehatan, 8, 1, (2004) 1-6
Didik Setiyo Widodo, Eko Sugiharto, Endang Tri Wahyuni, Pengambilan Ion Logam Mn2+ dan Ni2+ Menggunakan Na-Zeolit: Suatu Usaha Pengkajian Pemanfaatan Sumber Daya Alam Indonesia, Jurnal Kimia Sains dan Aplikasi, 7, 2, (2004) 4 http://dx.doi.org/10.14710/jksa.7.2.35-38
Aušra Mažeikiene, Marina Valentukevičiene, Juozas Jankauskas, Laboratory study of ammonium ion removal by using zeolite (clinoptilolite) to treat drinking water, Journal of Environmental Engineering and Landscape Management, 18, 1, (2010) 54-61 https://doi.org/10.3846/jeelm.2010.07
Edison Muzenda, John Kabuba, Freeman Ntuli, Mansoor Mollagee, Antoine F Mulaba-Bafubiandi, Cu (II) removal from synthetic waste water by ion exchange process, the World Congress on Engineering and Computer Science, San Francisco, USA, (2011)
Herlan Martono, Aisyah Aisyah, Studi Pengolahan Limbah Organik Secara Elektrokimia, in, Pusat Pengembangan Pengelolaan Limbah Radioaktif - BATAN, Jakarta, 2000
Li Jiaqing, Zheng Lei, Li Luoping, Shi Guoyue, Xian Yuezhong, Jin Litong, Photoelectro-Synergistic Catalysis at Ti/TiO2/PbO2 Electrode and Its Application on Determination of Chemical Oxygen Demand, Electroanalysis, 18, 22, (2006) 2251-2256 https://doi.org/10.1002/elan.200603644
Claudia Belviso, Francesco Cavalcante, Saverio Fiore, Synthesis of zeolite from Italian coal fly ash: Differences in crystallization temperature using seawater instead of distilled water, Waste Management, 30, 5, (2010) 839-847 https://doi.org/10.1016/j.wasman.2009.11.015

Last update:

No citation recorded.

Last update: 2026-09-08 16:10:22

No citation recorded.

As an article writer, the author has the right to use their article for various purposes, including use by institutions that employ the author or institutions that provide funding for the research. These author rights are granted without special permission.

Authors who publish a paper in JKSA have broad rights to use their work for teaching and scientific purposes without the need to request permission, including: (i) teaching in the author's class or institution; (ii) presenting the work at meetings or conferences and distributing copies to participants; (iii) using the work in training conducted by the author or the author's institution; (iv) distributing copies to colleagues for research purposes; (v) using the work in the compilation of subsequent works by the author; (vi) including the work in a thesis or dissertation; (vii) reusing part of the article in another work, with appropriate citation; (viii) preparing derivative works, with appropriate citation; and (ix) voluntarily posting the work on open websites operated by the author or the author's institution for scientific purposes, in accordance with the CC BY-SA License.

Authors and readers may copy and redistribute the material in any medium or format, and may remix, transform, and build upon the material for any purpose, provided that they give appropriate credit by citing the article or its content, provide a link to the license, and indicate if changes were made.

The authors submitting a manuscript do so on the understanding that, if accepted for publication, the copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses the rights to reproduce and distribute the article in all forms and media, including reprints, photographs, microfilms, and any other similar reproductions, as well as translations.

Reproducing any part of this journal, storing it in a database, or transmitting it in any form or medium is permitted without written permission from JKSA. However, the original source must be properly cited in accordance with academic conventions.

JKSA, the Chemistry Department of Diponegoro University, and the Editor make every effort to ensure that no inaccurate, false, or misleading data, opinions, or statements are published in JKSA. However, the content of each article is the sole and exclusive responsibility of its authors.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should bear the authors' original signatures and be sent to the Editor as a printed document, a scanned document sent via email, or by fax.

Prof. Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id