DOI: https://doi.org/10.14710/jksa.21.3.118-123

Potential Oxidative Treatment Using Pb-PbO2 Electrode in Electrodecolorizing Batik Wastewater

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Received: 6 Jul 2018; Revised: 21 Jul 2018; Accepted: 22 Jul 2018; Published: 31 Jul 2018.
Open Access Copyright 2018 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Abstract
Electrodecolorization of batik wastewater has been done. Study was performed to remediate aquatic environment containing dyes of batik industry by electrolysis, decreasing COD and some metal ions as well. Research was conducted by electrolyzing sample from Buaran Pekalongan and Semarang using Pb and PbO2 as electrodes at a constant applied potential. Solution after treating were analysed, zeolite sieving treatment, and final analysis by UV-Vis spectrophotometer for measuring decolorization percentages, atomic absorption spectrophotometerer (AAS) for evaluating metal ions of Cu2+, total Fe and Na+, and COD analysis. Results show that electrolysis of batik wastewater using PbO2 as anode effectively decolorize and decreasing COD values. Sample containing indigozol and remazol black B (RBB) were decolorized up to 100%. CODs were reduced to 98.6% and 95.4%, respectively. Zeolite treatment enhancing water quality by reducing ion concentration of Cu2+, total Fe ions and Na+.
Fulltext View|Download
Keywords: Batik wastewater; electrodecolorization; indigozol; PbO2 remazole black B

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Synthesis of Zeolite from Bagasse and Rice Husk Ashes as Surfactant Builder on Detergency Process: Variation of NaOH Concentration for Silica Isolation Synthesis of ZnO/NiO Thin Film on Fluorine-doped Tin Oxide (FTO) by Two Step Electrodeposition as Photoanode of a Solar Cell Assessing the Composition of 19th Century Lime Mortars from a Mission Chapel in the Former Hacienda de San Isidro de Mariquina Philippines More recent articles
Most cited articles
Mekanisme Transport Lantanum Melalui Membran Cair Berpendukung (SLM) dengan Senyawa Pengemban campuran Tributyl Phosphate (TBP) dan Di(2-Etyl-Hexyl) Phosporic Acid (D2EHPA) Hidrorengkah Fraksi Berat Minyak Bumi Menggunakan Katalis Lempung Terpilar Aluminium Berpengemban Nikel Sintesis 3-(3,4-Dimetoksi Fenil)-1-Propanol Melalui Hidroborasi Metileugenol Menggunakan H3B:Dietileter Total Hyptolide of Indonesian Hyptis pectinata extracts in a various solvent using HPLC and UV-Vis spectroscopy and their toxicities Pengaruh Pemerangkapan Enzim Alkalin Fosfatase ke dalam Silika dari Abu Sekam Padi terhadap Aktivitas Enzimatiknya More cited articles
  1. Margareth Elisa Karina Purba, Analisa Kadar Total Suspended Solid (TSS), Amonia (NH3), Sianida (CN-), dan Sulfida (S2-) pada Limbah Cair Bapedaldasu, Diploma-3 Kimia Analis, Universitas Sumatera Utara, Medan
  2. C. Chompuchan, T. Satapanajaru, P. Suntornchot, P. Pengthamkeerati, Decolorization of Reactive Black 5 and Reactive Red 198 using nanoscale zerovalent iron, International Journal of Environmental Science and Engineering, 2, 3, (2010) 123-127
  3. Didik Setiyo Widodo, Ismiyarto Ismiyarto, Fithri Noorikhlas, Elektroremediasi Perairan Tercemar: 3. Elektrodekolorisasi Larutan Remazol black B dengan Elektroda Timbal Dioksida/Karbon dan Analisis Larutan Sisa Dekolorisasi, Jurnal Kimia Sains dan Aplikasi, 12, 1, (2009) 6 http://dx.doi.org/10.14710/jksa.12.1.1-6
  4. Jiangtao Kong, Shaoyuan Shi, Lingcai Kong, Xiuping Zhu, Jinren Ni, Preparation and characterization of PbO2 electrodes doped with different rare earth oxides, Electrochimica Acta, 53, 4, (2007) 2048-2054 https://doi.org/10.1016/j.electacta.2007.09.003
  5. M. Ueda, A. Watanabe, T. Kameyama, Y. Matsumoto, M. Sekimoto, T. Shimamune, Performance characteristics of a new type of lead dioxide-coated titanium anode, Journal of Applied Electrochemistry, 25, 9, (1995) 817-822 http://dx.doi.org/10.1007/bf00233899
  6. I. Sirés, C. T. J. Low, C. Ponce-de-León, F. C. Walsh, The characterisation of PbO2-coated electrodes prepared from aqueous methanesulfonic acid under controlled deposition conditions, Electrochimica Acta, 55, 6, (2010) 2163-2172 https://doi.org/10.1016/j.electacta.2009.11.051
  7. H. Y. Peng, H. Y. Chen, W. S. Li, S. J. Hu, H. Li, J. M. Nan, Z. H. Xu, A study on the reversibility of Pb(II)/PbO2 conversion for the application of flow liquid battery, Journal of Power Sources, 168, 1, (2007) 105-109 https://doi.org/10.1016/j.jpowsour.2006.11.016
  8. Weiqing Han, Yong Chen, Lianjun Wang, Xiuyun Sun, Jiansheng Li, Mechanism and kinetics of electrochemical degradation of isothiazolin-ones using Ti/SnO2–Sb/PbO2 anode, Desalination, 276, 1, (2011) 82-88 https://doi.org/10.1016/j.desal.2011.03.027
  9. Ilyas Bachtiar, Didik Setiyo Widodo, Elektrodekolorisasi Limbah Cair Pabrik Tekstil di Wilayah Semarang dengan Elektroda PbO2/Pb, Jurnal Kimia Sains dan Aplikasi, 18, 3, (2015) 85-90 http://dx.doi.org/10.14710/jksa.18.3.85-90
  10. Ina Triavia, Didik Setiyo Widodo, Abdul Haris, Elektrodekolorisasi Limbah Cair Zat Warna Batik di Kota Solo dengan Elektroda PbO2/Cu, Jurnal Kimia Sains dan Aplikasi, 19, 1, (2016) 4 http://dx.doi.org/10.14710/jksa.19.1.11-14
  11. Kelly B. Payne, Tarek M. Abdel-Fattah, Adsorption of divalent lead ions by zeolites and activated carbon: effects of pH, temperature, and ionic strength, Journal of Environmental Science and Health, Part A: Toxic/Hazardous Substances and Environmental Engineering, 39, 9, (2004) 2275-2291 https://doi.org/10.1081/ESE-200026265
  12. Abdur Rahman, Budi Hartono, Penyaringan Air Tanah dengan Zeolit Alami untuk Menurunkan Kadar Besi dan Mangan, Makara Kesehatan, 8, 1, (2004) 1-6
  13. Didik Setiyo Widodo, Eko Sugiharto, Endang Tri Wahyuni, Pengambilan Ion Logam Mn2+ dan Ni2+ Menggunakan Na-Zeolit: Suatu Usaha Pengkajian Pemanfaatan Sumber Daya Alam Indonesia, Jurnal Kimia Sains dan Aplikasi, 7, 2, (2004) 4 http://dx.doi.org/10.14710/jksa.7.2.35-38
  14. Aušra Mažeikiene, Marina Valentukevičiene, Juozas Jankauskas, Laboratory study of ammonium ion removal by using zeolite (clinoptilolite) to treat drinking water, Journal of Environmental Engineering and Landscape Management, 18, 1, (2010) 54-61 https://doi.org/10.3846/jeelm.2010.07
  15. Edison Muzenda, John Kabuba, Freeman Ntuli, Mansoor Mollagee, Antoine F Mulaba-Bafubiandi, Cu (II) removal from synthetic waste water by ion exchange process, the World Congress on Engineering and Computer Science, San Francisco, USA, (2011)
  16. Herlan Martono, Aisyah Aisyah, Studi Pengolahan Limbah Organik Secara Elektrokimia, in, Pusat Pengembangan Pengelolaan Limbah Radioaktif - BATAN, Jakarta, 2000
  17. Li Jiaqing, Zheng Lei, Li Luoping, Shi Guoyue, Xian Yuezhong, Jin Litong, Photoelectro-Synergistic Catalysis at Ti/TiO2/PbO2 Electrode and Its Application on Determination of Chemical Oxygen Demand, Electroanalysis, 18, 22, (2006) 2251-2256 https://doi.org/10.1002/elan.200603644
  18. Claudia Belviso, Francesco Cavalcante, Saverio Fiore, Synthesis of zeolite from Italian coal fly ash: Differences in crystallization temperature using seawater instead of distilled water, Waste Management, 30, 5, (2010) 839-847 https://doi.org/10.1016/j.wasman.2009.11.015

Last update:

No citation recorded.

Last update: 2024-11-18 17:42:16

No citation recorded.