Sintesis Metil Eugenol dan Benzil Eugenol dari Minyak Daun Cengkeh

*Ngadiwiyana Ngadiwiyana scopus  -  Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
Ismiyarto Ismiyarto scopus  -  Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
Published: 1 Dec 2004.
Open Access Copyright 2004 Jurnal Kimia Sains dan Aplikasi
License URL: http://creativecommons.org/licenses/by-sa/4.0/

Citation Format:
Abstract
Eugenol merupakan komponen utama minyak daun cengkeh dan biasa digunakan sebagai obat sakit gigi, demam dan penyusun minyak wangi. Pengembangan eugenol mulai banyak dilakukan, khususnya membuat senyawa turunannya. Salah satunya dengan melakukan reaksi alkilasi terhadap gugus hidroksil. Dalam penelitian ini, alkilasi eugenol dilakukan melalui dua tahap yaitu dengan membuat garam eugenolat melalui reaks antara eugenol dengan NaOH dan dilanjutkan reaksi garam eugenolat dengan metil iodida dan benzil klorida. Hasil-hasil reaksi dipisahkan dan dianalisis menggunakan spektroskopi IR dan kromatografi gas-spektroskopi massa. Hasil reaksi berupa larutan berwarna kuning dengan rendemen metileugenol dan benzileugenol masing-masing 53 % dan 47 %.
Keywords: eugenol; alkilasi

Article Metrics:

  1. Agusta, A., 2000, Minyak Atsiri Tumbuhan Tropika Indonesia, Bandung: Penerbit ITB, hal. 35
  2. Anonim., 1986, Petunjuk Bercocok Tanam Cengkeh, Yogyakarta: Penerbit Kanisius, hal. 27
  3. Anwar, C., 1994, The Conversion of Eugenolin to more Valuable Substanses, Desertasi, Faculty of Mathematics and Natural Sciense in Gadjah Mada University, Yogyakarta, hal. 10-14
  4. Austin, G.T., 1987, Shreve’s Chemical Process Industries, 5nd edition, New York: Mc Graw-Hill Book Company, pp. 649-672
  5. Fessenden, J., dan Fessenden, J., 1997, Dasar-dasar Kimia Organik, Jakarta: Penerbit Binarupa Aksara, hal. 342-346
  6. Guenther, E., 1990, Minyak Atsiri, 1990, Jilid IV B, Jakarta: Penerbit UI Press, hal. 449-494
  7. Harold, H., 1987, Organic Chemistry, 7nd ed, U.S.A: Houghton Mifflin Company, hal. 220
  8. Ketaren, S., 1985, Pengantar Teknologi Minyak Atsiri, 1985, Jakarta: Penerbit Balai Pustaka, hal. 277-284
  9. Mc Murry, J., 1988, Organic Chemistry, 2nd ed, California: Brook/Cote Pub. Co
  10. Morrison, R. J., and Boyd, R. N., 1987, Organic Chemistry, 5th. ed., Allyn and Bacon, Inc. Toronto, hal. 703-704
  11. Ngadiwiyana., 2000, Dimerisasi Metilisoeugenol dengan Katalis HCl dan Hidrasi Metilisoeugenol dengan Metode OM-DM, Tesis Pasca Sarjana UGM, Yogyakarta, hal. 15-21
  12. Purwono, W. Anwar, C., Fitriani, D., dan Anggraini, I., 2003, Gama Sains, V, (1), 55-63
  13. Sastrohamidjojo, H., 2002, Buku Ajar Kimia Minyak atsiri, Yogyakarta: F.MIPA UGM, hal. 139-141
  14. Sastrohamidjojo, H., 2001, Spektroskopi, Cetakan kedua, Yogyakarta: Liberty, hal. 139-141
  15. Sohilait, H.J., 2002, Sigma, V, (2), 35-139
  16. Solomons, Graham, T. W., 1982, Organic Chemistry, 4th. ed., John Wiley & Sons, New York, hal. 649-672
  17. Sujadi., 1998, Metode Pemisahan, Yogyakarta: Penerbit UGM Press, 32-50
  18. Sykes, P., 1989, Penuntun Mekanisme Reaksi Kimia Organik, Edisi ke enam, Jakarta: Penerbit PT Gramedia, hal. 39-40
  19. Tan, H.K., 1991, Bulletin of Entomological Research,, 72, 709-716
  20. Vargas, R.I., Stark, J.D., Kido, M.H., Ketter, H.D., and Whitehand, L.C., 2000, J Econ Entomol, 93, (1), 81-87
  21. Windolz., 1976, The Merck Index, 9nd ed, New york: Merck and Co

Last update: 2021-03-03 21:12:00

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  2. One pot reaction to synthesize allyl etherified eugenol from clove oil

    IOP Conference Series: Materials Science and Engineering, 127 , 2019. doi: 10.1088/1757-899X/509/1/012098
  3. Synthesis of copolymer eugenol crosslinked with divinyl benzene and preliminary study on its antibacterial activity

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