DOI: https://doi.org/10.14710/jksa.25.4.137-145

Silica-rich Sodalite Synthesis: The Effect of Variations in Ultrasound Treatment and Hydrothermal Temperature

1Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

2Chemistry Engineering Department, Faculty of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

Received: 10 Nov 2021; Revised: 20 Mar 2022; Accepted: 23 Mar 2022; Published: 30 Apr 2022.
Open Access Copyright 2022 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
Silica-rich sodalite zeolite has been synthesized by ultrasound treatment and hydrothermal temperature variation. This study aimed to determine the effect of ultrasound treatment and hydrothermal temperature variations on the crystallinity, hydrophobicity, and structural properties of silica-rich sodalite zeolite. The synthesis was conducted by reacting a sodium aluminate and sodium silicate solution by varying Si/Al ratios of 20, 30, 40, 60, 80, and 90. The next step was to characterize the product. The product with the best crystallinity was used as a reference to determine the effect of ultrasound and hydrothermal temperature. The reaction gel was treated with and without ultrasound and hydrothermal using autoclave at 100, 150, and 200°C for 24 hours. The last step was the product characterization using XRD, FTIR, and GSA. The XRD showed similarity peaks at 2θ = 14.058°; 24.41°; 31.73°; 34.75°; 42.88°. The best crystallinity was silica-rich sodalite zeolite with a Si/Al ratio of 30. Meanwhile, silica-rich sodalite zeolite peaks were obtained at 2θ = 14.16°, 24.66°, 31.99°, 35.13°, and 43.39° by ultrasound treatment and hydrothermal temperature variation (100, 150, and 200°C). Ultrasound treatment revealed the presence of other peaks besides sodalite at 2θ = 19.05° and 27°, where these peaks were referred to as SAPO-56. In conclusion, the degree of crystallinity increased with increasing temperature, decreasing Si-OH/Si-O-Si showed increased hydrophobic properties. Increasing the hydrothermal temperature of 150 and 200°C with and without ultrasound treatment increased the surface area significantly to 114.137 m2/g and 160.717 m2/g, and the pore volume of sodalite with a Si/Al ratio of 30 to 0.318 cc/g and 0.274 cc/g.
Fulltext View|Download
Keywords: Silica-rich sodalite; ultrasound; hydrothermal; crystallinity; hydrophobicity
Funding: Kementerian Riset Teknologi dan Pendidikan Tinggi, Republik Indonesia

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Synthesis of Ionic Imprinted Membrane (IIM) Based on Sulfonated Polyeugenol for Selective Transport of Gold (III) Metal Ions from Motherboard Waste Silica-rich Sodalite Synthesis: The Effect of Variations in Ultrasound Treatment and Hydrothermal Temperature In Vitro Immunomodulatory Activity of Virgin Coconut Oil (VCO) with and without Bromelain Enzyme from Pineapple Waste (Ananas comosus (L) Merr) More recent articles
Most cited articles
Pengaruh Agen Pencangkok Heparin terhadap Kemampuan Transpor Kreatinin dan Urea Membran Turunan Kitosan Interlayer-free Silica Pectin Membrane for Wetland Saline Water via Pervaporation Sintesis Metil Eugenol dan Benzil Eugenol dari Minyak Daun Cengkeh Dimerisasi Metilisoeugenol dengan Katalis HCl Sintesis Zeolit A dan Kemungkinan Penggunaannya Sebagai Penukar Kation More cited articles
  1. N. V. Chukanov, S. M. Aksenov, R. K. Rastsvetaeva, Structural chemistry, IR spectroscopy, properties, and genesis of natural and synthetic microporous cancrinite-and sodalite-related materials: a review, Microporous and Mesoporous Materials, 323, 111098, (2021), 1-44 https://doi.org/10.1016/j.micromeso.2021.111098
  2. Orevaoghene Eterigho-Ikelegbe, Samson Bada, Michael O. Daramola, Rosemary Falcon, Synthesis of high purity hydroxy sodalite nanoparticles via pore-plugging hydrothermal method for inorganic membrane development: Effect of synthesis variables on crystallinity, crystal size and morphology, Materials Today: Proceedings, 38, 2, (2021), 675-681 https://doi.org/10.1016/j.matpr.2020.03.693
  3. C. L. Eden, M. O. Daramola, Evaluation of silica sodalite infused polysulfone mixed matrix membranes during H2/CO2 separation, Materials Today: Proceedings, 38, 2, (2021), 522-527 https://doi.org/10.1016/j.matpr.2020.02.393
  4. S. Sriatun, H. Susanto, W. Widayat, A. Darmawan, S. Sriyanti, R. Kurniasari, R. Kurniawati, Synthesis of silica-rich zeolite using quaternary ammonium-based templates, Journal of Physics: Conference Series, 2020 https://doi.org/10.1088/1742-6596/1524/1/012087
  5. Maria Rubtsova, Ekaterina Smirnova, Sevastyan Boev, Michail Kotelev, Kirill Cherednichenko, Vladimir Vinokurov, Yuri Lvov, Aleksandr Glotov, Nanoarchitectural approach for synthesis of highly crystalline zeolites with a low Si/Al ratio from natural clay nanotubes, Microporous and Mesoporous Materials, 330, 111622, (2022), 1-9 https://doi.org/10.1016/j.micromeso.2021.111622
  6. Justyna Szerement, Alicja Szatanik-Kloc, Renata Jarosz, Tomasz Bajda, Monika Mierzwa-Hersztek, Contemporary applications of natural and synthetic zeolites from fly ash in agriculture and environmental protection, Journal of Cleaner Production, 311, 127461, (2021), 1-19 https://doi.org/10.1016/j.jclepro.2021.127461
  7. Nan Jiang, Ran Shang, Sebastiaan G. J. Heijman, Luuk C. Rietveld, High-silica zeolites for adsorption of organic micro-pollutants in water treatment: A review, Water Research, 144, (2018), 145-161 https://doi.org/10.1016/j.watres.2018.07.017
  8. Norsuhailizah Sazali, Zawati Harun, Tijjani Abdullahi, Faiz Hafeez Azhar, Azlinnorazia Ahmad, Nurul Izwanie Rasli, Norazlianie Sazali, Potential of Transforming Sodalite from Synthesis Kaolin with a Mild Condition of the Hydrothermal Method, Biointerface Research in Applied Chemistry, 12, 6, (2022), 7376-7393 https://doi.org/10.33263/BRIAC126.73767393
  9. Meyga Evi Ferama Sari, Suprapto Suprapto, Didik Prasetyoko, Direct synthesis of sodalite from kaolin: the influence of alkalinity, Indonesian Journal of Chemistry, 18, 4, (2018), 607-613 https://doi.org/10.22146/ijc.25191
  10. Sriatun, Ranu Luthfi Ananto, Effect of Hydrothermal Time on The Character of High Silica Sodalite, International Journal of Academic Multidisciplinary Research (IJAMR), 5, 10, (2021), 134-137
  11. Reza Khoshbin, Ramin Karimzadeh, Synthesis of mesoporous ZSM-5 from rice husk ash with ultrasound assisted alkali-treatment method used in catalytic cracking of light naphtha, Advanced Powder Technology, 28, 8, (2017), 1888-1897 https://doi.org/10.1016/j.apt.2017.04.024
  12. Boitumelo Makgabutlane, Lebea N. Nthunya, Edward N. Nxumalo, Nicholas M. Musyoka, Sabelo D. Mhlanga, Microwave irradiation-assisted synthesis of zeolites from coal fly ash: An optimization study for a sustainable and efficient production process, ACS Omega, 5, 39, (2020), 25000-25008 https://doi.org/10.1021/acsomega.0c00931
  13. Danutė Vaičiukynienė, Leonas Jakevičius, Aras Kantautas, Vitoldas Vaitkevičius, Vilimantas Vaičiukynas, The effect of ultrasound on Na-A zeolite synthesis based on sodium aluminosilicate gels and solid materials, Revista Romana de Materiale, 50, 4, (2020), 471-477
  14. Natalya E. Gordina, Valery Yu. Prokof’ev, Yuliya N. Kul’pina, Nina V. Petuhova, Sevil I. Gazahova, Olga E. Hmylova, Effect of ultrasound on the synthesis of low-modulus zeolites from a metakaolin, Ultrasonics Sonochemistry, 33, (2016), 210-219 https://doi.org/10.1016/j.ultsonch.2016.05.008
  15. Valery Yu Prokof'ev, Natalya E. Gordina, Ekaterina M. Konstantinova, Viktoriya V. Voynova, Tatyana N. Borisova, Thermal treatment of a mixture for the NaP zeolite synthesis based on sodium metasilicate and alumina: Effect of ultrasound, Materials Chemistry and Physics, 213, (2018), 76-82 https://doi.org/10.1016/j.matchemphys.2018.03.090
  16. Xiaojun Zeng, Xudong Hu, Hanbin Song, Guohua Xia, Zong-Yang Shen, Ronghai Yu, Martin Moskovits, Microwave synthesis of zeolites and their related applications, Microporous and Mesoporous Materials, 323, 111262, (2021), 1-18 https://doi.org/10.1016/j.micromeso.2021.111262
  17. S. Sina Hosseini Boosari, Sonia Eskandari, Abolfazl Shakouri, Mahdi Fathizadeh, Effect of heating period and temperature on the synthesis of nano-beta zeolite assisted by microwaves, Journal Membrane Science & Technology, 8, 1, (2018), 1000180 http://dx.doi.org/10.4172/2155-9589.1000180
  18. Geovana Stafin, Edson Cezar Grzebielucka, Sandra Regina Masetto Antunes, Christiane Philippini Ferreira Borges, André Vitor Chaves de Andrade, Suellen Aparecida Alves, Éder Carlos Ferreira de Souza, Synthesis of zeolites from residual diatomite using a microwave-assisted hydrothermal method, Waste Management, 126, (2021), 853-860 https://doi.org/10.1016/j.wasman.2021.04.029
  19. Longjie Cui, Ruyue Han, Lu Yang, Yibo Wu, Rujing Pei, Fuxiang Li, Synthesis and characterization of mesoporous sodalite and investigation of the effects of inorganic salts on its structure and properties, Microporous and Mesoporous Materials, 306, 110385, (2020), 1-9 https://doi.org/10.1016/j.micromeso.2020.110385
  20. Sriatun Sriatun, Heru Susanto, Widayat Widayat, Adi Darmawan, Hydrocracking of Coconut Oil on the NiO/Silica-Rich Zeolite Synthesized Using a Quaternary Ammonium Surfactant, Indonesian Journal of Chemistry, 21, 2, (2021), 361-375 https://doi.org/10.22146/ijc.55522
  21. Bimo Tunggal Dipowardani, Sriatun Sriatun, Taslimah Taslimah, Sintesis silika kristalin menggunakan surfaktan cetiltrimetilamonium bromida (CTAB) dan trimetilamonium klorida (TMACl) sebagai pencetak pori, Jurnal Kimia Sains dan Aplikasi, 11, 1, (2008), 20-28 https://doi.org/10.14710/jksa.11.1.20-28
  22. Yanyan Mu, Yu Zhang, Jiangyang Fan, Cuili Guo, Effect of ultrasound pretreatment on the hydrothermal synthesis of SSZ-13 zeolite, Ultrasonics Sonochemistry, 38, (2017), 430-436 https://doi.org/10.1016/j.ultsonch.2017.03.043
  23. Ruben M. Dewes, Heidy Ramirez Mendoza, Mafalda Valdez Lancinha Pereira, Cécile Lutz, Tom Van Gerven, Experimental and Numerical Investigation of the Effect of Ultrasound on the Growth Kinetics of Zeolite A, Ultrasonics Sonochemistry, 82, 105909, (2022), 1-7 https://doi.org/10.1016/j.ultsonch.2022.105909
  24. M. Mahima Kumar, Hrudananda Jena, Direct single-step synthesis of phase pure zeolite Na–P1, hydroxy sodalite and analcime from coal fly ash and assessment of their Cs+ and Sr2+ removal efficiencies, Microporous and Mesoporous Materials, 333, 111738, (2022), 1-12 https://doi.org/10.1016/j.micromeso.2022.111738
  25. Jie Luo, Haijun Zhang, Jian Yang, Hydrothermal synthesis of sodalite on alkali-activated coal fly ash for removal of lead ions, Procedia Environmental Sciences, 31, (2016), 605-614 https://doi.org/10.1016/j.proenv.2016.02.105
  26. Jintang Li, Xue Zeng, Xiaobing Yang, Chaonan Wang, Xuetao Luo, Synthesis of pure sodalite with wool ball morphology from alkali fusion kaolin, Materials Letters, 161, (2015), 157-159 https://doi.org/10.1016/j.matlet.2015.08.058
  27. Jamshid Behin, Hossein Kazemian, Sohrab Rohani, Sonochemical synthesis of zeolite NaP from clinoptilolite, Ultrasonics Sonochemistry, 28, (2016), 400-408 https://doi.org/10.1016/j.ultsonch.2015.08.021
  28. Ozgul Dere Ozdemir, Sabriye Piskin, A novel synthesis method of zeolite X from coal fly ash: alkaline fusion followed by ultrasonic-assisted synthesis method, Waste and Biomass Valorization, 10, 1, (2019), 143-154 https://doi.org/10.1007/s12649-017-0050-7
  29. Rui Li, Aseem Chawla, Noemi Linares, James G. Sutjianto, Karena W. Chapman, Javier García Martínez, Jeffrey D. Rimer, Corrections to “Diverse Physical States of Amorphous Precursors in Zeolite Sol Gel Syntheses”, Industrial & Engineering Chemistry Research, 57, 32, (2018), 11258-11258 https://doi.org/10.1021/acs.iecr.8b03506
  30. Julien Devos, Meera A. Shah, Michiel Dusselier, On the key role of aluminium and other heteroatoms during interzeolite conversion synthesis, RSC Advances, 11, 42, (2021), 26188-26210 https://doi.org/10.1039/D1RA02887A
  31. Sriatun Sriatun, Taslimah Taslimah, Linda Suyati, Synthesis of Zeolite from Sugarcane Bagasse Ash Using Cetyltrimethylammonium Bromide as Structure Directing Agent, Indonesian Journal of Chemistry, 18, 1, (2018), 159-165 https://doi.org/10.22146/ijc.22197
  32. Sriatun Sriatun, Adi Darmawan, Sriyanti Sriyanti, Synthesis and Characterization of Zeolite/Magnetitte Composite from Iron Sand of Marina Beach, Advanced Science Letters, 23, 7, (2017), 6524-6526 https://doi.org/10.1166/asl.2017.9672
  33. S. M. Pourali, A. Samadi-Maybodi, Role of gel aging in template-free synthesis of micro and nano-crystalline sodalites, Chemistry of Solid Materials, 2, 1, (2014), 21-31
  34. P. Vongvoradit, P. Worathanakul, Fast crystallization of SUZ-4 zeolite with hydrothermal synthesis: Part I temperature and time effect, Procedia Engineering, 32, (2012), 198-204 https://doi.org/10.1016/j.proeng.2012.01.1257
  35. Maarten Houlleberghs, Eric Breynaert, Karel Asselman, Ewoud Vaneeckhaute, Sambhu Radhakrishnan, Michael W. Anderson, Francis Taulelle, Mohamed Haouas, Johan A. Martens, Christine E. A. Kirschhock, Evolution of the crystal growth mechanism of zeolite W (MER) with temperature, Microporous and Mesoporous Materials, 274, (2019), 379-384 https://doi.org/10.1016/j.micromeso.2018.09.012
  36. Hai-Chen Wang, Silvana Botti, Miguel A. L. Marques, Predicting stable crystalline compounds using chemical similarity, npj Computational Materials, 7, 1, (2021), 1-9 https://doi.org/10.1038/s41524-020-00481-6
  37. Tahani Aldahri, Jamshid Behin, Hossein Kazemian, Sohrab Rohani, Synthesis of zeolite Na-P from coal fly ash by thermo-sonochemical treatment, Fuel, 182, (2016), 494-501 https://doi.org/10.1016/j.fuel.2016.06.019
  38. Tiffany Yit Siew Ng, Thiam Leng Chew, Yin Fong Yeong, Synthesis of small pore zeolite via ultrasonic-assisted hydrothermal synthesis, Materials Today: Proceedings, 16, (2019), 1935-1941 https://doi.org/10.1016/j.matpr.2019.06.071
  39. Pameli Pal, Jugal K. Das, Nandini Das, Sibdas Bandyopadhyay, Synthesis of NaP zeolite at room temperature and short crystallization time by sonochemical method, Ultrasonics Sonochemistry, 20, 1, (2013), 314-321 https://doi.org/10.1016/j.ultsonch.2012.07.012
  40. Dipak B. Shukla, Vyomesh P. Pandya, Estimation of crystalline phase in ZSM‐5 zeolites by infrared spectroscopy, Journal of Chemical Technology & Biotechnology, 44, 2, (1989), 147-154 https://doi.org/10.1002/jctb.280440206
  41. Eugenii A. Paukshtis, Mariya A. Yaranova, Irina S. Batueva, Bair S. Bal'zhinimaev, A FTIR study of silanol nests over mesoporous silicate materials, Microporous and Mesoporous Materials, 288, 109582, (2019), 1-5 https://doi.org/10.1016/j.micromeso.2019.109582
  42. V. V. Potapov, L. T. Zhuravlev, Temperature dependence of the concentration of silanol groups in silica precipitated from a hydrothermal solution, Glass Physics and Chemistry, 31, 5, (2005), 661-670 https://doi.org/10.1007/s10720-005-0111-z
  43. Tao Yin, Xuan Meng, Linpeng Jin, Chao Yang, Naiwang Liu, Li Shi, Prepared hydrophobic Y zeolite for adsorbing toluene in humid environment, Microporous and Mesoporous Materials, 305, 110327, (2020), 1-11 https://doi.org/10.1016/j.micromeso.2020.110327
  44. Satish A. Mahadik, D. B. Mahadik, V. G. Parale, P. B. Wagh, Satish Gupta, A. Venkateswara Rao, Recoverable and thermally stable superhydrophobic silica coating, Journal of Sol-Gel Science and Technology, 62, 3, (2012), 490-494 https://doi.org/10.1007/s10971-012-2753-3
  45. Reza Khoshbin, Ramin Karimzadeh, The beneficial use of ultrasound in free template synthesis of nanostructured ZSM-5 zeolite from rice husk ash used in catalytic cracking of light naphtha: effect of irradiation power, Advanced Powder Technology, 28, 3, (2017), 973-982 https://doi.org/10.1016/j.apt.2017.01.001

Last update:

No citation recorded.

Last update: 2024-04-24 16:43:28

No citation recorded.