Synthesis of Ionic Imprinted Membrane (IIM) Based on Sulfonated Polyeugenol for Selective Transport of Gold (III) Metal Ions from Motherboard Waste

Muhammad Cholid Djunaidi; Fadjrin Nur Rahmayani; Khabibi khabibi

doi:10.14710/jksa.25.4.161-168

DOI: https://doi.org/10.14710/jksa.25.4.161-168

Synthesis of Ionic Imprinted Membrane (IIM) Based on Sulfonated Polyeugenol for Selective Transport of Gold (III) Metal Ions from Motherboard Waste

Muhammad Cholid Djunaidi

, Fadjrin Nur Rahmayani, Khabibi khabibi

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

Received: 22 Jan 2022; Revised: 4 Apr 2022; Accepted: 25 Apr 2022; Published: 30 Apr 2022.

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Abstract

Ionic imprinted membrane (IIM) was successfully synthesized using sulfonated polyeugenol, a derivative of eugenol as a functional polymer, with PVA as a base membrane and PEGDE as a crosslinker. IIM Au(III) is a membrane with an Au(III) ion template. This study aimed to determine the pH effect of a feed phase for selective transport of IIM Au(III), comparing it with a non-imprinted membrane (NIM) against Au³⁺ metal ions from motherboard waste. It also aimed to compare the membrane selectivity of Au³⁺ metal ions to Cu²⁺ metal ions, which are also found in motherboard waste. Gold samples were prepared using H(AuCl₄) standard and leaching solutions from motherboard waste. The leaching of the motherboard used aqua regia and the assistance of a microwave to accelerate the leaching process. The optimum transport of Au³⁺ metal ions was when using IIM Au(III) at pH 3. This proved that the presence of a template affected IIM Au(III) to recognize Au(III) ions. IIM Au(III) showed higher selectivity than NIM, as evidenced by the percentage in the receiving phase of the Au³⁺ metal ions, which was more significant than the Cu²⁺ metal ions from the motherboard leaching solution.

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Keywords: ionic imprinted membrane, sulfonated polyeugenol, gold metal ion, motherboard, microwave

Funding: Universitas Diponegoro

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Section: Research Articles

Language : EN

In Vol 25, No 4 (2022): Volume 25 Issue 4 Year 2022

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