DOI: https://doi.org/10.14710/jksa.26.2.50-56

Effect of NaOH Concentration Toward the Characteristics of Activated Natural Zeolite from Blitar – East Java

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University, Malang, Indonesia

Received: 10 Nov 2022; Revised: 20 Jan 2023; Accepted: 15 Feb 2023; Published: 28 Feb 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
This study discusses the activation of natural zeolite from Blitar City – East Java using NaOH solution (0.5 M and 1.0 M). Characteristics of unactivated and activated zeolites were also investigated, as well as the effect of the activator (NaOH solution) on functional groups, element composition, pore size, specific surface area, and total pore volume. FTIR spectroscopy, XRF, and gas physisorption were conducted to support the study. Experimental data showed that: (1) the major functional groups were observed at 1250-780 cm-1 in the infrared spectra, in which the unactivated and the activated zeolite were not significantly different; (2) the elemental composition of zeolite (Si and Al) tended to decrease after the activation process; (3) the pore size of the activated zeolite increased while the surface area and total pore volume decreased. Based on this study, activated zeolite (AZB-1.0) showed the optimum result: the pore size increased by 4.12847 nm, and the total pore volume did not decrease significantly by 0.04987 cc/g.
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Keywords: Natural zeolite; activated zeolite; alkali activation, CO2 adsorption
Funding: Universitas Brawijaya

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Section: Research Articles
Language : EN
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  1. Satriyo Krido Wahono, Hernawan, Anis Kristiani, Silvester Tursiloadi, Haznan Abimanyu, Characterization and Utilization of Gunungkidul Natural Zeolite for Bioethanol Dehydration, Energy Procedia, 47, (2014), 263-267 https://doi.org/10.1016/j.egypro.2014.01.223
  2. S. K. Wahono, D. J. Prasetyo, T. H. Jatmiko, A. Suwanto, D. Pratiwi, K. Vasilev, Transformation of mordenite-clinoptilolite natural zeolite at different calcination temperatures, IOP Conference Series: Earth and Environmental Science, 2019 https://doi.org/10.1088/1755-1315/251/1/012009
  3. Iwan Setiawan, Leny M. Estiaty, Dewi Fatimah, Sri Indarto, Lediyantje Lintjewas, Andri Alkausar, Aryo D. Handoko, Anita Yuliyanti, Jakah Jakah, Geologi dan Petrokimia Endapan Zeolit daerah Bayah dan Sukabumi, RISET Geologi dan Pertambangan, 30, 1, (2020), 39-54
  4. Dewi Yuanita Lestari, Kajian modifikasi dan karakterisasi zeolit alam dari berbagai negara, Prosiding Seminar Nasional Kimia dan Pendidikan Kimia, Yogyakarta, 2010
  5. Gustri Nurliati, Y. K. Krisnandi, R. Sihombing, Zainus Salimin, Studies of Modification of Zeolite by Tandem Acid-Base Treatments and its Adsorptions Performance Towards Thorium, Atom Indonesia, 41, 2, (2015), 87-95 https://doi.org/10.17146/aij.2015.382
  6. Grandprix T. M. Kadja, Moh Mualliful Ilmi, Noerma J. Azhari, Munawar Khalil, Adroid T. N. Fajar, I. G. B. N. Makertihartha, Melia L. Gunawan, Carolus B. Rasrendra, I. G. Wenten, Recent advances on the nanoporous catalysts for the generation of renewable fuels, Journal of Materials Research and Technology, 17, (2022), 3277-3336 https://doi.org/10.1016/j.jmrt.2022.02.033
  7. Natalia Sobuś, Izabela Czekaj, Volodymyr Diichuk, Igor M. Kobasa, Characteristics of the structure of natural zeolites and their potential application in catalysis and adsorption processes, Technical Transactions, 117, 1, (2020), 1-20 https://doi.org/10.37705/TechTrans/e2020043
  8. Mohamad Djaeni, Laeli Laeli Kurniasari, Setia Budi Sasongko, Preparation of natural zeolite for air dehumidification in food drying, International Journal of Science and Engineering, 8, 2, (2015),
  9. Vanda Liliana Babalau Fuss, Gabriel Bruj, Lucian Dordai, Marius Roman, Oana Cadar, Anca Becze, Evaluation of the impact of different natural zeolite treatments on the capacity of eliminating/reducing odors and toxic compounds, Materials, 14, 13, (2021), 3724 https://doi.org/10.3390/ma14133724
  10. Muhammad Al Muttaqii, David Candra Birawidha, Kusno Isnugroho, Muhammad Yamin, Yusup Hendronursito, Amila Dini Istiqomah, Diego Putra Dewangga, Pengaruh aktivasi secara kimia menggunakan larutan asam dan basa terhadap karakteristik zeolit alam, Jurnal Riset Teknologi Industri, 11, 2, (2019), 266-271 http://dx.doi.org/10.26578/jrti.v13i2.5577
  11. E. Davarpanah, M. Armandi, S. Hernández, D. Fino, R. Arletti, S. Bensaid, M. Piumetti, CO2 capture on natural zeolite clinoptilolite: Effect of temperature and role of the adsorption sites, Journal of Environmental Management, 275, (2020), 111229 https://doi.org/10.1016/j.jenvman.2020.111229
  12. Chayun Pida Renni, F. Widhi Mahatmanti, Nuni Widiarti, Pemanfaatan Zeolit Alam Teraktivasi HNO3 sebagai Ion Logam Fe (III) dan Cr (VI), Indonesian Journal of Chemical Science, 7, 1, (2018), 64-70
  13. Widayat Widayat, Roesyadi Achmad, Rachimoellah Muhammad, Diethyl Ether Production Process with Various Catalyst Type, International Journal of Science and Engineering, 4, 1, (2013), 6-10 https://doi.org/10.12777/ijse.4.1.6-10
  14. Anis Kristiani, Sudiyarmanto Sudiyarmanto, Fauzan Aulia, Luthfiana Nurul Hidayati, Haznan Abimanyu, Metal supported on natural zeolite as catalysts for conversion of ethanol to gasoline, Sriwijaya International Conference on Engineering, Science and Technology (SICEST 2016), Palembang, 2017 https://doi.org/10.1051/matecconf/201710101001
  15. Ricky Indra Kusuma, Johan Prabowo Hadinoto, Aning Ayucitra, Felycia Edi Soetaredjo, Suryadi Ismadji, Natural zeolite from Pacitan Indonesia, as catalyst support for transesterification of palm oil, Applied Clay Science, 74, (2013), 121-126 https://doi.org/10.1016/j.clay.2012.04.021
  16. Ahmad Ainurofiq, Syaiful Choiri, Drug release mechanism of slightly soluble drug from nanocomposite matrix formulated with zeolite/hydrotalcite as drug carrier, Tropical Journal of Pharmaceutical Research, 14, 7, (2015), 1129-1135 https://doi.org/10.4314/tjpr.v14i7.2
  17. Karmen Margeta, N. Zabukovec Logar, Mario Šiljeg, Anamarija Farkaš, Natural zeolites in water treatment–how effective is their use, IntechOpen, 2013, https://doi.org/10.5772/50738
  18. R. F. I. Rahmayani, Y. Arryanto, I. Kartini, The effect of alkaline activation on the zeolite binding properties toward dissolved irons, Journal of Physics: Conference Series, Kota Banda Aceh, Indonesia, 2020 https://doi.org/10.1088/1742-6596/1460/1/012084
  19. Yulius Dala Ngapa, Study of the acid-base effect on zeolite activation and its characterization as adsorbent of methylene blue dye, JKPK (Jurnal Kimia dan Pendidikan Kimia), 2, 2, (2017), 90-96 https://doi.org/10.20961/jkpk.v2i2.11904
  20. Cheng Wang, Shaozheng Leng, Huidong Guo, Liyun Cao, Jianfeng Huang, Acid and alkali treatments for regulation of hydrophilicity/hydrophobicity of natural zeolite, Applied Surface Science, 478, (2019), 319-326 https://doi.org/10.1016/j.apsusc.2019.01.263
  21. Suhartana Suhartana, Pardoyo Pardoyo, Activation of Natural Zeolite and Its Application for Adsorbents in Domestic Wastewater Treatment in Tembalang District, Semarang City, Jurnal Kimia Sains dan Aplikasi, 23, 1, (2020), 28-33 https://doi.org/10.14710/jksa.23.1.28-33
  22. Arifin Arifin, Latifah Latifah, Sintesis Biodiesel Dari Minyak Goreng Bekas Dengan Menggunakan Katalis Zeolit Alam Termodifikasi, Indonesian Journal of Chemical Science, 4, 2, (2015),
  23. Dessy Dwi Septian, Sri Sugiarti, Modifikasi Zeolit Alam Ende dengan Garam Logam serta Potensinya Sebagai Katalis Transformasi Glukosa Menjadi 5-Hidroksimetilfurfural (HMF), ALCHEMY Jurnal Penelitian Kimia, 15, 2, (2019), 203-218 https://doi.org/10.20961/alchemy.15.2.28180.203-218
  24. D. A. Wulandari, E. Djubaedah, Nasruddin, Water adsorption behavior of Indonesian natural zeolite based on NaOH treatment: A preliminary study, AIP Conference Proceedings, Padang, Indonesia, 2020 https://doi.org/10.1063/5.0006710
  25. Ayten Ates, Gökçen Akgül, Modification of natural zeolite with NaOH for removal of manganese in drinking water, Powder Technology, 287, (2016), 285-291 https://doi.org/10.1016/j.powtec.2015.10.021
  26. Dorien Kerstens, Brent Smeyers, Jonathan Van Waeyenberg, Qiang Zhang, Jihong Yu, Bert F. Sels, State of the art and perspectives of hierarchical zeolites: practical overview of synthesis methods and use in catalysis, Advanced Materials, 32, 44, (2020), 2004690 https://doi.org/10.1002/adma.202004690
  27. Febi Yusniyanti, Wega Trisunaryanti, Triyono Triyono, Acid-Alkaline Treatment of Mordenite and Its Catalytic Activity in the Hydrotreatment of Bio-Oil, Indonesian Journal of Chemistry, 21, 1, (2020), 37-45 https://doi.org/10.22146/ijc.51496
  28. Rina Nurianingsih, Sriatun Sriatun, Adi Darmawan, Polyaniline Modified Natural Zeolite as Adsorbent for Chromium(III) Metal Ion, Jurnal Kimia Sains dan Aplikasi, 22, 6, (2019), 7 https://doi.org/10.14710/jksa.22.6.292-298
  29. Matthias Thommes, Katsumi Kaneko, Alexander V. Neimark, James P. Olivier, Francisco Rodriguez-Reinoso, Jean Rouquerol, Kenneth S. W. Sing, Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report), Pure and Applied Chemistry, 87, 9-10, (2015), 1051-1069 https://doi.org/10.1515/pac-2014-1117
  30. Junwen Gu, Jiaqi Lin, Andrew J. Smith, Siriwat Soontaranon, Supagorn Rugmai, Chanapa Kongmark, Marc-Olivier Coppens, Gopinathan Sankar, Towards understanding mesopore formation in zeolite Y crystals using alkaline additives via in situ small-angle X-ray scattering, Microporous and Mesoporous Materials, 338, (2022), 111867 https://doi.org/10.1016/j.micromeso.2022.111867
  31. Nabiollah Mansouri, Navid Rikhtegar, H. Ahmad Panahi, Farideh Atabi, B. Karimi Shahraki, Porosity, characterization and structural properties of natural zeolite-clinoptilolite-as a sorbent, Environment Protection Engineering, 39, 1, (2013), 139-152
  32. G. U. Ryu, Hammad R. Khalid, Namkon Lee, Zhen Wang, Haeng-Ki Lee, The effects of NaOH concentration on the hydrothermal synthesis of a hydroxyapatite–zeolite composite using blast furnace slag, Minerals, 11, 1, (2020), 21 https://doi.org/10.3390/min11010021
  33. Ulrich S. Schubert, Nicola Hüsing, Synthesis of inorganic materials, 3rd completely rev. and enlarged ed., Wiley-VCH, Weinheim, Chichester, 2012
  34. Kateřina Hrachovcová, Zdeněk Tišler, Eliška Svobodová, Jan Šafář, Modified alkali activated zeolite foams with improved textural and mechanical properties, Minerals, 10, 5, (2020), 483 https://doi.org/10.3390/min10050483
  35. Mohammad A. Al-Ghouti, Dana A. Da'ana, Guidelines for the use and interpretation of adsorption isotherm models: A review, Journal of Hazardous Materials, 393, (2020), 122383 https://doi.org/10.1016/j.jhazmat.2020.122383

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