DOI: https://doi.org/10.14710/jksa.27.6.265-270

Effect of Precursors Concentration on The Optical and Photoelectrochemical Properties of Bi₂S₃/TiO₂ Nanotubes Arrays Photoanode Synthesized by the SILAR Technique

Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Depok, 16424, Indonesia

Received: 13 Jan 2024; Revised: 8 May 2024; Accepted: 28 May 2024; Published: 30 Jun 2024.
Open Access Copyright 2024 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

The use of robust solar energy-driven photocatalysis materials to address the global energy and environmental crisis has gained significant attention in recent years. However, the wide band gaps in many robust semiconductor photocatalysts hinder their absorption of visible light from the solar spectrum. To address this issue, the modification of the large band gap semiconductor with the lower band gap material using the Successive Ionic Layers Adsorption and Reaction (SILAR) technique has emerged as an economical, accessible, and reproducible method for depositing nanoscale materials onto semiconductor substrates. This research aims to know how the concentration variation of cation and anion precursors in the SILAR technique affects the optical and photoelectrochemical properties of the resulting composite materials. Bi₂S₃ serves as a modifier for TiO₂ nanotube arrays (NTAs). The result shows that the cation-anion concentration ratio of 1:1.5 mM with five SILAR cycles gives the best photoelectrochemical performance, with a stable current density of 0.12 mA/cm², compared to pristine TiO₂ NTAs the current density of Bi₂S₃/TiO₂ NTAs is 15-fold. In addition, at each variation, the concentration ratio of cation and anion precursors decreases bandgap energy with each increase in the SILAR cycle.

Fulltext View|Download
Keywords: Bi₂S₃; Precursor concentration; SILAR; TiO₂ NTs

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Synthesis, Characterization and Molecular Docking of Bis-(1-(2,4-dichlorobenzoyl)-3-methylthiourea) Iron (III) Complex as Anticancer Candidate Antibacterial Properties of Bacterial Cellulose-Quercetin Composite Membrane Synthesis and Characterization of Silica-Biochar Composite as Rhodamine B Dye Adsorbent Study on the Upgrading Citronella (Cymbopogon nardus L.) Oil Isolation Using Microwave Assisted Hydro-distillation Method More recent articles
Most cited articles
Preparasi Katalis Zeolit Alam Asam sebagai Katalis dalam Proses Pirolisis Katalitik Polietilena Pengaruh Konsentrasi Substrat Maltosa terhadap Potensial Listrik Baterai Lactobacillus bulgaricus (MFC) Isolasi Senyawa Antioksidan dari Fraksi Etil Asetat Daun Tempuyung (Sonchus arvensis L) Pengaruh Agen Pencangkok Heparin terhadap Kemampuan Transpor Kreatinin dan Urea Membran Turunan Kitosan Sintesis Zeolit A dan Kemungkinan Penggunaannya Sebagai Penukar Kation More cited articles
  1. Tanzim Ur Rahman, Hridoy Roy, Athkia Fariha, Afrina Zaman Shoronika, Md Rashid Al-Mamun, Syed Z. Islam, Md Shahinoor Islam, Hadi M. Marwani, Aminul Islam, Abdulmohsen K. D. Alsukaibi, Mohammed M. Rahman, Md Rabiul Awual, Progress in plasma doping semiconductor photocatalysts for efficient pollutant remediation and hydrogen generation, Separation and Purification Technology, 320, (2023), 124141 https://doi.org/10.1016/j.seppur.2023.124141
  2. Ghaferah H. Al-Hazmi, Moamen S. Refat, Khaled F. Alshammari, Khadiza Tul Kubra, Ahmed Shahat, Efficient toxic doxorubicin hydrochloride removal from aqueous solutions using facial alumina nanorods, Journal of Molecular Structure, 1272, (2023), 134187 https://doi.org/10.1016/j.molstruc.2022.134187
  3. Md Shad Salman, Md Chanmiya Sheikh, Md Munjur Hasan, Md Nazmul Hasan, Khadiza Tul Kubra, Ariyan Islam Rehan, Mrs Eti Awual, Adiba Islam Rasee, R. M. Waliullah, Mohammed Sohrab Hossain, Md Abdul Khaleque, Abdulmohsen K. D. Alsukaibi, Hamed M. Alshammari, Md Rabiul Awual, Chitosan-coated cotton fiber composite for efficient toxic dye encapsulation from aqueous media, Applied Surface Science, 622, (2023), 157008 https://doi.org/10.1016/j.apsusc.2023.157008
  4. Ankit Kumar Vishwakarma, Ajaya Kumar Sharma, Ashok Kumar Mishra, Lallan Yadava, A titanium dioxide-based thick film gas sensor for propanol, Materials Letters: X, 17, (2023), 100184 https://doi.org/10.1016/j.mlblux.2023.100184
  5. Sry Wahyuni, Syukri Syukri, Syukri Arief, Green synthesis of Ag/TiO2 Nanocomposite Assisted by Gambier Leaf (Uncaria gambir Roxb) Extract, Jurnal Kimia Sains dan Aplikasi, 22, 6, (2019), 250-255 https://doi.org/10.14710/jksa.22.6.250-255
  6. Wanbiao Hu, Liping Li, Guangshe Li, Yun Liu, Ray L. Withers, Atomic-scale control of TiO6 octahedra through solution chemistry towards giant dielectric response, Scientific Reports, 4, (2014), 6582 https://doi.org/10.1038/srep06582
  7. Sherly Kasuma Warda Ningsih, Muhammad Iqbal Syauqi, Rahmat Wibowo, Jarnuzi Gunlazuardi, Effect of potential variation on morphology and photoelectrochemical properties of TiO2 nanotube arrays (TNAs) by two-step anodization method, Journal of Applied Electrochemistry, 54, 4, (2024), 739-756 https://doi.org/10.1007/s10800-023-01999-5
  8. I. A. T. Gaia, E. V. Guimarães, P. I. S. Maia, H. D. Mikhail, M. S. da Luz, A. C. A. S, R. S. Silva, Synthesis and investigation of optical and structural properties of Bi2O3/Bi2S3 nanoparticles in an aqueous solution, Physica B: Condensed Matter, 662, (2023), 414947 https://doi.org/10.1016/j.physb.2023.414947
  9. Minghua Wang, Longyu Yang, Jinyun Yuan, Linghao He, Yingpan Song, Hongzhong Zhang, Zhihong Zhang, Shaoming Fang, Heterostructured Bi2S3@NH2-MIL-125(Ti) nanocomposite as a bifunctional photocatalyst for Cr(VI) reduction and rhodamine B degradation under visible light, RSC Advances, 8, 22, (2018), 12459-12470 https://doi.org/10.1039/C8RA00882E
  10. Qingyao Wang, Zhiyuan Liu, Rencheng Jin, Ying Wang, Shanmin Gao, SILAR preparation of Bi2S3 nanoparticles sensitized TiO2 nanotube arrays for efficient solar cells and photocatalysts, Separation and Purification Technology, 210, (2019), 798-803 https://doi.org/10.1016/j.seppur.2018.08.050
  11. Abrar Ahmad, Fatih Tezcan, Gurbet Yerlikaya, Rehman Zia ur, Halime Paksoy, Gülfeza Kardaş, Three dimensional rosette-rod TiO2/Bi2S3 heterojunction for enhanced photoelectrochemical water splitting, Journal of Alloys and Compounds, 868, (2021), 159133 https://doi.org/10.1016/j.jallcom.2021.159133
  12. P. Sreedev, V. Rakhesh, N. S. Roshima, Balakrishnan Shankar, Preparation of Zinc Oxide Thin films by SILAR method and its Optical analysis, Journal of Physics: Conference Series, 1172, (2019), 012024 https://doi.org/10.1088/1742-6596/1172/1/012024
  13. Xinli Li, Xueyang Han, Di Zhu, Yongchao Chen, Lihua Li, Zhanhong Ma, Yongjun Gu, Fengzhang Ren, Jinliang Huang, Improvement of photoelectric properties of TiO2/Bi2S3 composite film by annealing treatment, Optical Materials, 91, (2019), 101-107 https://doi.org/10.1016/j.optmat.2019.03.015
  14. B. R. Sankapal, R. S. Mane, C. D. Lokhande, Successive ionic layer adsorption and reaction (SILAR) method for the deposition of large area (∼10 cm2) tin disulfide (SnS2) thin films, Materials Research Bulletin, 35, 12, (2000), 2027-2035 https://doi.org/10.1016/S0025-5408(00)00405-0
  15. Ines Khemissi, Lotfi Khezami, Khaled Trabelsi, Ahlem Guesmi, Abdessalem Kouki, John Kiwi, Brahim Bessais, Sami Rtimi, Anouar Hajjaji, Stable Ta2O5 nanotubes decorated by PbS by the SILAR method for photocatalytic dye degradation, Journal of Photochemistry and Photobiology A: Chemistry, 444, (2023), 114937 https://doi.org/10.1016/j.jphotochem.2023.114937
  16. Hawraa Sabah Hreo, Araa Mebdir Holi, Asla Abdullah Al-Zahrani, Asmaa Kadim Ayal, M. R. Almamari, Highly crystalline anatase TiO2 nanotubes array films enhanced with Bi2S3 for photoelectrochemical applications, Bulletin of Materials Science, 45, 4, (2022), 205 https://doi.org/10.1007/s12034-022-02781-7
  17. Samantha Prabath Ratnayake, Jiawen Ren, Elena Colusso, Massimo Guglielmi, Alessandro Martucci, Enrico Della Gaspera, SILAR Deposition of Metal Oxide Nanostructured Films, Small, 17, 49, (2021), 2101666 https://doi.org/10.1002/smll.202101666
  18. F. K. An'nur, B. V. Wihelmina, J. Gunlazuardi, R. Wibowo, Tandem system of dyes sensitized solar cell–photo electro chemical (DSSC-PEC) employing TiO2 nanotube/BiOBr as dark cathode for nitrogen fixation, AIP Conference Proceedings, 2243, (2020), 020002 https://doi.org/10.1063/5.0001100
  19. Prita Amelia, Jarnuzi Gunlazuardi, Development of BiOBr/TiO2 nanotubes electrode for conversion of nitrogen to ammonia in a tandem photoelectrochemical cell under visible light, International Journal of Renewable Energy Development, 12, 4, (2023), 702-710 https://doi.org/10.14710/ijred.2023.51314
  20. Teressa Binte Mohsin, S. M. Abidul Islam, Tahmina Tabassum Tonni, M. M. Rhaman, Analysis of conductivity and band-gap energy of bismuth ferrite nanoparticles as prospective photovoltaic material, Materials Today: Proceedings, (2023), https://doi.org/10.1016/j.matpr.2023.01.330
  21. Naeimeh Sadat Peighambardoust, Shahin Khameneh Asl, Raheleh Mohammadpour, Shahab Khameneh Asl, Band-gap narrowing and electrochemical properties in N-doped and reduced anodic TiO2 nanotube arrays, Electrochimica Acta, 270, (2018), 245-255 https://doi.org/10.1016/j.electacta.2018.03.091
  22. Mahnaz Darrudi, Hossein Tavakol, Mohamad Mohsen Momeni, Electrochemical co-deposition of cobalt and graphene, produced from recycled polypropylene, on TiO2 nanotube as a new catalyst for photoelectrochemical water splitting, International Journal of Hydrogen Energy, 48, 9, (2023), 3495-3510 https://doi.org/10.1016/j.ijhydene.2022.10.145
  23. T. Raguram, K. S. Rajni, Synthesis and characterisation of Cu - Doped TiO2 nanoparticles for DSSC and photocatalytic applications, International Journal of Hydrogen Energy, 47, 7, (2022), 4674-4689 https://doi.org/10.1016/j.ijhydene.2021.11.113
  24. Zhi Wu, Ding Yuan, Sheng Lin, Wenxi Guo, Dongping Zhan, Lan Sun, Changjian Lin, Enhanced photoelectrocatalytic activity of Bi2S3–TiO2 nanotube arrays hetero-structure under visible light irradiation, International Journal of Hydrogen Energy, 45, 56, (2020), 32012-32021 https://doi.org/10.1016/j.ijhydene.2020.08.258
  25. J. L. Qiao, Q. Y. Wang, J. X. Ye, Y. K. Xiao, Enhancing photoelectrochemical performance of TiO2 nanotube arrays by CdS and Bi2S3 co-sensitization, Journal of Photochemistry and Photobiology A: Chemistry, 319-320, (2016), 34-39 https://doi.org/10.1016/j.jphotochem.2015.12.020

Last update:

  1. Contemporary Progress on Multifarious Coordination Polymers for Organocatalytic, Sensing and Energy Mimetic Applications

    Shankab J. Phukan, Suraj Goswami, Neeraj K. Sah, Pranshu K. Gupta, Abhishek Rai, Tapas Ghatak, Chandni Pathak, Manas Roy, Ranjith Krishna Pai, Lallan Mishra, Somenath Garai. Materials Today Energy, 2024. doi: 10.1016/j.mtener.2024.101703

  2. Contemporary progress on multifarious coordination polymers for organocatalytic, sensing, and energy-mimetic applications

    Shankab J. Phukan, Suraj Goswami, Neeraj K. Sah, Pranshu K. Gupta, Abhishek Rai, Tapas Ghatak, Chandni Pathak, Manas Roy, Ranjith Krishna Pai, Lallan Mishra, Somenath Garai. Materials Today Energy, 46 , 2024. doi: 10.1016/j.mtener.2024.101703

Last update: 2024-11-21 03:22:42

No citation recorded.