Effect of Precursors Concentration on The Optical and Photoelectrochemical Properties of Bi₂S₃/TiO₂ Nanotubes Arrays Photoanode Synthesized by the SILAR Technique

Eko Martin Sinaga; Muhammad Iqbal Syauqi; Jarnuzi Gunlazuardi

doi:10.14710/jksa.27.6.265-270

DOI: https://doi.org/10.14710/jksa.27.6.265-270

Effect of Precursors Concentration on The Optical and Photoelectrochemical Properties of Bi₂S₃/TiO₂ Nanotubes Arrays Photoanode Synthesized by the SILAR Technique

Eko Martin Sinaga

, Muhammad Iqbal Syauqi

, Jarnuzi Gunlazuardi

Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Depok, 16424, Indonesia

Received: 13 Jan 2024; Revised: 8 May 2024; Accepted: 28 May 2024; Published: 30 Jun 2024.

BibTex Citation Data :

@article{JKSA61451,
    author = {Eko Martin Sinaga and Muhammad Iqbal Syauqi and Jarnuzi Gunlazuardi},
    title = {Effect of Precursors Concentration on The Optical and Photoelectrochemical Properties of Bi₂S₃/TiO₂ Nanotubes Arrays Photoanode Synthesized by the SILAR Technique},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {27},
    number = {6},
    year = {2024},
    keywords = {Bi₂S₃; Precursor concentration; SILAR; TiO₂ NTs},
    abstract = { The use of robust solar energy-driven photocatalysis materials to address the global energy and environmental crisis has gained significant attention in recent years. However, the wide band gaps in many robust semiconductor photocatalysts hinder their absorption of visible light from the solar spectrum. To address this issue, the modification of the large band gap semiconductor with the lower band gap material using the Successive Ionic Layers Adsorption and Reaction (SILAR) technique has emerged as an economical, accessible, and reproducible method for depositing nanoscale materials onto semiconductor substrates. This research aims to know how the concentration variation of cation and anion precursors in the SILAR technique affects the optical and photoelectrochemical properties of the resulting composite materials. Bi₂S₃ serves as a modifier for TiO₂ nanotube arrays (NTAs). The result shows that the cation-anion concentration ratio of 1:1.5 mM with five SILAR cycles gives the best photoelectrochemical performance, with a stable current density of 0.12 mA/cm², compared to pristine TiO₂ NTAs the current density of Bi₂S₃/TiO₂ NTAs is 15-fold. In addition, at each variation, the concentration ratio of cation and anion precursors decreases bandgap energy with each increase in the SILAR cycle. },
   issn = {2597-9914},   pages = {265--270}  doi = {10.14710/jksa.27.6.265-270},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/61451}
}

Citation Format:

Abstract

The use of robust solar energy-driven photocatalysis materials to address the global energy and environmental crisis has gained significant attention in recent years. However, the wide band gaps in many robust semiconductor photocatalysts hinder their absorption of visible light from the solar spectrum. To address this issue, the modification of the large band gap semiconductor with the lower band gap material using the Successive Ionic Layers Adsorption and Reaction (SILAR) technique has emerged as an economical, accessible, and reproducible method for depositing nanoscale materials onto semiconductor substrates. This research aims to know how the concentration variation of cation and anion precursors in the SILAR technique affects the optical and photoelectrochemical properties of the resulting composite materials. Bi₂S₃ serves as a modifier for TiO₂ nanotube arrays (NTAs). The result shows that the cation-anion concentration ratio of 1:1.5 mM with five SILAR cycles gives the best photoelectrochemical performance, with a stable current density of 0.12 mA/cm², compared to pristine TiO₂ NTAs the current density of Bi₂S₃/TiO₂ NTAs is 15-fold. In addition, at each variation, the concentration ratio of cation and anion precursors decreases bandgap energy with each increase in the SILAR cycle.

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Keywords: Bi₂S₃; Precursor concentration; SILAR; TiO₂ NTs

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Section: Research Articles

Language : EN

In Vol 27, No 6 (2024): Volume 27 Issue 6 Year 2024

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