DOI: https://doi.org/10.14710/jksa.27.12.603-610

Optimization of Zn/Al-Oxalate Hydrotalcite as an Environmentally Friendly Adsorbent for Dye Waste Processing

Department of Chemistry, Faculty of Sciences and Mathematics, Jenderal Soedirman University, Purwokerto, Indonesia

Received: 24 Jul 2024; Revised: 30 Dec 2024; Accepted: 30 Dec 2024; Published: 31 Dec 2024.
Open Access Copyright 2024 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
Methylene blue is a synthetic dye commonly used in the textile industry. Methylene blue waste that is discharged into water bodies without treatment causes environmental pollution. One method of waste treatment is adsorption. Hydrotalcite is an anionic clay consisting of stacked positively charged layers, usually divalent (+2) and trivalent (+3) metal cations, and has anions between the layers. This study aims to determine the synthesis method of Zn/Al-Oxalate hydrotalcite, and its characterization results are compared with Zn/Al-NO3 hydrotalcite to determine the optimum conditions of Zn/Al-Oxalate hydrotalcite in adsorbing methylene blue dye and to determine the kinetic and isotherm models of adsorption. Zn/Al-Oxalate hydrotalcite was successfully synthesized by the coprecipitation method and continued with the hydrothermal process at a temperature of 120°C for 20 hours. Hydrotalcite Zn/Al-Oxalate was characterized using FTIR and XRD. The optimum condition of hydrotalcite Zn/Al-Oxalate in adsorbing methylene blue dye was carried out by the batch method at optimum pH 7, contact time 60 minutes, adsorbent weight 80 mg, and methylene blue concentration 20 mg/L. The adsorption kinetics of hydrotalcite Zn/Al-Oxalate in adsorbing methylene blue followed the pseudo-second-order model. with a value of R2 = 0.9996 and k = 0.2047 mg/g.min and the adsorption isotherm follows the Langmuir adsorption isotherm model R2 = 0.9904, qm = 19.8413 mg/g and kL = 2.913 L/mg.
Fulltext View|Download
Keywords: Hydrotalcite; adsorption isotherm; adsorption kinetics; methylene blue

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Thermodynamic Study of Chitosan as a Corrosion Inhibitor for Carbon Steel in Chloride Solutions (NaCl and HCl) at Various Temperatures and Concentrations An Investigation into the Anti-Aggregation Potential of Swietenia macrophylla Triterpenoid on Bovine Serum Albumin: Docking and RMSF Optimization of Zn/Al-Oxalate Hydrotalcite as an Environmentally Friendly Adsorbent for Dye Waste Processing More recent articles
Most cited articles
Penentuan Total Kadar Fenol dari Daun Kersen Segar, Kering dan Rontok (Muntingia calabura L.) serta Uji Aktivitas Antioksidan dengan Metode DPPH Activity of Actinomycetes Isolated from Mangrove Segara Anakan Cilacap toward Methicillin-resistant Staphylococcus aureus (MRSA) Dealuminasi Zeolit Alam Cipatujah Melalui Penambahan Asam dan Oksidator Pemanfaatan Karbon Aktif Serbuk Gergaji Kayu Jati untuk Menurunkan Chemical Oxygen Demand (COD) Limbah Cair Industri Tekstil Isolasi Senyawa Antioksidan dari Fraksi Etil Asetat Daun Tempuyung (Sonchus arvensis L) More cited articles
  1. Iwan Hermawan, Analisis dampak kebijakan makroekonomi terhadap perkembangan industri tekstil dan produk tekstil Indonesia, Bulletin of Monetary Economics Banking, 13, 4, (2011), 7 https://doi.org/10.21098/bemp.v13i4.269
  2. Ni Putu Diantariani, Iryanti Eka Suprihatin, Ida Ayu Gede Widihati, Fotodegradasi zat warna tekstil methylene blue dan congo red menggunakan komposit ZnO-AA dan sinar UV, Jurnal Kimia, 10, 1, (2016), 133-140 https://doi.org/10.24843/JCHEM.2016.v10.i01.p18
  3. Shuyang Chen, Mei Zhang, Hanjie Chen, Ying Fang, Removal of Methylene Blue from Aqueous Solutions by Surface Modified Talc, Materials, 16, 9, (2023), 3597 https://doi.org/10.3390/ma16093597
  4. Dilla Sistesya, Heri Sutanto, Sifat Optis Lapisan ZnO:Ag yang Dideposisi di atas Substrat Kaca Menggunakan Metode Chemical Solution Deposition (CSD) dan Aplikasinya pada Degradasi Zat Warna Methylene Blue, Youngster Physics Journal, 2, 3, (2013), 71-80
  5. Ming Xu, Bo Bi, Bingbing Xu, Zhixia Sun, Lin Xu, Polyoxometalate-intercalated ZnAlFe-layered double hydroxides for adsorbing removal and photocatalytic degradation of cationic dye, Applied Clay Science, 157, (2018), 86-91 https://doi.org/10.1016/j.clay.2018.02.023
  6. Lili Xiao, Wei Ma, Mei Han, Zihong Cheng, The influence of ferric iron in calcined nano-Mg/Al hydrotalcite on adsorption of Cr (VI) from aqueous solution, Journal of Hazardous Materials, 186, (2011), 690-698 https://doi.org/10.1016/j.jhazmat.2010.11.052
  7. Chunping Chen, Poernomo Gunawan, Rong Xu, Self-assembled Fe3O4-layered double hydroxide colloidal nanohybrids with excellent performance for treatment of organic dyes in water, Journal of Materials Chemistry, 21, 4, (2011), 1218-1225 https://doi.org/10.1039/C0JM01696A
  8. R. Extremera, I. Pavlovic, M. R. Pérez, C. Barriga, Removal of acid orange 10 by calcined Mg/Al layered double hydroxides from water and recovery of the adsorbed dye, Chemical Engineering Journal, 213, (2012), 392-400 https://doi.org/10.1016/j.cej.2012.10.042
  9. Neza Rahayu Palapa, Arini Fousty Badri, Risfidian Mohadi, Tarmizi Taher, Aldes Lesbani, Mg/Cr-(COO)22- layered double hydroxide for malachite green removal, Communications in Science Technology, 7, 1, (2022), 91-97 https://doi.org/10.21924/cst.7.1.2022.851
  10. Xingzhong Guo, Pengan Yin, Hui Yang, Superb adsorption of organic dyes from aqueous solution on hierarchically porous composites constructed by ZnAl-LDH/Al(OH)3 nanosheets, Microporous and Mesoporous Materials, 259, (2018), 123-133 https://doi.org/10.1016/j.micromeso.2017.10.003
  11. Jingwan Huo, Xiaopeng Min, Qianqian Dong, Shangping Xu, Yin Wang, Comparison of Zn–Al and Mg–Al layered double hydroxides for adsorption of perfluorooctanoic acid, Chemosphere, 287, (2022), 132297 https://doi.org/10.1016/j.chemosphere.2021.132297
  12. L. Silaen, M. F. Azmi, N. R. Palapa, R. Mohadi, Elfita, A. Lesbani, Synthesis of macroanion [α-SiW12O40]4- as pillaring agents to layered double hydroxide Zinc-M3+, IOP Conference Series: Materials Science and Engineering, 902, (2020), 012048 https://doi.org/10.1088/1757-899X/902/1/012048
  13. Dian W. Dwiasi, Mudasir Mudasir, Roto Roto, Solid-phase extraction of amoxicillin in aqueous system by using Mg-Al-oxalate LDH as a stationary phase, Rasayan Journal of Chemistry, 13, 4, (2020), 2523-2529 https://doi.org/10.31788/RJC.2020.1345970
  14. Mustafa Özdemir, Özkan Durmuş, Ömer Şahin, Cafer Saka, Removal of methylene blue, methyl violet, rhodamine B, alizarin red, and bromocresol green dyes from aqueous solutions on activated cotton stalks, Desalination and Water Treatment, 57, 38, (2016), 18038-18048 https://doi.org/10.1080/19443994.2015.1085916
  15. Arini Fousty Badri, Novie Juleanti, Neza Rahayu Palapa, Yuliza Hanifah, Risfidian Mohadi, Mardiyanto Mardiyanto, Aldes Lesbani, Oxalate Intercalated Mg/Cr Layered Double Hydroxide as Adsorbent of Methyl Red and Methyl Orange From Aqueous Solution, Ecological Engineering & Environmental Technology, 22, 3, (2021), 71-81 https://doi.org/10.12912/27197050/135509
  16. Indah Riwayati, Suwardiyono Suwardiyono, Adsorpsi Zat Warna Methylene Blue Menggunakan Abu Alang-Alang (Imperata Cylindrica) Teraktivasi Asam Sulfat, Jurnal Inovasi Teknik Kimia, 4, 2, (2019), http://dx.doi.org/10.31942/inteka.v4i2.3016
  17. Marta Estrada-Ruiz, Daniel Cosano, Dolores Esquivel, Francisco J. Romero-Salguero, José Rafael Ruiz, 3D Hierarchical Composites of Hydrotalcite-Coated Carbon Microspheres as Catalysts in Baeyer–Villiger Oxidation Reactions, Crystals, 14, 10, (2024), 878 https://doi.org/10.3390/cryst14100878
  18. Paryanto Paryanto, Sunu Herwi Pranolo, Penyerapan Gas Karbon Dioksida (CO2) dalam Biogas dengan Larutan Calsium Hidroksida (Ca(OH)2), Ekuilibrium, 10, 2, (2022), 55-60
  19. Sung-Man Kim, In-Ho Yoon, Il-Gook Kim, Chan Woo Park, YoungHo Sihn, June-Hyun Kim, So-Jin Park, Cs desorption behavior during hydrothermal treatment of illite with oxalic acid, Environmental Science and Pollution Research, 27, 28, (2020), 35580-35590 https://doi.org/10.1007/s11356-020-09675-3
  20. James T. Richardson, Principles of Catalyst Development, Springer New York, NY, 1989, ^ https://doi.org/10.1007/978-1-4899-3725-4
  21. Khairun Nisah, Husniah Nadhifa, Analisis kadar logam Fe dan Mn pada air minum dalam kemasan (AMDK) dengan metode spektrofotometri serapan atom, Amina, 2, 1, (2020), 6-12 https://doi.org/10.22373/amina.v2i1.491
  22. Laura Dwi Rha Hayu, Edi Nasra, Minda Azhar, Sri Benti Etika, Adsorpsi Zat Warna Methylene Blue Menggunakan Karbon Aktif dari Kulit Durian (Durio zibethinus Murr.), Periodic, 10, 2, (2022), 8-13 https://doi.org/10.24036/p.v11i1.113349
  23. Doungmo Giscard, Théophile Kamgaing, Ranil Clément Tonleu Temgoua, Ervice Ymele, Francis Merlin Melataguia Tchieno, Ignas Kenfack Tonlé, Intercalation of oxalate ions in the interlayer space of a layered double hydroxide for nickel ions adsorption, International Journal of Basic and Applied Sciences, 5, 2, (2016), 144-150 https://doi.org/10.14419/ijbas.v5i2.5672
  24. Fatima Zahra Mahjoubi, Abderrahim Khalidi, Mohamed Abdennouri, Noureddine Barka, Zn–Al layered double hydroxides intercalated with carbonate, nitrate, chloride and sulphate ions: Synthesis, characterisation and dye removal properties, Journal of Taibah University for Science, 11, 1, (2017), 90-100 https://doi.org/10.1016/j.jtusci.2015.10.007
  25. Anselmus Boy Baunsele, Hildegardis Missa, Kajian kinetika adsorpsi metilen biru menggunakan adsorben sabut kelapa, Akta Kimia Indonesia, 5, 2, (2020), 76-85 http://dx.doi.org/10.12962/j25493736.v5i2.7791
  26. Sri Handayani, Cahyorini Kusumawardani, Kun Sri Budiasih, Sintesis dan Karakterisasi Hidrotalsit Mg/Al dengan Metode Kopresipitasi Hidrotermal untuk Reaksi Kondensasi Aldol, Jurusan Pendidikan Kimia, Universitas Negeri Yogyakarta, 2015

Last update:

No citation recorded.

Last update: 2025-01-21 11:50:10

No citation recorded.