Polimerisasi Eugenol Dengan Katalis Asam Sulfat Pekat

*Ngadiwiyana Ngadiwiyana scopus  -  Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
Published: 1 Aug 2005.
Open Access Copyright 2005 Jurnal Kimia Sains dan Aplikasi
License URL: http://creativecommons.org/licenses/by-sa/4.0/

Citation Format:
Abstract

Telah dilakukan polimerisasi kationik terhadap eugenol dengan menggunakan katalis asam sulfat pekat tanpa menggunakan media pelarut. Polimerisasi ini dilakukan pada suhu kamar, diperoleh hasil berbentuk padatan yang berwarna keungu-unguan dengan titik lebur 860C. Polimer yang terbentuk tidak larut dalamk air tetapi larut dalam aseton, etanol dan benzena. Identifikasi hasil dilakukan dengan spektrofotometri Infra Merah (FTIR) dan spektroskopi 1H-NMR. Berat molekul poli(eugenol) ditentukan dengan metode viskometri, diperoleh harga Mv = 7800,75 atau DP = 48

Keywords: eugenol; polimerisasi; viskometri

Article Metrics:

Article Info
Section: Research Articles
Language: ID
In Vol 8, No 2 (2005): Volume 8 Issue 2 Year 2005
Statistics: 1903 2936
Related articles
Pemanfaatan Kitosan Termodifikasi Asam Askorbat Sebagai Adsorben Ion Logam Kobalt (II) dan Nikel (II) Uji Aktivitas Antioksidan dengan DPPH fraksi Etil Asetat Daun Bidens pilosa L. Identifikasi Senyawa Penyusun Minyak Kulit Batang Kayu Manis (Cinnamomum cassia) Menggunakan GC-MS Potential Adsorption of Heavy Metal Ions by Eugenol Compounds and Derivatives through Ion Imprinted Polymer Optimasi Metoda CV-AAS untuk Analisis Raksa(II) Efektivitas Fotodegradasi Amoksisilin yang Dikatalisis dengan TiO2 dengan Keberadaan Ion Ag(I)
  1. Anwar, C.,1994, The Conversion of Eugenolin to more Valuable Substances, Desertasi, FMIPA UGM, Yogyakarta
  2. Cowd, M.A., 1985, Polimer Chemistry, diterjemahkan oleh Harry Firman, 1991
  3. Daly, W.H., S. Moulay, 1986, Synthesis of Poly(vinylcatechols), J. Polym. Sci. Polymer Symposium
  4. Fessenden, R.J., J.S. Fessenden, 1989, Organic Chemistry, diterjemahkan oleh A. Hadyana Pudjaatmaka, 1991, Kimia Organik, jilid I, Penerbit Airlangga, Jakarta
  5. Guenther, E., 1952, The Essential Oil, volume V, D. Van Norstrand Co. Inc., New York
  6. Hardjono Sastrohamidjojo, 1985, Spektroskopi, Edisi Pertama, Penerbit Liberty, Yogyakarta
  7. Intiningsih, 1995, Polimerisasi Amilisoeugenol dengan Katalis Asam Sulfat Pekat, skripsi, FMIPA-UGM, Yogyakarta
  8. Ketaren, S., 1985, Pengantar Teknologi Minyak Atsiri, PN Balai Pustaka, Jakarta
  9. March, J., 1977, Advanced Organic Chemistry, Reactions, Mechanisms, and Structures, Second Edition, Mc. Graw Hill International Book Company, Aucklan
  10. Norman, R.O.C., 1978, Principle of Organic Synthesis, 2nd edition, Chapman and Hall, London
  11. Rosenthal, L.C., 1990, A Polymer Viscosity Experiment with No Right Answer, J. Chem. Educ
  12. Setiadi, T., 1986, Ekspor Minyak Atsiri Indonesia, Proceeding Diskusi Minyak Atsiri V, Departement Perindustrian Indonesia
  13. Solomons, T.W.G., 1982, Fundamental of Organic Chemistry, John Willey and Son, New York
  14. Steven, M.P., 1975, Polymer Chemistry An Introduction, Addison Weshley Publishing Company, Inc., London
  15. Sudri, N.M., 1989, Studi Polimerisasi Metilisoeugenol dengan Katalis Boron Trifluorida Dietil Eter Kompleks, skripsi, FMIPA-UGM, Yogyakarta
  16. Vogel, A.I., 1956, Text Book of Practical Organic Chemistry, Third edition, The English Language Book Society and Longman, New York

Last update: 2021-03-04 01:16:08

  1. Synthesis of copolymer eugenol crosslinked with divinyl benzene and preliminary study on its antibacterial activity

    Nor Basid Adiwibawa Prasetya, Ngadiwiyana, Ismiyarto, Purbowatiningrum Ria Sarjono. IOP Conference Series: Materials Science and Engineering, 127 , 2019. doi: 10.1088/1757-899X/509/1/012102

  2. Potential Adsorption of Heavy Metal Ions by Eugenol Compounds and Derivatives through Ion Imprinted Polymer

    Muhammad Cholid Djunaidi, Khabibi Khabibi. Jurnal Kimia Sains dan Aplikasi, 22 (6), 2019. doi: 10.14710/jksa.22.6.263-268

  3. Synthesis and study of antibacterial activity of polyeugenol

    Nor Basid Adiwibawa Prasetya, Ngadiwiyana, Ismiyarto, Purbowatiningrum Ria Sarjono. IOP Conference Series: Materials Science and Engineering, 127 , 2019. doi: 10.1088/1757-899X/509/1/012101

  4. Effects of percent weight of divinylbenzene as crosslinking agent on the properties of eugenol–divinylbenzene copolymers

    N B A Prasetya, N Ngadiwiyana, I Ismiyarto, P R Sarjono. Journal of Physics: Conference Series, 127 , 2020. doi: 10.1088/1742-6596/1524/1/012089

  5. Antibacterial activity of polyeugenol againststaphylococcus aureusandescherichia coli

    D S Handayani, Pranoto, D A Saputra, S D Marliyana. IOP Conference Series: Materials Science and Engineering, 127 , 2019. doi: 10.1088/1757-899X/578/1/012061

  6. Effect of initial temperature and concentration of catalyst in polyeugenol production

    Widayat, Alviano Fatuchrohman, Ellen Gustiasih. AIP Conference Proceedings, 127 , 2015. doi: 10.1063/1.4938322

Last update: 2021-03-04 01:16:08

  1. Synthesis of copolymer eugenol crosslinked with divinyl benzene and preliminary study on its antibacterial activity

    Nor Basid Adiwibawa Prasetya, Ngadiwiyana, Ismiyarto, Purbowatiningrum Ria Sarjono. IOP Conference Series: Materials Science and Engineering, 127 , 2019. doi: 10.1088/1757-899X/509/1/012102

  2. Antibacterial and antioxidant activities of polyeugenol with high molecular weight

    Rahim E.A.. Indonesian Journal of Chemistry, 20 (3), 2020. doi: 10.22146/ijc.44659

  3. Synthesis and study of antibacterial activity of polyeugenol

    Nor Basid Adiwibawa Prasetya, Ngadiwiyana, Ismiyarto, Purbowatiningrum Ria Sarjono. IOP Conference Series: Materials Science and Engineering, 127 , 2019. doi: 10.1088/1757-899X/509/1/012101

  4. Synthesis of copoly-(eugenol-stearyl acrylate) via cationic polymerization

    Handayani D.. Journal of Physics: Conference Series, 127 (1), 2019. doi: 10.1088/1742-6596/1153/1/012124
Copyright 2005 Jurnal Kimia Sains dan Aplikasi
License URL: http://creativecommons.org/licenses/by-sa/4.0/

As an article writer, the author has the right to use their articles for various purposes, including use by institutions that employ authors or institutions that provide funding for research. Author rights are granted without special permission.

Author who publishes a paper at JKSA has the broad right to use their work for teaching and scientific purposes without the need to ask permission, including: used for (i) teaching in the author's class or institution, (ii) presentation at meetings or conferences and distributing copies to participants ; (iii) training conducted by the author or author's institution; (iv) distribution to colleagues for research use; (v) use in the compilation of subsequent authors' works; (vi) inclusion in a thesis or dissertation; (vi) reuse of part of the article in another work (with citation); (vii) preparation of derivative works (with citation); (viii) voluntary posting on open websites operated by authors or author institutions for scientific purposes (follow the CC BY-SA License).

Authors and readers can copy and redistribute material in any media or format, and mix, modify, and build material for any purpose but they must provide appropriate credit (provide article citation or content), providing links to the license, and indicate if there are changes.

The authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations.

Reproduce any part of this journal, its storage in the database or its transmission by all forms or media is permitted does not need for written permission from JKSA. However, it should be cited as an honor in academic manners

JKSA and the Chemistry Department of Diponegoro University and the Editor make every effort to ensure that there are no data, opinions, or false or misleading statements published in JKSA. However, the content of the article is the sole and exclusive responsibility of each author.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should be signed originally and send to the Editor in the form of printed letters, scanned documents sent via email or fax.

 

Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id