DOI: https://doi.org/10.14710/presipitasi.v17i1.85-95

Sintesis dan Karakterisasi Zeolit dari Abu Bagasse Sebagai Adsorben Logam Berat Cu(II)

Zeolites Synthesis and Characterization from Bagasse Ash as Cu (II) Heavy Metal Adsorbent

*Adhi Setiawan scopus  -  Politeknik Perkapalan Negeri Surabaya, Indonesia
Jihan Nabillah Hanun  -  Politeknik Perkapalan Negeri Surabaya, Indonesia
Ahmad Erlan Afiuddin  -  Politeknik Perkapalan Negeri Surabaya, Indonesia

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Abstract
The relatively high silica content in bagasse ash can be used as raw material for making zeolite. Zeolite can be used as a heavy metal adsorbent in industrial wastewater treatment. This study aims to synthesize zeolite from bagasse ash and to apply zeolite as an adsorbent of Cu(II) in a continuous system reactor. The effects of contact time, zeolite size, and concentration of Cu(II) solution on the removal efficiency of metals have been studied in this research. The synthesis of zeolite was carried out using the hydrothermal method at 100°C for 7 hours. The synthesized zeolite was characterized using SEM-EDX, XRD, FTIR, and BET The adsorption process was carried out using a continuous reactor with a flow rate of 0.4 L/min and flowed for 60 minutes with sampling at 15-minute intervals. The zeolite size used was 100 and 200 mesh. The results of SEM-EDX analysis showed that Zeolite has an irregular morphology and contains Si at 35.15%. The XRD results show that the zeolite crystallinity is relatively low. The specific surface area of zeolite at size 100 mesh and 200 mesh were 439.48 m2 /g and 697.76 m2/g respectively. The best Cu(II) waste adsorption test results were obtained under zeolite conditions with a particle size of 200 mesh, the concentration of Cu(II) wastewater of 25 mg/L, and an operational time of 60 minutes with a removal efficiency of Cu(II) of 41.57%
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Keywords: sugarcane bagasse ash, hydrothermal, zeolite

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Section: Original Research Article
Language : ID
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  1. Ariska, D., Hadiwidodo, M., & Wardhana, I.W. 2013. Pemanfaatan Residu Bahan Bakar Batu Bara (Bottom Ash) Sebagai Adsorben Zat Warna Reaktif Dan Logam Berat (Cu dan Ni) dari Limbah Cair Tekstil Dengan Reaktor Sistem Kontinyu (Studi Kasus: Limbah Cair PT. APAC Inti Corpora)
  2. Institutional Repository Departemen Teknik Lingkungan Fakultas Teknik Universitas Diponegoro
  3. Asl, S.M.H., Javadian, H., Khavarpour, M ., Belviso, C., Taghavi, M., & Maghsudi, M. 2019. Porous Adsorbents Derived from Coal Fly Ash as Cost-Effective and Environmentally-Friendly Sources of Aluminosilicate for Sequestration of Aqueous And Gaseous Pollutants: A Review. Journal Clean Production, 208, 1131–1147
  4. Balakrishnan, M., & Batra, V.S. 2011. Valorization of Solid Waste in Sugar Factories with Possible Applications in India: A Review. Journal of Environmental Management, 92(11), 2886–2891
  5. Belviso, C. 2018. State of The Art Applications of fly Ash From Coal and Biomass: A Focus on Zeolite Synthesis Processes and Issues. Progress in Energy Combustion Science, 65, 109–135
  6. Das, G., Pradhan, N.C., Madhu, G.M., & Preetham, H.S. 2013. Removal of Cadmium from Aqueous Streams by Zeolites Synthesized from Fly Ash. Journal of Materials and Environmental Science, 4, 410–419
  7. Goscianska, J., Ptaszkowska-Koniarz, M., Frankowski, M., Franus, M., Panek, R., & Franus, W. 2018. Removal of Phosphate from Water by Lanthanum-Modified Zeolites Obtained from Fly Ash. Journal of Colloid and Interface Science, 513, 72–81
  8. Moises, M.P., da Silva, C.T.P., Meneguin, J.G., Girotto, E.M., Radovanovic, E. 2013. Synthesis of Zeolite NaA from Sugarcane Bagasse Ash. Materials Letters, 108, 243–246
  9. Nibou, D., Mekatel, H., Amokrane, S., Barkat, M., & Trari, M. 2010. Adsorption of Zn2+ Ions onto NaA and NaX Zeolites: Kinetic, Equilibrium and Thermodynamic Studies. Journal of Hazardous Materials, 173(1¬–3), 637–646
  10. Ojha, K., Pradhan, N.C., dan Samanta, A.N. 2004. Zeolite from Fly Ash: Sinthesis and Characterization. Bulletin of Materials Science, 27(6), 555–564
  11. Oliveira, J.A., Cunha, F.A., & Ruotolo, L.A.M. 2019. Synthesis of Zeolite from Sugarcane Bagasse Fly Ash and Its Application as a Low-Cost Adsorbent to Remove Heavy Metals. Journal of Cleaner Production, 229, 956–963
  12. Poh Ng, E., Hao Chow, J., Mukti, R.R., Muraza, O., Ling, T.C., & Wong, K.L. 2017. Hydrothermal Synthesis of Zeolite A from Bamboo Leaf Biomass and Its Catalytic Activity in Cyanoethylation of Methanol under Autogenic Pressure and Air Conditions. Materials Chemistry and Physics, 201, 78–85
  13. Pratiwi, N.A., & Sunarto, S. 2018. Perbandingan Validasi Metode Analisis Ion Tembaga(II) Tanpa Pengompleks dan Dengan Pengompleks Na-Dietilditiokarbamat Secara Spektrofotometri Uv-Vis. Jurnal Kimia Dasar, 7(3), 96–105
  14. Purnomo, W.C., Salim, C., & Hinode, H. 2012. Synthesis of Pure Na-X and Na-A Zeolite from Bagasse Fly Ash. Microporous and Mesoporous Materials, 162, 6–13
  15. Saceda, J.J.F., de Leon, R.L., Rintramee, K., Prayoonpokarach, S., & Wittayakun, J. 2011. Properties of Silica from Rice Husk and Rice Husk Ash and Their Utilization for Zeolite Y Synthesis. Quimica Nova, 34(8), 1394–1397
  16. Santasnachok, C., Kurniawan, W., Salim, C., & Hinode, H. (2014). The Utility of Rice Husk Ash from Biomass Power Plant: Synthesis of NaA and NaX Zeolites Using The Two Step Method Hydrothermal. Journal of Advanced Agricultural Technologies, 1 (2), 75–81
  17. Setiawan, A., Basyiruddin, F., & Dermawan, D. 2019. Biosorpsi Logam Berat Cu(Ii) Menggunakan Limbah Saccharomyces Cerevisiae. Jurnal Presipitasi, 16(1), 29–35
  18. Shaheen, S.M., Derbalah, A.S., & Moghanm F.S. 2012. Removal of Heavy Metals from Aqueous Solution by Zeolite in Competitive Sorption System. International Journal of Environmental Science and Development, 3(4), 362–367
  19. Shawabkeh, R., Al-Harahsheh, A., Hami, M., & Khlaifat, A. 2004. Conversion of Oil Shale Ash into Zeolite for Cadmium and Lead Removal from Wastewater. Fuel 83, (7–8), 981–985
  20. Sriatun, S., Taslimah, T., Suyati, L. (2018). Synthesis of Zeolite from Bagasse ash Using Cetyltrimethylammonium Bromide as Structure Directing Agent. Indonesian Journal of Chemistry, 18(1) 159–165
  21. Velmurugan, P., Kumar, V.R., & Dhinakaran, G. 2011. Dye Removal from Aqueous Solution Using Low Cost Adsorbent. International Journal of Environmental Sciences, 1(7), 1492–1503
  22. Visa, M. & Popa, N. 2015. Adsorption of Heavy Metals Cations onto Zeolite Material from Aqueous Solution. Journal of Membrane Science and Technology, 5(1), 1–8
  23. Yu, J., Yang, Y., Chen, W., Xu, D., Guo, H., Li, K., & Liu, H. 2016. Synthesis and Application of Zeolitic Material from Fly Ash by One-Pot Method at Low Temperature. Green Energy and Environment, 1(2), 166–171

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