Departement of Chemical Engineering, University of Diponegoro Jl. Prof. Sudharto, Tembalang, Semarang, 50239, Indonesia Tel./Fax: +62-24-7460058, Indonesia
BibTex Citation Data :
@article{IJRED13338, author = {Tutuk Kusworo and Muhammad Hakim and H Hadiyanto}, title = {Enhancement of Hybrid SPEEK Based Polymer–Cyclodextrin-Silica Inorganic Membrane for Direct Methanol Fuel Cell Application}, journal = {International Journal of Renewable Energy Development}, volume = {6}, number = {2}, year = {2017}, keywords = {Direct Methanol Fuel Cell, Poly(ether ether ketone), cyclodextrin-silica, sulfonation, ionic conductivity}, abstract = { Direct methanol fuel cell (DMFC) is one of several types of fuel cells that use proton exchange membrane (PEM) as a liaison between the reaction at the cathode and anode. Polyether-ether ketone (PEEK) is one of the aromatic polymer that can be applied in DMFC because of its characteristics that are resistant to DMFC environment. The polymer is also quite easy in the sulfonation process using concentrated sulfuric acid. However the role of polyether-ether ketone as DMFC membrane material is still lack of advantage due to its low conductivity and therefore the modification is required to increase the value of proton conductivity of the membrane. The purpose of this experiment is to modify the membrane (sPEEK) with the addition of cyclodextrins-silica, additive variation charge of 2%, 6% and 10%, time and temperature were fixed at 4 hours and 65 o C. The results showed the best results of membrane sPEEK was obtained at the addition of -cyclodextrin -silica 10% with the membrane characteristics of ion exchange capacity of 2.19 meq / g polymer, the degree of sulfonation of 81%, methanol permeability of 3.09 x 10-9 cm2 / s and water uptake membrane of 64%. Article History : Received January 18 th 2017; Received in revised form April 21 st 2017; Accepted June 22 nd 2017; Available online How to Cite This Article : Kusworo, T.D., Hakim, M.F. and Hadiyanto, H. (2017) Enhancement of Hybrid SPEEK Based Polymer–Cyclodextrin-Silica Inorganic Membrane for Direct Methanol Fuel Cell Application. International Journal of Renewable Energy Development, 6(2), 165-170. https://doi.org/10.14710/ijred.6.2.165-170 }, pages = {165--170} doi = {10.14710/jis.%v.%i.%Y.316-326}, url = {https://ejournal.undip.ac.id/index.php/ijred/article/view/13338} }
Refworks Citation Data :
Direct methanol fuel cell (DMFC) is one of several types of fuel cells that use proton exchange membrane (PEM) as a liaison between the reaction at the cathode and anode. Polyether-ether ketone (PEEK) is one of the aromatic polymer that can be applied in DMFC because of its characteristics that are resistant to DMFC environment. The polymer is also quite easy in the sulfonation process using concentrated sulfuric acid. However the role of polyether-ether ketone as DMFC membrane material is still lack of advantage due to its low conductivity and therefore the modification is required to increase the value of proton conductivity of the membrane. The purpose of this experiment is to modify the membrane (sPEEK) with the addition of cyclodextrins-silica, additive variation charge of 2%, 6% and 10%, time and temperature were fixed at 4 hours and 65oC. The results showed the best results of membrane sPEEK was obtained at the addition of -cyclodextrin -silica 10% with the membrane characteristics of ion exchange capacity of 2.19 meq / g polymer, the degree of sulfonation of 81%, methanol permeability of 3.09 x 10-9 cm2 / s and water uptake membrane of 64%.
Article History: Received January 18th 2017; Received in revised form April 21st 2017; Accepted June 22nd 2017; Available online
How to Cite This Article: Kusworo, T.D., Hakim, M.F. and Hadiyanto, H. (2017) Enhancement of Hybrid SPEEK Based Polymer–Cyclodextrin-Silica Inorganic Membrane for Direct Methanol Fuel Cell Application. International Journal of Renewable Energy Development, 6(2), 165-170.
https://doi.org/10.14710/ijred.6.2.165-170
Article Metrics:
Last update:
A review on sulfonated poly (ether ether ketone) based‐membrane in direct borohydride fuel cell applications
Synthesis and applicability study of novel poly(dopamine)-modified carbon nanotubes based polymer electrolyte membranes for direct methanol fuel cell
Last update: 2023-12-09 08:58:28
This journal provides immediate open access to its content on the principle that making research freely available to the public supports a greater global exchange of knowledge. Articles are freely available to both subscribers and the wider public with permitted reuse.
All articles published Open Access will be immediately and permanently free for everyone to read and download. We are continuously working with our author communities to select the best choice of license options: Creative Commons Attribution-ShareAlike (CC BY-SA). Authors and readers can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
International Journal of Renewable Energy Development (ISSN:2252-4940) published by CBIORE is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
