skip to main content

Synthesis and Characterization Analysis of Banana Peel Carbon Activated as Adsorption of Copper (Cu)

1Physics Education, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Kentingan, Surakarta, Indonesia, Indonesia

2Department of Physics, University of Riau, Simpang Baru, Pekanbaru 28293, Indonesia., Indonesia

3Research Center for Biomass and Bioproducts, National Research and Innovation Agency, Bogor 16911, Indonesia., Indonesia

Received: 11 Sep 2023; Revised: 19 Feb 2025; Accepted: 17 Apr 2025; Available online: 25 May 2025; Published: 31 May 2025.
Editor(s): Budi Warsito

Citation Format:
Abstract

Activated carbon is a porous material widely used in various industrial and environmental applications, especially as an adsorbent in liquid waste treatment and gas purification. Banana peel, an abundant and renewable carbon source, is an environmentally friendly and sustainable raw material for activated carbon. However, optimization of the activation process is essential to improve the characteristics and adsorption performance of activated carbon. This study aims to evaluate the effect of KOH activation on the synthesis and characterization of banana peel-based activated carbon. Carbonization and chemical activation processes were carried out, then morphology and chemical structure characterization were performed using Field Emission Scanning Electron Microscopy (FE-SEM), Energy Dispersive X-ray (EDX), and Fourier Transform Infrared Spectroscopy (FTIR). The analysis showed that the activated carbon obtained has a well-developed pore structure with a porosity level of 74.80% and contains O-H, C-H, C=O, and C-Cl functional groups, which play a role in metal ion interactions. The hydrophilic nature of the activated carbon was studied through contact angle analysis, while the adsorption capacity towards copper ions (Cu) was determined using an Atomic Absorption Spectrophotometer (AAS). The results showed that the highest adsorption efficiency of 99.99% was achieved on activated carbon with 20% concentration and 15 minutes contact time. With good pore characteristics and high adsorption efficiency, banana peel-based activated carbon has the potential to be an efficient and sustainable adsorbent in heavy metal waste treatment applications. This research provides further insight into the utilization of biomass waste to produce functional materials of high-added value.

Fulltext View|Download
Keywords: Adsorption; Copper (Cu); Activated Carbon; Banana Peel; Carbonization; Potassium hydroxide
Funding: Universitas Sebelas Maret under contract 934/UN27/HK/2023; Universitas Sebelas Maret under contract 194.2/UN27.22/PT.01.03/2024

Article Metrics:

  1. Agarry, S. E., “Anthracene Bioadsorption from Simulated Wastewater by Chemically-Treated Unripe Plantain Peel Bioadsorbent: Batch Kinetics and Isothermal Modeling Studies,” Polycycl. Aromat. Compd., vol. 39, no. 1, pp. 23–43, Jan. 2019, doi: 10.1080/10406638.2016.1255650
  2. Al Haider, S. A., Al Fatlawi, S., & Nasir, M. J., “Utilizing Activated Carbon Developed from Banana Peels as Permeable Reactive Barrier in Copper Removal from Polluted Groundwater,” J. Ecol. Eng., vol. 23, no. 1, pp. 83–90, Jan. 2022, doi: 10.12911/22998993/143973
  3. Allwar, A., Setiawan, A., Ermawan, H. A., & Alviansah, T. “Removal of Cu(II) ions from aqueous solution by activated carbon produced from banana fruit bunch (Musa paradisiaca),” Desalin. Water Treat., vol. 172, pp. 139–147, Dec. 2019, doi: 10.5004/dwt.2019.24668
  4. Arsad, E. “Technology of Processing and Utilization of Activated Carbon for Industry,” J. Ris. Ind. Has. Hutan, vol. 2, no. 2, p. 43, Dec. 2010, doi: 10.24111/jrihh.v2i2.1146
  5. Auliya, R. “Synthesis and Characterization of Activated Carbon from Banana Peel (Musa Paradisiaca L.) As An Adsorbent of Polycyclic Aromatic Hydrocarbon Phenanthrene Compounds,” 2018
  6. Damayanti and Hidayah, “The Effect of Commercial Adsorbents on the Reduction of Phosphates and Anionic Surfactants (Detergents) in Laundry Waste Water,” Envirous, vol. 2, no. 1, pp. 18–26, Aug. 2023, doi: 10.33005/envirous.v2i1.54
  7. Darweesh, M. A., Elgendy, M. Y., Ayad, M. I., Ahmed, A. M., Elsayed, N. K., & Hammad, W. A., “Adsorption isotherm, kinetic, and optimization studies for copper (II) removal from aqueous solutions by banana leaves and derived activated carbon,” South African J. Chem. Eng., vol. 40, pp. 10–20, Apr. 2022, doi: 10.1016/j.sajce.2022.01.002
  8. Erlina, Umiatin, and Esmar B. “Effect of KOH solution concentration on coconut shell activated carbon for Cu metal adsorption.,” Proc. Natl. Semin. Phys., vol. 4, 2015
  9. Gumarang, P. “Synthesis and analysis of substance changes (Evolution) in Marshmallow-based activated carbon material.,” Diss. UIN Sunan Gunung Djati Bandung, 2019
  10. Hartanto, Singgih, and Ratnawati "Making activated carbon from palm oil shells by chemical activation method.," Indones. J. Mater. Sci., vol. 12, no. 1, pp. 12–16, 2010
  11. Kwok, D. Y., & Neumann, “Contact angle measurement and contact angle interpretation,” Adv. Colloid Interface Sci., vol. 81, no. 3, pp. 167–249, 1999
  12. Lestari, “Adsorption of lead levels in activated banana peel adsorbents,” Acad. Pharm. Surabaya, 2021
  13. Maslukah, L., Zainuri, A., Wirasatriya, A., and Salma, A., “Spatial Distribution of Chlorophyll-a and Its Relationship with Dissolved Inorganic Phosphate Influenced by Rivers in the North Coast of Java,” J. Ecol. Eng., vol. 20, no. 7, pp. 18–25, Jul. 2019, doi: 10.12911/22998993/108700
  14. Meilinda. K. A., “Study of Photocatalysis Overhaul of Methanyl Yellow Dye Using Activated ZnO-Carbon Catalyst Composite Banana Peel Irradiated by UV Light.,” 2023
  15. T. T. Nadew, M. Keana, T. Sisay, B. Getye, and N. G. Habtu, “Synthesis of activated carbon from banana peels for dye removal of an aqueous solution in textile industries: optimization, kinetics, and isotherm aspects,” Water Pract. Technol., vol. 18, no. 4, pp. 947–966, Apr. 2023, doi: 10.2166/wpt.2023.042
  16. Nadew, T. T., Keana, M., Sisay, T., Getye, B., & Habtu, N. G., “Making activated carbon from coconut shell charcoal with ZnCl2 and Na2CO3 activators as adsorbents to reduce phenol levels in wastewater,” ITS Eng. J., vol. 2, no. 1, pp. F116–F120, 2018, doi: https://doi.org/10.12962/j23373539.v2i1.2437
  17. Priambodo, I., “Effect of KOH Solution Concentration, Holding Time, and Chemical Activation Temperature on the Manufacture of Activated Carbon from Banana Peels for the Development of Hydrogen Storage,” Furn. J., vol. 2, no. 2, 2016
  18. Rahmah, A., “Effect of KOH Concentration in the Manufacture of Plantain Peel Activated Carbon as an EDLC Type Supercapacitor Electrode Application,” Diss. Brawijaya Univ., 2016
  19. Shafirinia, R., Wardhana, I. W., & Oktiawan, “The Effect of Adsorbent Size Variation and Flow Discharge on The Reduction of Chrome (Cr) And Copper (Cu) With Activated Charcoal from Banana Peel Waste in The Liquid Waste of The Chrome Electroplating Industry,” Dr. Diss. Diponegoro Univ., 2016
  20. Alifaturrahma, P., & Hendriyanto, “Utilization of kepok banana peel as an adsorbent to set aside Cu metal,” Sci. J. Environ. Eng., vol. 8, no. 2, pp. 105–111, 2018
  21. Anetha, O., “Adsorbent Made from Kepok Banana Peel (Musa Paradisiaca, L.) For Laboratory Liquid Waste Treatment,” Dr. Diss. Lampung State Polytech., 2022
  22. Putri, D. P., Wahida, S. A., & Marlinda, “Utilization of Kepok Banana Skin (Musa Paradisiaca L.) As an adsorbent to reduce COD (Chemical Oxygen Demand) levels in laundry wastewater.,” J. Information, Sci. Technol., vol. 5, no. 02, pp. 71–77, 2022
  23. Angraini, N., Agustina, T. E., & Hadiah, “The Effect of pH in Laboratory Wastewater Treatment with Adsorption Method to Reduce Heavy Metal Levels of Pb, Cu, and Cd.,” J. Environ. Sci., vol. 20, no. 2, pp. 345–355, 2022
  24. Yusuf, J. Y., Soleimani, H., Chuan, L. K., Sanusi, Y. K., & Adebayo, L. L. “Physicochemical properties and microwave absorption performance of Co3O4 and banana peel-derived porous activated carbon composite at X-band frequency,” J. Alloys Compd., vol. 888, p. 161474, Dec. 2021, doi: 10.1016/j.jallcom.2021.161474
  25. Suthers, I. M., Richardson, A. J., & Rissik, D. “The importance of plankton. Plankton: A Guide to Their Ecology and Monitoring for Water Quality,” pp. 1–13, 2019
  26. Wiberg, Egon, and Nils Wiberg “Inorganic chemistry,” Acad. Press, 2001
  27. Wells, A. F., “Structural inorganic chemistry,” Oxford Class. Texts Ph, 2012

Last update:

No citation recorded.

Last update: 2025-06-24 03:27:33

No citation recorded.