Fabrikasi Dye-Sensitized Solar Cell Menggunakan Fotosensitizer Ekstrak Bunga Rosela (Hibiscus sabdariffa L) dan Elektrolit Padat Berbasis PEG (Polyethylene Glycol)

Mustaqim Mustaqim; Abdul Haris; Gunawan Gunawan

doi:10.14710/jksa.20.2.62-67

DOI: https://doi.org/10.14710/jksa.20.2.62-67

Fabrikasi Dye-Sensitized Solar Cell Menggunakan Fotosensitizer Ekstrak Bunga Rosela (Hibiscus sabdariffa L) dan Elektrolit Padat Berbasis PEG (Polyethylene Glycol)

Mustaqim Mustaqim, Abdul Haris

, Gunawan Gunawan

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

Published: 1 Jul 2017.

BibTex Citation Data :

@article{JKSA16706,
    author = {Mustaqim Mustaqim and Abdul Haris and Gunawan Gunawan},
    title = {Fabrikasi Dye-Sensitized Solar Cell Menggunakan Fotosensitizer Ekstrak Bunga Rosela (Hibiscus sabdariffa L) dan Elektrolit Padat Berbasis PEG (Polyethylene Glycol)},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {20},
    number = {2},
    year = {2017},
    keywords = {Dye-Sensitized Solar Cell; Bunga Rosela; Hibiscus sabdariffa L; Elektrolit Padat},
    abstract = {Telah dibuat  Dye-Sensitized Solar Cell  (DSSC) menggunakan dye alami ekstrak bunga Rosela dan elektrolit padat berbasis PEG yang mengandung pasangan redoks I - /I 3  - .  Dye-Sensitized Solar Cell  dikonstruksi dengan struktur sandwich menggunakan fotoelektrode TiO 2  yang dideposisi pada kaca  Transparent Conductive Oxide  (TCO) dengan elektrode lawan grafit. Dye ekstrak bunga rosela dimaserasi dalam campuran metanol, asam asetat dan air selama 24 jam dan digunakan untuk perendaman fotoelektroda TiO 2  selama 1 jam dan 24 jam. Dye dikarakterisasi menggunakan FT-IR dan UV-Vis dan TiO 2  menggunakan X-RD dan SEM. Kinerja sel surya diuji di bawah sinar matahari selama 1 jam pada jam 12:15-13:15 dengan suhu atmosfir 39°C. Spektra UV-Vis dan FT-IR larutan dye menunjukkan adanya kandungan antosianin pada panjang gelombang maksimum 530 nm dan diperkuat dengan munculnya gugus hidroksil, benzena dan karbonil pada serapan inframerah. Hasil karakterisasi XRD dan SEM menunjukkan TiO 2  memiliki fase kristalin anatase dengan ukuran kristal sebesar 41,56 nm dan morfologi permukaan dengan ukuran rongga sekitar 94,11nm dan ketebalan penampang lintang sekitar 39,05.  Dye-Sensitized Solar Cell  yang dibuat menghasilkan potensial rangkaian terbuka (VOC) sebesar 0,124 V dan 0,127 V , arus rangkaian pendek (ISC) 0,084 mA dan 1,275 mA, serta efisiensi 0,00098 % dan 0,01883 % masing-masing untuk perendaman fotoelektroda TiO 2  1 jam dan 24 jam.},
   issn = {2597-9914},   pages = {62--67}  doi = {10.14710/jksa.20.2.62-67},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/16706}
}

Citation Format:

Abstract

Telah dibuat Dye-Sensitized Solar Cell (DSSC) menggunakan dye alami ekstrak bunga Rosela dan elektrolit padat berbasis PEG yang mengandung pasangan redoks I^-/I₃^-. Dye-Sensitized Solar Cell dikonstruksi dengan struktur sandwich menggunakan fotoelektrode TiO₂ yang dideposisi pada kaca Transparent Conductive Oxide (TCO) dengan elektrode lawan grafit. Dye ekstrak bunga rosela dimaserasi dalam campuran metanol, asam asetat dan air selama 24 jam dan digunakan untuk perendaman fotoelektroda TiO₂ selama 1 jam dan 24 jam. Dye dikarakterisasi menggunakan FT-IR dan UV-Vis dan TiO₂ menggunakan X-RD dan SEM. Kinerja sel surya diuji di bawah sinar matahari selama 1 jam pada jam 12:15-13:15 dengan suhu atmosfir 39°C. Spektra UV-Vis dan FT-IR larutan dye menunjukkan adanya kandungan antosianin pada panjang gelombang maksimum 530 nm dan diperkuat dengan munculnya gugus hidroksil, benzena dan karbonil pada serapan inframerah. Hasil karakterisasi XRD dan SEM menunjukkan TiO₂ memiliki fase kristalin anatase dengan ukuran kristal sebesar 41,56 nm dan morfologi permukaan dengan ukuran rongga sekitar 94,11nm dan ketebalan penampang lintang sekitar 39,05. Dye-Sensitized Solar Cell yang dibuat menghasilkan potensial rangkaian terbuka (VOC) sebesar 0,124 V dan 0,127 V , arus rangkaian pendek (ISC) 0,084 mA dan 1,275 mA, serta efisiensi 0,00098 % dan 0,01883 % masing-masing untuk perendaman fotoelektroda TiO₂ 1 jam dan 24 jam.

Fulltext View|Download Email colleagues

Keywords: Dye-Sensitized Solar Cell; Bunga Rosela; Hibiscus sabdariffa L; Elektrolit Padat

Article Metrics:

Article Info

Section: Research Articles

Language : ID

In Vol 20, No 2 (2017): Volume 20 Issue 2 Year 2017

Most cited articles

Pirolisis Kulit Biji Jambu Mete (Anacardium occidentale L.) dengan Katalis Ni-Ag/Zeolit Synthesis of Nano Chitosan as Carrier Material of Cinnamon’s Active Component Pengaruh Variasi Jenis Asam terhadap Karakter Nanosilika yang Disintesis dari Abu Sekam Padi Sintesis Lempung Terpilar Titania Total Hyptolide of Indonesian Hyptis pectinata extracts in a various solvent using HPLC and UV-Vis spectroscopy and their toxicities More cited articles

M. Grätzel, A. J. McEvoy, Principles and applications of dye sensitized nanocrystalline solar cells (DSC), Asian Journal on Energy and Environment, 5, 3, (2004) 197-210
Jarnuzi Gunlazuardi, Fotokatalisis pada Permukaan TiO2: Aspek Fundamental dan Aplikasinya, Seminar Nasional Kimia Fisika II, (2001)
K. Kalyanasundaram, M. Grätzel, Applications of functionalized transition metal complexes in photonic and optoelectronic devices, Coordination Chemistry Reviews, 177, 1, (1998) 347-414 https://doi.org/10.1016/S0010-8545(98)00189-1
Miao Wang, Xurui Xiao, Xiaowen Zhou, Xueping Li, Yuan Lin, Investigation of PEO-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells, Solar Energy Materials and Solar Cells, 91, 9, (2007) 785-790 https://doi.org/10.1016/j.solmat.2007.01.009
Mi-Ra Kim, Sung-Ho Jin, Sung-Hae Park, Hyun-Jeong Lee, Eun-Hee Kang, Jin-Kook Lee, Photovoltaic Properties and Preparations of Dye-Sensitized Solar Cells Using Solid-State Polymer Electrolytes, Molecular Crystals and Liquid Crystals, 444, 1, (2006) 233-239 http://dx.doi.org/10.1080/15421400500365037
Michael Grätzel, Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells, Journal of Photochemistry and Photobiology A: Chemistry, 164, 1, (2004) 3-14 https://doi.org/10.1016/j.jphotochem.2004.02.023
Akhiruddin Maddu, Mahfuddin Zuhri, Irmansyah Irmansyah, Penggunaan Ekstrak Antosianin Kol Merah Sebagai Fotosensitizer pada Sel Surya TiO2 Nanokristal Tersensitisasi Dye, Makara, 11, 2, (2009) 78-84
P. M. Sirimanne, M. K. I. Senevirathna, E. V. A. Premalal, P. K. D. D. P. Pitigala, V. Sivakumar, K. Tennakone, Utilization of natural pigment extracted from pomegranate fruits as sensitizer in solid-state solar cells, Journal of Photochemistry and Photobiology A: Chemistry, 177, 2, (2006) 324-327 https://doi.org/10.1016/j.jphotochem.2005.07.003
Khwanchit Wongcharee, Vissanu Meeyoo, Sumaeth Chavadej, Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers, Solar Energy Materials and Solar Cells, 91, 7, (2007) 566-571 https://doi.org/10.1016/j.solmat.2006.11.005
Brian A. Gregg, Excitonic Solar Cells, The Journal of Physical Chemistry B, 107, 20, (2003) 4688-4698 10.1021/jp022507x
Moon-Sung Kang, Jong Hak Kim, Jongok Won, Yong Soo Kang, Dye-sensitized solar cells based on crosslinked poly(ethylene glycol) electrolytes, Journal of Photochemistry and Photobiology A: Chemistry, 183, 1, (2006) 15-21 https://doi.org/10.1016/j.jphotochem.2006.02.013
Wilman Septina, D Fajarisandi, M Aditia, Pembuatan Prototipe Solar Cell Murah dengan Bahan Organik-Inorganik (Dye-sensitized Solar Cell), in: Laporan Akhir Penelitian Bidang Energi, Penghargaan PT. Rekayasa Industri, 2007
Jae-Wook Lee, Kyung-June Hwang, Wang-Geun Shim, Kyung-Hee Park, Hal-Bon Gu, Kyu-Hyuk Kwun, Energetic surface heterogeneity of nanocrystalline TiO2 films for dye-sensitized solar cells, Korean Journal of Chemical Engineering, 24, 5, (2007) 847-850 10.1007/s11814-007-0052-4
Greg P. Smestad, Michael Gratzel, Demonstrating Electron Transfer and Nanotechnology: A Natural Dye-Sensitized Nanocrystalline Energy Converter, Journal of Chemical Education, 75, 6, (1998) 752 10.1021/ed075p752

Last update:

Pengaruh Variasi Jarak Sumber Cahaya Terhadap Kinerja Dye Sensitized Solar Cell (DSSC) Menggunakan Ekstrak Antosianin Bunga Rossela
Rafika Andari. JAMI: Jurnal Ahli Muda Indonesia, 1 (2), 2020. doi: 10.46510/jami.v1i2.27
Synthesis of ZnO/NiO Thin Film on Fluorine-doped Tin Oxide (FTO) by Two Step Electrodeposition as Photoanode of a Solar Cell
Ines Ayu Handayani, Abdul Haris, Didik Setiyo Widodo. Jurnal Kimia Sains dan Aplikasi, 21 (3), 2018. doi: 10.14710/jksa.21.3.124-130
Increasing Efficiency of Dye-Sensitized Solar Cell (DSSC) Originating from Yellow Sweet Potato Extract as Dye Sensitizer: Effect of Acetic Acid, Polyethylene Glycol, and Polyvinyl Alcohol as TiO2 binders
Yulia Nadhirah, RD Kusumanto, Abu Hasan. Jurnal Kimia Sains dan Aplikasi, 23 (11), 2020. doi: 10.14710/jksa.23.11.403-408

Last update: 2026-09-15 05:48:37

No citation recorded.

As an article writer, the author has the right to use their article for various purposes, including use by institutions that employ the author or institutions that provide funding for the research. These author rights are granted without special permission.

Authors who publish a paper in JKSA have broad rights to use their work for teaching and scientific purposes without the need to request permission, including: (i) teaching in the author's class or institution; (ii) presenting the work at meetings or conferences and distributing copies to participants; (iii) using the work in training conducted by the author or the author's institution; (iv) distributing copies to colleagues for research purposes; (v) using the work in the compilation of subsequent works by the author; (vi) including the work in a thesis or dissertation; (vii) reusing part of the article in another work, with appropriate citation; (viii) preparing derivative works, with appropriate citation; and (ix) voluntarily posting the work on open websites operated by the author or the author's institution for scientific purposes, in accordance with the CC BY-SA License.

Authors and readers may copy and redistribute the material in any medium or format, and may remix, transform, and build upon the material for any purpose, provided that they give appropriate credit by citing the article or its content, provide a link to the license, and indicate if changes were made.

The authors submitting a manuscript do so on the understanding that, if accepted for publication, the copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses the rights to reproduce and distribute the article in all forms and media, including reprints, photographs, microfilms, and any other similar reproductions, as well as translations.

Reproducing any part of this journal, storing it in a database, or transmitting it in any form or medium is permitted without written permission from JKSA. However, the original source must be properly cited in accordance with academic conventions.

JKSA, the Chemistry Department of Diponegoro University, and the Editor make every effort to ensure that no inaccurate, false, or misleading data, opinions, or statements are published in JKSA. However, the content of each article is the sole and exclusive responsibility of its authors.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should bear the authors' original signatures and be sent to the Editor as a printed document, a scanned document sent via email, or by fax.

Prof. Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id