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Blue Methylene Retrieval using Silica-Salicylic Acid Modified Filtering

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 31 Jan 2018.
Open Access Copyright 2018 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0/.

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Abstract

The retrieval of methylene blue using a silica-modified sulfide-salicylic acid has been carried out. Salicylate-silica-acid alloys have been prepared by comparing the four media ie filter paper, silica-filter paper, salicylic acid-filter paper and salicylic acid-silica-filter paper. This study aims to study the recovery of methylene blue using salicylic acid-modified silica filtering with various parameters on the adsorption and desorption process. The results showed that the salicylic acid-silica alloy could improve the capability of methylene blue removal. The result of pH variation on the adsorption process showed that at pH 7 methylene blue can be taken 92.89%. Whereas at concentration variation, salicylic acid at 5 mM can take methylene blue equal to 92.86%. The desorption results showed that pH 1 methylene blue could be desorbed at 308.89 mg/g, while the variation of contact time of desorption ie at 110 minutes could an saturate the blue methylene by 589,61 mg/g. The UV-Vis analysis showed a decrease in absorbance in salicylic acid after contact with silica. The FTIR analysis also shows that in salicylate-silica-acid alloys there are Si-O groups derived from silica and C = O derived from salicylic acid.

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Keywords: methylene blue; silica; salicylic acid

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  3. E.-S.Z. El-Ashtoukhy, Y.O Fouad, Liquid–liquid extraction of methylene blue dye from aqueous solutions using sodium dodecylbenzenesulfonate as an extractant, Alexandria Engineering Journal, 54, (2015) 77-81 10.1016/j.aej.2014.11.007
  4. Reza S. Razmara, Ali Daneshfar, Reza Sahrai, Determination of methylene blue and sunset yellow in wastewater and food samples using salting-out assisted liquid–liquid extraction, Journal of Industrial and Engineering Chemistry, 17, 3, (2011) 533-536 http://dx.doi.org/10.1016/j.jiec.2010.10.028
  5. Hekun Han, Wei Wei, Zhifeng Jiang, Junwei Lu, Jianjun Zhu, Jimin Xie, Removal of cationic dyes from aqueous solution by adsorption onto hydrophobic/hydrophilic silica aerogel, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 509, Supplement C, (2016) 539-549 http://dx.doi.org/10.1016/j.colsurfa.2016.09.056
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  7. M. Soniya, G. Muthuraman, Comparative study between liquid–liquid extraction and bulk liquid membrane for the removal and recovery of methylene blue from wastewater, Journal of Industrial and Engineering Chemistry, 30, (2015) 266-273 http://dx.doi.org/10.1016/j.jiec.2015.05.032
  8. Reza Hosseinzadeh, Khatereh Khorsandi, Maryam Jahanshiri, Combination photodynamic therapy of human breast cancer using salicylic acid and methylene blue, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 184, Supplement C, (2017) 198-203 http://dx.doi.org/10.1016/j.saa.2017.05.008
  9. Yasemin Bulut, Haluk Aydın, A kinetics and thermodynamics study of methylene blue adsorption on wheat shells, Desalination, 194, 1, (2006) 259-267 http://dx.doi.org/10.1016/j.desal.2005.10.032
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