skip to main content

Silica Magnetite Adsorbent: Effect of Drying Temperature of Silica Sol Gel on Magnetite Core Structure

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Received: 9 Jul 2018; Published: 31 Jul 2018.
Open Access Copyright 2018 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Abstract
Recently, magnetite was investigated as water purification adsorbent because it’s unique magnetic properties that improved the adsorption efficiency through desorption process. But magnetite oxidized into maghemite/hematite with the increase of temperature. This transformation should be avoided to maintain the magnetic properties of magnetite. In this research magnetite separated from iron sand by magnetic extraction then coated with silica via sol gel method. The effect of drying temperature in sol gel had change the magnetite core structure into maghemite and found no formation of hematite at 350⁰C. Silica coating proved had protected magnetite from transformation into hematite due to drying temperature until 350⁰C .
Fulltext View|Download
Keywords: magnetite, coating silica, sol gel, adsorben, drying effect

Article Metrics:

  1. Amyn S. Teja, Pei-Yoong Koh, Synthesis, properties, and applications of magnetic iron oxide nanoparticles, Progress in Crystal Growth and Characterization of Materials, 55, 1, (2009) 22-45 https://doi.org/10.1016/j.pcrysgrow.2008.08.003
  2. Ritu D. Ambashta, Mika Sillanpää, Water purification using magnetic assistance: A review, Journal of Hazardous Materials, 180, 1, (2010) 38-49 https://doi.org/10.1016/j.jhazmat.2010.04.105
  3. D. Harikishore Kumar Reddy, Yeoung-Sang Yun, Spinel ferrite magnetic adsorbents: Alternative future materials for water purification?, Coordination Chemistry Reviews, 315, (2016) 90-111 https://doi.org/10.1016/j.ccr.2016.01.012
  4. Agus Yulianto, Satria Bijaksana, Waloejo Loeksmanto, Comparative Study on Magnetic Characterization of Iron Sand from Several Locations in Central Java, Indonesian Journal of Physics, 14, 2, (2003) 63-66
  5. Bilalodin, Sunardi, Muhtar Effendy, Analisis Kandungan Senyawa Kimia dan Uji Sifat Magnetik Pasir Besi Pantai Ambal, Jurnal Fisika Indonesia, 17, 50, (2013) 29-31
  6. Dedi Sufiandi, Konsentrasi Pasir Besi Titan Dari Pengotornya Dengan Cara Magnetik, Metalurgi Majalah Ilmu dan Teknologi, 26, 1, (2015) 15-20 http://dx.doi.org/10.14203/metalurgi.v26i1.4
  7. Cafer T. Yavuz, Arjun Prakash, J. T. Mayo, Vicki L. Colvin, Magnetic separations: From steel plants to biotechnology, Chemical Engineering Science, 64, 10, (2009) 2510-2521 https://doi.org/10.1016/j.ces.2008.11.018
  8. Fauziatul Fajaroh, Heru Setyawan, Adrian Nur, I. Wuled Lenggoro, Thermal stability of silica-coated magnetite nanoparticles prepared by an electrochemical method, Advanced Powder Technology, 24, 2, (2013) 507-511 https://doi.org/10.1016/j.apt.2012.09.008
  9. Rochelle M. Cornell, Udo Schwertmann, The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses, Wiley, 2006
  10. Aránzazu del Campo, Tapas Sen, Jean-Paul Lellouche, Ian J. Bruce, Multifunctional magnetite and silica–magnetite nanoparticles: Synthesis, surface activation and applications in life sciences, Journal of Magnetism and Magnetic Materials, 293, 1, (2005) 33-40 https://doi.org/10.1016/j.jmmm.2005.01.040
  11. Enobong R. Essien, Oluyemi A. Olaniyi, Luqman A. Adams, Rafiu O. Shaibu, Sol-Gel-Derived Porous Silica: Economic Synthesis and Characterization, Journal of Minerals and Materials Characterization and Engineering, 11, 10, (2012) 976-981 http://dx.doi.org/10.4236/jmmce.2012.1110098
  12. C. A. Milea, C. Bogatu, A. DuŢĂ, The Influence of Parameters in Silica Sol-Gel Process, Bulletin of the Transilvania University of Brasov, Series I: Engineering Sciences, 4, 1, (2011) 59-66
  13. Henny Dwi Bhakti, Mashuri, Pengaruh Ukuran Partikel Fe3O4 Dari Pasir Besi Sebagai Bahan Penyerap Radar Pada Frekuensi X-Band dan Ku-Band, in, Institut Teknologi Sepuluh Nopember, Surabaya, 2014
  14. Xiaoli Zhao, Yali Shi, Thanh Wang, Yaqi Cai, Guibin Jiang, Preparation of silica-magnetite nanoparticle mixed hemimicelle sorbents for extraction of several typical phenolic compounds from environmental water samples, Journal of Chromatography A, 1188, 2, (2008) 140-147 https://doi.org/10.1016/j.chroma.2008.02.069
  15. Samira Hozhabr Araghi, Mohammad H. Entezari, Mahmoud Chamsaz, Modification of mesoporous silica magnetite nanoparticles by 3-aminopropyltriethoxysilane for the removal of Cr(VI) from aqueous solution, Microporous and Mesoporous Materials, 218, (2015) 101-111 https://doi.org/10.1016/j.micromeso.2015.07.008
  16. Damien Faivre, Iron Oxides: From Nature to Applications, Wiley, 2016
  17. N. Mahmed, O. Heczko, A. Lancok, S. P. Hannula, The magnetic and oxidation behavior of bare and silica-coated iron oxide nanoparticles synthesized by reverse co-precipitation of ferrous ion (Fe2+) in ambient atmosphere, Journal of Magnetism and Magnetic Materials, 353, (2014) 15-22 https://doi.org/10.1016/j.jmmm.2013.10.012

Last update:

  1. Synthesis and Characterization of SiO2/ZnO Nanocomposites from Zinc Waste and Mount Merapi Volcanic Ash

    Sunardi Sunardi, Silviana Silviana. Jurnal Kimia Sains dan Aplikasi, 23 (10), 2020. doi: 10.14710/jksa.23.10.365-369

Last update: 2024-11-22 02:22:38

No citation recorded.