Studi Teoritis Penggunaan Derivasi Asam Siano sebagai Akseptor Elektron dalam Pelargonidin sebagai Senyawa Pewarna Sel Surya Sensitasi

Muhamad Imam Muslim; Sudarlin Sudarlin

doi:10.14710/jksa.22.4.123-128

DOI: https://doi.org/10.14710/jksa.22.4.123-128

Studi Teoritis Penggunaan Derivasi Asam Siano sebagai Akseptor Elektron dalam Pelargonidin sebagai Senyawa Pewarna Sel Surya Sensitasi

Theoretical Study on the Use Cyano Acid Derivation as Electron Acceptors in Pelargonidin as Dye Compounds of Sensitized Solar Cells (DSSC)

Muhamad Imam Muslim , Sudarlin Sudarlin

Jurusan Kimia, Fakultas Sains dan Teknologi, UIN Sunan Kalijaga, Indonesia

Received: 2 Oct 2018; Revised: 17 Jun 2019; Accepted: 20 Jun 2019; Published: 31 Jul 2019.

BibTex Citation Data :

@article{JKSA20523,
    author = {Muhamad Muslim and Sudarlin Sudarlin},
    title = {Studi Teoritis Penggunaan Derivasi Asam Siano sebagai Akseptor Elektron dalam Pelargonidin sebagai Senyawa Pewarna Sel Surya Sensitasi},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {22},
    number = {4},
    year = {2019},
    keywords = {DSSC; Pelargonidin; HOMO-LUMO; DFT; TDDFT; VRP; LHE; Spectra; Bond Length; Electron Acceptor},
    abstract = {The theoretical study of the use of cyano acid derivatives as electron acceptor groups in pelargonidin as a dye compound in sensitized solar cells (DSSC) was successfully carried out. Theoretical study was carried out with the purpose to determine the effect modification of the addition of cyanoacrylic benzothiadiazole, cyanoacrylate, cyanovinyl, and cyanocynamic as electron acceptors to the characteristics of pelargonidin as dye DSSC. The effect of modification is based on the parameters of bond length, spectra, molecular electron density, light harvesting efficiency (LHE), (V RP ), and HOMO-LUMO energy. The molecular structure created using the Avogadro program, then optimized by DFT/TDDFT method using a base set 6.311G *. Based on the results of research on pelargonidin-benzothiadiazole cyanoacrylate is a better modification when compared with pelargonidin without modification or pelargonidin modified with other cyano acids. This modification is better modification based on parameters molecular electron density, HOMO-LUMO energy, (V RP ), bond lengths, and spectra. Pelargonidin-benzothiadiazole cyanoacrylic electron density in LUMO conditions centred in benzothiadiazole cyanoacrylic, HOMO and LUMO energy of dye is -4.97856 eV & -2,56731 eV, V RP  value 0.439, bond lengths 1.936 Å, and spectra at wavelength 393.14 nm & 377.09 nm. Based on the light harvesting efficiency (LHE), pelargonidin without modification is the best modification with an LHE value 0.820.},
   issn = {2597-9914},   pages = {123--128}  doi = {10.14710/jksa.22.4.123-128},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/20523}
}

Citation Format:

Abstract

The theoretical study of the use of cyano acid derivatives as electron acceptor groups in pelargonidin as a dye compound in sensitized solar cells (DSSC) was successfully carried out. Theoretical study was carried out with the purpose to determine the effect modification of the addition of cyanoacrylic benzothiadiazole, cyanoacrylate, cyanovinyl, and cyanocynamic as electron acceptors to the characteristics of pelargonidin as dye DSSC. The effect of modification is based on the parameters of bond length, spectra, molecular electron density, light harvesting efficiency (LHE), (V_RP), and HOMO-LUMO energy. The molecular structure created using the Avogadro program, then optimized by DFT/TDDFT method using a base set 6.311G *. Based on the results of research on pelargonidin-benzothiadiazole cyanoacrylate is a better modification when compared with pelargonidin without modification or pelargonidin modified with other cyano acids. This modification is better modification based on parameters molecular electron density, HOMO-LUMO energy, (V_RP), bond lengths, and spectra. Pelargonidin-benzothiadiazole cyanoacrylic electron density in LUMO conditions centred in benzothiadiazole cyanoacrylic, HOMO and LUMO energy of dye is -4.97856 eV & -2,56731 eV, V_RP value 0.439, bond lengths 1.936 Å, and spectra at wavelength 393.14 nm & 377.09 nm. Based on the light harvesting efficiency (LHE), pelargonidin without modification is the best modification with an LHE value 0.820.

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Keywords: DSSC; Pelargonidin; HOMO-LUMO; DFT; TDDFT; VRP; LHE; Spectra; Bond Length; Electron Acceptor

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Section: Research Articles

Language : ID

In Vol 22, No 4 (2019): Volume 22 Issue 4 Year 2019

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