DOI: https://doi.org/10.14710/jksa.22.4.143-149

Pengaruh Komposisi Elektrolit pada Proses Penyisihan Nikel dari Tiruan Air Limbah Elektroplating Menggunakan Sel Elektrodeposisi Dua Ruang

Effect of Electrolyte Composition on Nickel Removal Process from Artificial Electroplating Wastewater Using Two-Room Electrodeposition Cells

Research Unit for Clean Technology, Indonesian Institute of Science (LIPI), Indonesia

Received: 6 May 2019; Revised: 15 Jul 2019; Accepted: 20 Jul 2019; Published: 31 Jul 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Research of removal of soluble nickel from artificial electroplating wastewater has been investigated. The research aim to know optimum electrolit composition in nickel electrodeposition process. This study was conducted within a batch system using double chamber electrodeposition cell separated by water hyacinth leaf. Electrodeposition cell was equipped with a copper plate as cathode, graphite plate as anode, H2SO4 anolyte, NiSO4 catholyte with Na2SO4 added as supporting electrolyte. Electrodeposition performed at 5V direct current voltage for 4 hours each running and varied the concentration of H2SO4 anolyte (0,2 M; 0,6 M and 1 M), pHinitial catholyte (2; 4 and 6) and Na2SO4 (catholyte) supporting electrolyte (0 M; 0,2 M; 0,6 M and 1 M). The statistic analysis results showed that the concentration of 0.2 M H2SO4, pHinitial catholyte of 6 and 0.2 M Na2SO4 with an optimum concentration of nickel concentration values decrease of 18,433 % and nickel deposition on the cathode of 0.042 grams.
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Keywords: nickel removal; double chamber electrodeposition cell; anolyte H2SO4; pHinitial catholyte; supporting electrolyte Na2SO4
Funding: Research Unit for Clean Technology - LIPI

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Language : ID
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  1. Konstantinos Dermentzis, Removal of nickel from electroplating rinse waters using electrostatic shielding electrodialysis/electrodeionization, Journal of Hazardous Materials, 173, 1, (2010) 647-652 https://doi.org/10.1016/j.jhazmat.2009.08.133
  2. Puji Rahayu, Khabibi Khabibi, Adsorpsi Ion Logam Nikel(II) oleh Kitosan Termodifikasi Tripolifosfat, Jurnal Kimia Sains dan Aplikasi, 19, 1, (2016) 21-26 http://doi.org/10.14710/jksa.19.1.21-26
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  4. Xiu-lian Ren, Qi-feng Wei, Zhe Liu, Jun Liu, Electrodeposition conditions of metallic nickel in electrolytic membrane reactor, Transactions of Nonferrous Metals Society of China, 22, 2, (2012) 467-475 https://doi.org/10.1016/S1003-6326(11)61200-4
  5. Pramujo Widiatmoko, Isdiriayani Nurdin, Pengaruh Krom Pada Elektrodeposisi Nikel dari Larutan Nikel-Krom, Jurnal Teknik Kimia Indonesia, 10, 2, (2011) 54-60
  6. Jing Lu, Qi-hua Yang, Zhao Zhang, Effects of additives on nickel electrowinning from sulfate system, Transactions of Nonferrous Metals Society of China, 20, (2010) s97-s101 https://doi.org/10.1016/S1003-6326(10)60020-9
  7. Isdiriayani Nurdin, Pramujo Widiatmoko, Yanti, Nickel Recovery from Nickel and Chromium Containing Wastewater by Electrodeposition Method, in: International Conference on Environment 2010 (ICENV 2010), Penang, Malaysia, 2010
  8. H. D. Doan, A. Weli, J. Wu, A combined photocatalytic and electrochemical treatment of wastewater containing propylene glycol methyl ether and metal ions, Chemical Engineering Journal, 151, 1, (2009) 51-58 https://doi.org/10.1016/j.cej.2009.01.041
  9. I. Giannopoulou, D. Panias, Copper and nickel recovery from acidic polymetallic aqueous solutions, Minerals Engineering, 20, 8, (2007) 753-760 https://doi.org/10.1016/j.mineng.2007.02.009
  10. Y. Oztekin, Z. Yazicigil, Recovery of metals from complexed solutions by electrodeposition, Desalination, 190, 1, (2006) 79-88 https://doi.org/10.1016/j.desal.2005.07.017
  11. U. S. Mohanty, B. C. Tripathy, P. Singh, S. C. Das, Effect of Cd2+ on the electrodeposition of nickel from sulfate solutions. Part II: Polarisation behaviour, Journal of Electroanalytical Chemistry, 566, 1, (2004) 47-52 https://doi.org/10.1016/j.jelechem.2003.11.010
  12. P. Fornari, C. Abbruzzese, Copper and nickel selective recovery by electrowinning from electronic and galvanic industrial solutions, Hydrometallurgy, 52, 3, (1999) 209-222
  13. https://doi.org/10.1016/S0304-386X(99)00019-5
  14. G. Orhan, C. Arslan, H. Bombach, M. Stelter, Nickel recovery from the rinse waters of plating baths, Hydrometallurgy, 65, 1, (2002) 1-8 https://doi.org/10.1016/S0304-386X(02)00038-5
  15. Sri Suryaningsih, Analisa Sifat Adsorpsi Logam Berat pada Eceng Gondok dalam Pengelolaan Air Limbah Elektroplating, Jurnal Material dan Energi Indonesia, 7, 1, (2017) 44-48 https://doi.org/10.24198/jmei.v7i01.12368

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