DOI: https://doi.org/10.14710/jksa.22.3.99-104

Interlayer-free Membran Silika Pektin untuk Pervaporasi Air Rawa Asin

Interlayer-free Silica Pectin Membrane for Wetland Saline Water via Pervaporation

Chemical Engineering Department, Universitas Lambung Mangkurat, Indonesia

Received: 31 Mar 2019; Revised: 7 May 2019; Accepted: 15 May 2019; Published: 31 May 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Wetland in South Kalimantan is one of surface water sources to provide clean water. However, seawater intrusion has spread into the wetland aquifer and reduce the quality of water. Silica-pectin membrane is a promising technology for desalination. The membranes were tested for desalination by pervaporation at room temperature (~25 °C). During pervaporation process, the water contacts to membrane and the separation is started to occurs as vapour phase by maintaining vacuum pressure (~1 bar). The permeate was collected in the cold trap after condensed using nitrogen liquid. The purpose of this research was to investigate the performance of interlayer-free silica pectin membrane for wetland saline water. Experimental results shows the fluxes of membrane are 0.35 and 0.19 kg.m-2 h-1 ( pectin 0%wt); 0.23 and 0.16 kg.m-2 h-1 (pectin 0.1%wt); 0.58 and 3.63 kg.m-2 h-1 (pectin 0.5%wt); 3.40 and 0.12 kg.m-2 h-1 (pectin 2.5%wt) calcined at 300 and 400 °C, respectively. Natural organic matter (NOM) and salt concentration in wetland saline water can reduce the fluxes up to (~98%). Nevertheless, overall salt rejection of membranes achieved >99%. It was found that low calcination gives better performance at high pectin concentration. While pectin concentration was limited at high calcination.
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Keywords: Carbon sustainable template; pervaporation; silica precursor; sol-gel; wetland saline water

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  7. S. Wijaya, M. C. Duke, J. C. Diniz da Costa, Carbonised template silica membranes for desalination, Desalination, 236, 1, (2009) 291-298 https://doi.org/10.1016/j.desal.2007.10.079
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  21. Robin J White, Vitaly L Budarin, James H Clark, Pectin-Derived Porous Materials, Chemistry – A European Journal, 16, 4, (2010) 1326-1335 https://doi.org/10.1002/chem.200901879
  22. A. G. Pandolfo, A. F. Hollenkamp, Carbon properties and their role in supercapacitors, Journal of Power Sources, 157, 1, (2006) 11-27 https://doi.org/10.1016/j.jpowsour.2006.02.065
  23. M. M. Titirici, M. Antonietti, Chemistry and materials options of sustainable carbon materials made by hydrothermal carbonization, Chem Soc Rev, 39, 1, (2010) 103-116 https://doi.org/10.1039/b819318p
  24. Rasel Das, Md Eaqub Ali, Sharifah Bee Abd Hamid, Seeram Ramakrishna, Zaira Zaman Chowdhury, Carbon nanotube membranes for water purification: A bright future in water desalination, Desalination, 336, Supplement C, (2014) 97-109 https://doi.org/10.1016/j.desal.2013.12.026
  25. M. C. Duke, S. Mee, J. C. Diniz da Costa, Performance of porous inorganic membranes in non-osmotic desalination, Water Research, 41, 17, (2007) 3998-4004 https://doi.org/10.1016/j.watres.2007.05.028
  26. M. Elma, C. Yacou, J. C. Diniz da Costa, D. K. Wang, Performance and long term stability of mesoporous silica membranes for desalination, Membranes (Basel), 3, 3, (2013) 136-150 https://doi.org/10.1002/chem.200901879/10.3390/membranes3030136
  27. Muthia Elma, Zaini Lambri Assyaifi, Hairullah, Pembuatan silica thin film sebagai pelapis membran dari prekursor TEOS (Tetra Ethyl Orthosilicate), Quantum Jurnal Inovasi Pendidikan Sains, 8, 2, (2017) 78-82 https://doi.org/10.1002/adfm.200800624
  28. Chen Zhou, Junjie Zhou, Aisheng Huang, Seeding-free synthesis of zeolite FAU membrane for seawater desalination by pervaporation, Microporous and Mesoporous Materials, 234, (2016) 377-383 https://doi.org/10.1016/j.micromeso.2016.07.050
  29. Muthia Elma, Christelle Yacou, David K. Wang, Simon Smart, João C. Diniz da Costa, Microporous Silica Based Membranes for Desalination, Water, 4, 3, (2012) 629 https://doi.org/10.3390/w4030629
  30. Renate M. de Vos, Wilhelm F. Maier, Henk Verweij, Hydrophobic silica membranes for gas separation, Journal of Membrane Science, 158, 1, (1999) 277-288 https://doi.org/10.1016/S0376-7388(99)00035-6
  31. Jinhui Wang, Masakoto Kanezashi, Tomohisa Yoshioka, Toshinori Tsuru, Effect of calcination temperature on the PV dehydration performance of alcohol aqueous solutions through BTESE-derived silica membranes, Journal of Membrane Science, 415-416, (2012) 810-815 https://doi.org/10.1016/j.memsci.2012.05.073
  32. Anu Matilainen, Egil T. Gjessing, Tanja Lahtinen, Leif Hed, Amit Bhatnagar, Mika Sillanpää, An overview of the methods used in the characterisation of natural organic matter (NOM) in relation to drinking water treatment, Chemosphere, 83, 11, (2011) 1431-1442 https://doi.org/10.1016/j.chemosphere.2011.01.018
  33. Armine Avagyan, Benjamin R. K. Runkle, Lars Kutzbach, Application of high-resolution spectral absorbance measurements to determine dissolved organic carbon concentration in remote areas, Journal of Hydrology, 517, (2014) 435-446 https://doi.org/10.1016/j.jhydrol.2014.05.060
  34. A. Maartens, P. Swart, E. P. Jacobs, Humic membrane foulants in natural brown water: characterization and removal, Desalination, 115, 3, (1998) 215-227 https://doi.org/10.1016/S0011-9164(98)00041-1
  35. S. R. Gray, C. B. Ritchie, T. Tran, B. A. Bolto, Effect of NOM characteristics and membrane type on microfiltration performance, Water Research, 41, 17, (2007) 3833-3841 https://doi.org/10.1016/j.watres.2007.06.020
  36. Xiaojun Cui, Kwang-Ho Choo, Natural Organic Matter Removal and Fouling Control in Low-Pressure Membrane Filtration for Water Treatment, Environmental Engineering Research, 19, 1, (2014) 1-8 https://doi.org/10.4491/eer.2014.19.1.001
  37. Hiroshi Yamamura, Kenji Okimoto, Katsuki Kimura, Yoshimasa Watanabe, Hydrophilic fraction of natural organic matter causing irreversible fouling of microfiltration and ultrafiltration membranes, Water Research, 54, (2014) 123-136 https://doi.org/10.1016/j.watres.2014.01.024
  38. Kang Xie, Siqing Xia, Jing Song, Jixiang Li, Liping Qiu, Jiabin Wang, Shoubin Zhang, The Effect of Salinity on Membrane Fouling Characteristics in an Intermittently Aerated Membrane Bioreactor, Journal of Chemistry, 2014, (2014) 7 https://doi.org/10.1155/2014/765971

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