Fruit Stalk Extract from Chili Peppers (Capsicum annum L.) as a Natural Antioxidant to Inhibit Oxidation in Crude Palm Oil

Rahmiwati Hilma; Eka Tri Setya Wulandari; Zaldi Arman

doi:10.14710/jksa.23.4.124-128

DOI: https://doi.org/10.14710/jksa.23.4.124-128

Fruit Stalk Extract from Chili Peppers (Capsicum annum L.) as a Natural Antioxidant to Inhibit Oxidation in Crude Palm Oil

Rahmiwati Hilma¹

, Eka Tri Setya Wulandari¹, Zaldi Arman²

¹Chemistry Study Program, Universitas Muhammadiyah Riau, Indonesia

²Department of Agrotechnology, Faculty of Agriculture, University of Riau, Indonesia

Received: 8 Dec 2019; Revised: 3 Apr 2020; Accepted: 7 Apr 2020; Published: 30 Apr 2020.

BibTex Citation Data :

@article{JKSA27117,
    author = {Rahmiwati Hilma and Eka Wulandari and Zaldi Arman},
    title = {Fruit Stalk Extract from Chili Peppers (Capsicum annum L.) as a Natural Antioxidant to Inhibit Oxidation in Crude Palm Oil},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {23},
    number = {4},
    year = {2020},
    keywords = {Fruit stalk; chili pepper (Capsicum annum L.); flavonoids; total phenolic; antioxidant; effectiveness of the extract},
    abstract = { Fruit stalk of chili pepper ( Capsicum annum  L.) so far is still an untapped waste. The content of active compounds in fruit and fruit stalk of chili pepper ( C. annum  L.) is known to have good antioxidant activity. The purpose of this study was to evaluate the extract of fruit stalk of chili pepper in inhibiting the oxidation of crude palm oil (CPO). In this study, the extraction of fruit stalk of chili pepper ( C. annum  L.) was carried out with n-hexane (from now on referred to as CHE) solvent and with ethanol solvent (from now on referred to as CEE). CHE and CEE were analyzed for total phenolic and flavonoid analyzes. Next, an evaluation of antioxidant activity was carried out using the DPPH method. The effectiveness test of adding the two extracts to the quality of CPO was carried out for ten days using a Completely Randomized Design (CRD) analysis. The parameters observed were peroxide numbers, free fatty acids, and iodine numbers. Data were analyzed by ANOVA and followed by a Least Significance Different (LSD) test. The results show that the total phenolic value is 0.257 mg QE/g dry weight in CEE and 0.003 mg QE/g dry weight in CHE. Total flavonoid values are 0.155 mg QE/g dry weight in CEE and 0.003 mg QE/g in CHE. IC 50  values for DPPH test extract are 223.72 μg/mL in CEE and 953.77 μg/mL in CHE. The test results of the effectiveness of the two extracts against CPO show thin CEE, and CHE significantly (P <0.05) influences to CPO free fatty acids, peroxide number, and iodine number. Both extracts can protect CPO from oxidation. CEE is more effective in maintaining CPO quality for ten days with free fatty acid values (2.1%), peroxide value values 0.48 meq/kg, and iodine number 54.8. Furthermore, this result meets the CPO quality standard, according to SNI-01-2901-2006. },
   issn = {2597-9914},   pages = {124--128}  doi = {10.14710/jksa.23.4.124-128},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/27117}
}

Citation Format:

Abstract

Fruit stalk of chili pepper (Capsicum annum L.) so far is still an untapped waste. The content of active compounds in fruit and fruit stalk of chili pepper (C. annum L.) is known to have good antioxidant activity. The purpose of this study was to evaluate the extract of fruit stalk of chili pepper in inhibiting the oxidation of crude palm oil (CPO). In this study, the extraction of fruit stalk of chili pepper (C. annum L.) was carried out with n-hexane (from now on referred to as CHE) solvent and with ethanol solvent (from now on referred to as CEE). CHE and CEE were analyzed for total phenolic and flavonoid analyzes. Next, an evaluation of antioxidant activity was carried out using the DPPH method. The effectiveness test of adding the two extracts to the quality of CPO was carried out for ten days using a Completely Randomized Design (CRD) analysis. The parameters observed were peroxide numbers, free fatty acids, and iodine numbers. Data were analyzed by ANOVA and followed by a Least Significance Different (LSD) test. The results show that the total phenolic value is 0.257 mg QE/g dry weight in CEE and 0.003 mg QE/g dry weight in CHE. Total flavonoid values are 0.155 mg QE/g dry weight in CEE and 0.003 mg QE/g in CHE. IC₅₀ values for DPPH test extract are 223.72 μg/mL in CEE and 953.77 μg/mL in CHE. The test results of the effectiveness of the two extracts against CPO show thin CEE, and CHE significantly (P <0.05) influences to CPO free fatty acids, peroxide number, and iodine number. Both extracts can protect CPO from oxidation. CEE is more effective in maintaining CPO quality for ten days with free fatty acid values (2.1%), peroxide value values 0.48 meq/kg, and iodine number 54.8. Furthermore, this result meets the CPO quality standard, according to SNI-01-2901-2006.

Fulltext View|Download

Keywords: Fruit stalk; chili pepper (Capsicum annum L.); flavonoids; total phenolic; antioxidant; effectiveness of the extract

Funding: PT. Chevron Pacific Indonesia

Article Metrics:

Article Info

Section: 8th - International Conference of the Indonesian Chemical Society (ICICS)

Language : EN

In Vol 23, No 4 (2020): Volume 23 Issue 4 Year 2020

Recent articles

Utilization of Rubber seed shell and Palm Oil Fronds as Composite Materials for Automotive Industry In Silico Screening Anticancer of Six Triterpenoids toward miR-494 and TNF-α Targets Improving the Performance of Zinc Oxide Photocatalysts for Phenol Degradation through Addition of Lanthanum Species Anti-aggregation effect of Ascorbic Acid and Quercetin on aggregated Bovine Serum Albumin Induced by Dithiothreitol: Comparison of Turbidity and Soluble Protein Fraction Methods More recent articles

Most cited articles

Pengaruh Serbuk Kaca dan Variasi Suhu Pembakaran pada Pembuatan Genteng Lempung Sedimentasi Banjir Kanal Timur Kota Semarang terhadap Kuat Tekan serta Daya Serapnya terhadap Air Conversion of Wood Waste to be a Source of Alternative Liquid Fuel Using Low Temperature Pyrolysis Method Pengaruh Perlakuan Asam dan Kalium Permanganat terhadap Karakter Zeolit Tasik Synthesis of Nano Chitosan as Carrier Material of Cinnamon’s Active Component Isolasi Bakteri Endofit pada Rimpang Jahe Merah (Zingiber officinale Linn. Var Rubrum) Penghasil Senyawa Antioksidan More cited articles

Arai W Sachiho, Pembangunan perkebunan kelapa sawit di Provinsi Riau: sebuah tafsiran seputar pemberdayaan petani kebun, Komaba Studies in Human Geography, 19, (2008), 1-16
Tri Yuni Hendrawati, Studi Pengaruh Penggunaan Antioksidan Golongan Phenolik dan Aminik terhadap Ketahanan Oksidasi Minyak Sawit pada Berbagai Tingkat Kemurnian, Master thesis, Program Pascasarjana, Institut Pertanian Bogor, 2001, Bogor
Cahya Alfiah and Wahono Hadi Susanto, Penangananpasca Panen Kelapa Sawit (Penyemprotan CaCl2 dan Kalium Sorbat terhadap Mutu Crude Palm Oil), Jurnal Pangan dan Agroindustri, 3, 1, (2014), 61-72
Teuku Maimun, Nasrul Arahman, Fikriatul Arifah Hasibuan and Putri Rahayu, Penghambatan Peningkatan Kadar Asam Lemak Bebas (Free Fatty Acid) pada Buah Kelapa Sawit dengan Menggunakan Asap Cair, Jurnal Teknologi dan Industri Pertanian Indonesia, 9, 2, (2017), 44-49 https://doi.org/10.17969/jtipi.v9i2.8469
Nikolaos Gougoulias, Eleni Wogiatzi, Ioannis Vagelas, Liviu Giurgiulescu, Ioanna Gogou, Maria-Nektaria Ntalla and Dimitrios Kalfountzos, Comparative Study on Polyphenols Content, Capsaicin and Antioxidant Activity of Different Hot Peppers Varieties (Capsicum annuum L.) under Environmental Conditions of Thessaly Region, Greece, Carpathian Journal of Food Science & Technology, 9, 1, (2017), 109-116
Ahlem Rebaya, Souad Igueld Belghith, Béatrice Baghdikian, Valérie Mahiou Leddet, Fathi Mabrouki, Evelyne Olivier, JK Cherif and Malika Trabelsi Ayadi, Total phenolic, total flavonoid, tannin content, and antioxidant capacity of Halimium halimifolium (Cistaceae), Journal of Applied Pharmaceutical Science, 5, 1, (2014), 52-57 https://doi.org/10.7324/JAPS.2015.50110
Elin Novia Sembiring, Berna Elya and Rani Sauriasari, Phytochemical screening, total flavonoid and total phenolic content and antioxidant activity of different parts of Caesalpinia bonduc (L.) Roxb, Pharmacognosy journal, 10, 1, (2018), 123-127 https://dx.doi.org/10.5530/pj.2018.1.22
I Sani, C Owoade, A Abdulhamid, Isah M Fakai and F Bello, Evaluation of physicochemical properties, phytochemicals and mineral composition of Cocosnuciferal (Coconut) kernel oil, International Journal of Advanced Research in Chemical Science, 1, 8, (2014), 22-30
Rahmiwati Hilma, Herliani Herliani and M Almurdani, Determination of Total Phenolic, Flavonoid Content Andfree Radical Scavenging Activity of Etanol Extract Sawo Stem Bark (Manilkara zapota (L.)), Prosiding CELSciTech, 2018
Hery Winarsi, Antioksidan alami dan radikal bebas: Potensi dan aplikasi dalam kesehatan, Penerbit Kanisius, Yogyakarta, 2007
Badan Standardisasi Nasional, 2006, Minyak kelapa sawit (crude palm oil), SNI 01-2901-2006, Jakarta

Last update:

Ultrasonic-Assisted Extraction of Xanthorrhizol from Curcuma xanthorrhiza Roxb. Rhizomes by Natural Deep Eutectic Solvents: Optimization, Antioxidant Activity, and Toxicity Profiles
Adelina Simamora, Kris Herawan Timotius, Heri Setiawan, Febrina Amelia Saputri, Chinthia Rahadi Putri, Dewi Aryani, Ratih Asmana Ningrum, Abdul Mun’im. Molecules, 29 (9), 2024. doi: 10.3390/molecules29092093

Last update: 2024-12-26 23:37:57

No citation recorded.

As an article writer, the author has the right to use their articles for various purposes, including use by institutions that employ authors or institutions that provide funding for research. Author rights are granted without special permission.

Author who publishes a paper at JKSA has the broad right to use their work for teaching and scientific purposes without the need to ask permission, including: used for (i) teaching in the author's class or institution, (ii) presentation at meetings or conferences and distributing copies to participants ; (iii) training conducted by the author or author's institution; (iv) distribution to colleagues for research use; (v) use in the compilation of subsequent authors' works; (vi) inclusion in a thesis or dissertation; (vi) reuse of part of the article in another work (with citation); (vii) preparation of derivative works (with citation); (viii) voluntary posting on open websites operated by authors or author institutions for scientific purposes (follow the CC BY-SA License).

Authors and readers can copy and redistribute material in any media or format, and mix, modify, and build material for any purpose but they must provide appropriate credit (provide article citation or content), providing links to the license, and indicate if there are changes.

The authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations.

Reproduce any part of this journal, its storage in the database or its transmission by all forms or media is permitted does not need for written permission from JKSA. However, it should be cited as an honor in academic manners

JKSA and the Chemistry Department of Diponegoro University and the Editor make every effort to ensure that there are no data, opinions, or false or misleading statements published in JKSA. However, the content of the article is the sole and exclusive responsibility of each author.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should be signed originally and send to the Editor in the form of printed letters, scanned documents sent via email or fax.

Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id