skip to main content

Direct Investigation of Synthesis of Gold Nanoparticles Using Polyscias scutellaria Leaf Extract in the Hexane-Water System Using the Centrifugal Liquid Membrane-Spectrophotometry Method

1Study Program of Medical Laboratory Technology, Faculty of Science and Technology, Binawan University, Indonesia

2Study Program of Pharmacy, Faculty of Science and Technology, Binawan University, Indonesia

3Study Program of Physical Engineering, Faculty of Science and Technology, Binawan University, Indonesia

Received: 13 May 2020; Revised: 4 Jul 2020; Accepted: 17 Jul 2020; Available online: 24 Jul 2020; Published: 31 Jul 2020.
Open Access Copyright 2020 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

The Centrifugal liquid Membrane (CLM) method, which provides an ultra-thin two-phase liquid membrane system in a rotating glass cell, was successfully applied to Green Synthesis from Polyscias scutellaria (PS) capped gold nanoparticles (AuNPs-PS) using a Mangkokan leaf (Polyscias scutellaria) extract as a reducing agent and stabilizer in the hexane-water system. PS extract in hexane fraction as the organic phase has a UV absorption spectrum at the maximum wavelength, λmax of 220 nm, while the precursor of HAuCl4 solution as an aqueous phase has an λmax of 214 nm. Investigation of AuNPs-PS formation was carried out at various concentrations of Mangkokan leaf extract concentration; i.e., 0.001 0.003; 0.005; 0.007 and 0.009%, while the reaction was carried out at various rotational speeds of 5,000-9,000 rpm. The formation and stability of AuNPs-PS were observed from the phenomenon of surface plasmon resonance (SPR) and absorbance changes as measured by a UV-Vis spectrophotometer. The results of measurements using CLM-Spectrophotometry shows the formation of AuNPs-PS in the hexane-water system at λmax of 534 nm.

Fulltext View|Download
Keywords: Green Synthesis; Centrifugal Liquid Membrane-spectrophotometry; Au Nanoparticles; Hexane-Water System; Polyscias scutellaria
Funding: Hibah Kementerian Riset dan Teknologi/Badan Riset dan Inovasi Nasional Nomor 051/LL3/PG/2020.

Article Metrics:

  1. Nilufar Torabi, Azin Nowrouzi, Ali Ahadi, Safoura Vardasbi, Behrouz Etesami, Green synthesis of gold nanoclusters using seed aqueous extract of Cichorium intybus L. and their characterization, SN Applied Sciences, 1, 9, (2019), 981 https://doi.org/10.1007/s42452-019-1035-x
  2. Arpita Basu, Sarmishtha Ray, Supriyo Chowdhury, Arnab Sarkar, Deba Prasad Mandal, Shamee Bhattacharjee, Surekha Kundu, Evaluating the antimicrobial, apoptotic, and cancer cell gene delivery properties of protein-capped gold nanoparticles synthesized from the edible mycorrhizal fungus Tricholoma crassum, Nanoscale Research Letters, 13, 1, (2018), 154 https://doi.org/10.1186/s11671-018-2561-y
  3. Arkan Kareem Buraihi, Amal Khudair Abbas, Zainab J. Shanan, Bassam K. Abdul Amir, The Efficacy of Gold Nanoparticles in Inhibiting the Toxic Effect of Tamoxifen on the Kidneys of Male Albino Mice, Biochemical and Cellular Archives, 19, suppl. 1, (2019), 2205-2211
  4. Mingjin Zhu, Xinying Li, Liming Ge, Yaxin Zi, Man Qi, Yulin Li, Defu Li, Changdao Mu, Green synthesis of κ-carrageenan@ Ag submicron-particles with high aqueous stability, robust antibacterial activity and low cytotoxicity, Materials Science and Engineering: C, 106, (2020), 110185 https://doi.org/10.1016/j.msec.2019.110185
  5. Linhai Biao, Shengnan Tan, Qinghuan Meng, Jing Gao, Xuewei Zhang, Zhiguo Liu, Yujie Fu, Green Synthesis, Characterization and Application of Proanthocyanidins-Functionalized Gold Nanoparticles, Nanomaterials, 8, 1, (2018), 53 https://doi.org/10.3390/nano8010053
  6. Azim Akbarzadeh, Davood Zare, Ali Farhangi, Mohammad R Mehrabi, Dariush Norouzian, Shahram Tangestaninejad, Majid Moghadam, Nasim Bararpour, Synthesis and characterization of gold nanoparticles by tryptophane, American Journal of Applied Sciences, 6, 4, (2009), 691-695 https://doi.org/10.3844/ajassp.2009.691.695
  7. Ratna Batari, Identifikasi senyawa flavonoid pada sayuran indigenous Jawa Barat, undergraduate thesis, Fakutas Teknologi Pertanian, Institut Pertanian Bogor, Bogor
  8. P. Renuga Devi, C. Senthil Kumar, P. Selvamani, N. Subramanian, K. Ruckmani, Synthesis and characterization of Arabic gum capped gold nanoparticles for tumor-targeted drug delivery, Materials Letters, 139, (2015), 241-244 https://doi.org/10.1016/j.matlet.2014.10.010
  9. Sry Wahyuni, Syukri Syukri, Syukri Arief, Green synthesis of Ag/TiO2 Nanocomposite Assisted by Gambier Leaf (Uncaria gambir Roxb) Extract, Jurnal Kimia Sains dan Aplikasi, 22, 6, 250-255 https://doi.org/10.14710/jksa.22.6.250-255
  10. Yoki Yulizar, Akira Ohashi, Hirohisa Nagatani, Hitoshi Watarai, Kinetic study of Ni(II) and Zn(II) complexation with a pyridylazo extractant by a centrifugal liquid membrane method, Analytica Chimica Acta, 419, 1, (2000), 107-114 https://doi.org/10.1016/S0003-2670(00)00970-3
  11. Yoki Yulizar, Akira Ohashi, Hitoshi Watarai, Kinetic complexation mechanisms of Ni(II) and Zn(II) with a pyridylazo-ligand at liquid–liquid interfaces, Analytica Chimica Acta, 447, 1, (2001), 247-254 https://doi.org/10.1016/S0003-2670(01)01286-7
  12. Yoki Yulizar, Hitoshi Watarai, In Situ Measurement of Aggregate Formation Kinetics of Nickel(II)-Pyridylazoaminophenol Complex at the Heptane-Water Interface by Centrifugal Liquid Membrane Spectrophotometry, Bulletin of the Chemical Society of Japan, 76, 7, (2003), 1379-1386 https://doi.org/10.1246/bcsj.76.1379
  13. Yoki Yulizar, Hideaki Monjushiro, Hitoshi Watarai, Interfacial aggregate growth process of Fe(II) and Fe(III) complexes with pyridylazophenol in solvent extraction system, Journal of Colloid and Interface Science, 275, 2, (2004), 560-569 https://doi.org/10.1016/j.jcis.2004.02.045
  14. Atiqah Nur Choiry, Pengukuran langsung kompleks nanopartikel Au -asam Merkaptosuksinat-Fe(II) untuk Reduksi Cr(VI) dengan metode Centrifugal Liquid Membrane (CLM), undergraduate thesis, Chemistry Department, Universitas Indonesia, Jakarta
  15. Yoki Yulizar, Tresye Utari, Harits Atika Ariyanta, Digha Maulina, Green Method for Synthesis of Gold Nanoparticles Using Polyscias scutellaria Leaf Extract under UV Light and Their Catalytic Activity to Reduce Methylene Blue, Journal of Nanomaterials, 2017, (2017), 3079636 https://doi.org/10.1155/2017/3079636

Last update:

  1. Green synthesis, properties, and biomedical potential of gold nanoparticles: A comprehensive review

    Zain Fatima, Ramsha Saleem, Rana Rashad Mahmood Khan, Maira Liaqat, Muhammad Pervaiz, Zohaib Saeed, Gulzar Muhammad, Muhammad Amin, Shahzad Rasheed. Biocatalysis and Agricultural Biotechnology, 59 , 2024. doi: 10.1016/j.bcab.2024.103271

Last update: 2024-11-16 06:21:50

No citation recorded.