skip to main content

Effect of Dolomite Addition on Fly Ash Based Ceramic Membrane to Reduce COD and BOD of Liquid Waste

Department of Chemistry, Universitas Negeri Semarang, Semarang 50221, Indonesia

Received: 25 May 2021; Revised: 1 Jul 2021; Accepted: 2 Jul 2021; Available online: 21 Dec 2021; Published: 31 Dec 2021.
Open Access Copyright 2021 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Abstract
Ceramic membrane technology plays an essential role in separation fields such as wastewater treatment. Fly ash as a membrane material has proven to be very effective for many separation processes, including water and air purification, as well as industrial and environmental resource recovery. This study aims to develop a microfiltration ceramic membrane based on fly ash with the addition of dolomite. The synthesized ceramic membranes were then characterized using XRD, SEM, and TGA. Ceramic membranes are used to reduce COD and BOD levels in tofu industrial wastewater. The results showed that the value of membrane porosity tends to increase with the addition of dolomite 0% (D0) to 30% (D30). The increase in the porosity value in the membrane was followed by a decrease in the average pore size, namely 1.6994 m at D0 and 1.1730 m at D30. The membrane with 30% dolomite composition has the best mechanical properties with a compressive strength of 35.29 MPa and superior thermal resistance. This is very beneficial for the use of membranes in the long term. Meanwhile, the membrane filtration ability and the ability of the membrane to reduce COD and BOD levels of waste increased with the addition of dolomite from 0% to 30%. However, the decrease in COD and BOD was smaller in the membrane with 45% dolomite. D30 membrane can reduce COD 80% and BOD up to 71.44%. D30 membrane is the most effective fly ash and dolomite composition in forming pores on the membrane with the best COD and BOD reduction performance.
Fulltext View|Download
Keywords: Ceramic Membrane; fly ash; Dolomite; COD, BOD
Funding: Universitas Negeri Semarang

Article Metrics:

  1. Sareh Rezaei Hosein Abadi, Mohammad Reza Sebzari, Mahmood Hemati, Fatemeh Rekabdar, Toraj Mohammadi, Ceramic membrane performance in microfiltration of oily wastewater, Desalination, 265, 1, (2011), 222-228 https://doi.org/10.1016/j.desal.2010.07.055
  2. Wa Atima, BOD dan COD sebagai parameter pencemaran air dan baku mutu air limbah, Biosel: Biology Science and Education, 4, 1, (2015), 83-93 http://dx.doi.org/10.33477/bs.v4i1.532
  3. Chengwen Song, Tonghua Wang, Yanqiu Pan, Jieshan Qiu, Preparation of coal-based microfiltration carbon membrane and application in oily wastewater treatment, Separation and Purification Technology, 51, 1, (2006), 80-84 https://doi.org/10.1016/j.seppur.2005.12.026
  4. Yingchao Dong, Jian-er Zhou, Bin Lin, Yongqing Wang, Songlin Wang, Lifeng Miao, Ying Lang, Xingqin Liu, Guangyao Meng, Reaction-sintered porous mineral-based mullite ceramic membrane supports made from recycled materials, Journal of Hazardous Materials, 172, 1, (2009), 180-186 https://doi.org/10.1016/j.jhazmat.2009.06.148
  5. Jiaoying Cui, Xiongfu Zhang, Haiou Liu, Shuqin Liu, King Lun Yeung, Preparation and application of zeolite/ceramic microfiltration membranes for treatment of oil contaminated water, Journal of Membrane Science, 325, 1, (2008), 420-426 https://doi.org/10.1016/j.memsci.2008.08.015
  6. S. Khemakhem, R. Ben Amar, A. Larbot, Synthesis and characterization of a new inorganic ultrafiltration membrane composed entirely of Tunisian natural illite clay, Desalination, 206, 1, (2007), 210-214 https://doi.org/10.1016/j.desal.2006.03.567
  7. L. Palacio, Y. Bouzerdi, M. Ouammou, A. Albizane, J. Bennazha, A. Hernández, J. I. Calvo, Ceramic membranes from Moroccan natural clay and phosphate for industrial water treatment, Desalination, 245, 1, (2009), 501-507 https://doi.org/10.1016/j.desal.2009.02.014
  8. M. R. Weir, E. Rutinduka, C. Detellier, C. Y. Feng, Q. Wang, T. Matsuura, R. Le Van Mao, Fabrication, characterization and preliminary testing of all-inorganic ultrafiltration membranes composed entirely of a naturally occurring sepiolite clay mineral, Journal of Membrane Science, 182, 1, (2001), 41-50 https://doi.org/10.1016/S0376-7388(00)00547-0
  9. Jing Fang, Guotong Qin, Wei Wei, Xinqing Zhao, Preparation and characterization of tubular supported ceramic microfiltration membranes from fly ash, Separation and Purification Technology, 80, 3, (2011), 585-591 https://doi.org/10.1016/j.seppur.2011.06.014
  10. Abdelhamid Harabi, Fahima Zenikheri, Boukhemis Boudaira, Ferhat Bouzerara, Abdelkrim Guechi, Lazhar Foughali, A new and economic approach to fabricate resistant porous membrane supports using kaolin and CaCO3, Journal of the European Ceramic Society, 34, 5, (2014), 1329-1340 https://doi.org/10.1016/j.jeurceramsoc.2013.11.007
  11. Yi-Lan Elaine Fung, Huanting Wang, Nickel aluminate spinel reinforced ceramic hollow fibre membrane, Journal of Membrane Science, 450, (2014), 418-424 https://doi.org/10.1016/j.memsci.2013.09.036
  12. Jingjie Cao, Xinfa Dong, Lingling Li, Yingchao Dong, Stuart Hampshire, Recycling of waste fly ash for production of porous mullite ceramic membrane supports with increased porosity, Journal of the European Ceramic Society, 34, 13, (2014), 3181-3194 https://doi.org/10.1016/j.jeurceramsoc.2014.04.011
  13. Li Zhu, Yingchao Dong, Stuart Hampshire, Sophie Cerneaux, Louis Winnubst, Waste-to-resource preparation of a porous ceramic membrane support featuring elongated mullite whiskers with enhanced porosity and permeance, Journal of the European Ceramic Society, 35, 2, (2015), 711-721 https://doi.org/10.1016/j.jeurceramsoc.2014.09.016
  14. Yingchao Dong, Xingqin Liu, Qianli Ma, Guangyao Meng, Preparation of cordierite-based porous ceramic micro-filtration membranes using waste fly ash as the main raw materials, Journal of Membrane Science, 285, 1, (2006), 173-181 https://doi.org/10.1016/j.memsci.2006.08.032
  15. Jing Liu, Yingchao Dong, Xinfa Dong, Stuart Hampshire, Li Zhu, Zhiwen Zhu, Lingling Li, Feasible recycling of industrial waste coal fly ash for preparation of anorthite-cordierite based porous ceramic membrane supports with addition of dolomite, Journal of the European Ceramic Society, 36, 4, (2016), 1059-1071 https://doi.org/10.1016/j.jeurceramsoc.2015.11.012
  16. Keiko Sasaki, Xinhong Qiu, Yukiho Hosomomi, Sayo Moriyama, Tsuyoshi Hirajima, Effect of natural dolomite calcination temperature on sorption of borate onto calcined products, Microporous and Mesoporous Materials, 171, (2013), 1-8 https://doi.org/10.1016/j.micromeso.2012.12.029
  17. Eka Suprihatin, Titin Anita Zaharah, Nelly Wahyuni, Pembuatan Membran Silika dari Fly Ash dan Aplikasinya untuk Menurunkan Kadar COD dan BOD Limbah Cair Kelapa Sawit, Jurnal Kimia Khatulistiwa, 4, 3, (2015), 48-53
  18. Yanfei Chen, Qiming Feng, Guofan Zhang, Dezhi Liu, Runzhe Liu, Effect of Sodium Pyrophosphate on the Reverse Flotation of Dolomite from Apatite, Minerals, 8, 7, (2018), 278 https://doi.org/10.3390/min8070278
  19. Dong Zou, Minghui Qiu, Xianfu Chen, Enrico Drioli, Yiqun Fan, One step co-sintering process for low-cost fly ash based ceramic microfiltration membrane in oil-in-water emulsion treatment, Separation and Purification Technology, 210, (2019), 511-520 https://doi.org/10.1016/j.seppur.2018.08.040
  20. Devagi Kanakaraju, Muhamad Hazim bin Ya, Ying-Chin Lim, Andrea Pace, Combined Adsorption/Photocatalytic dye removal by copper-titania-fly ash composite, Surfaces and Interfaces, 19, (2020), 100534 https://doi.org/10.1016/j.surfin.2020.100534
  21. Songxue Wang, Jiayu Tian, Qiao Wang, Zhiwei Zhao, Fuyi Cui, Guibai Li, Low-temperature sintered high-strength CuO doped ceramic hollow fiber membrane: Preparation, characterization and catalytic activity, Journal of Membrane Science, 570-571, (2019), 333-342 https://doi.org/10.1016/j.memsci.2018.10.078
  22. José Pascual, José Zapatero, María C. Jiménez de Haro, Ignacio Varona, Angel Justo, José L. Pérez-Rodríguez, Pedro J. Sánchez-Soto, Porous mullite and mullite-based composites by chemical processing of kaolinite and aluminium metal wastes, Journal of Materials Chemistry, 10, 6, (2000), 1409-1141 http://dx.doi.org/10.1039/A909380J
  23. Shaoqin Ruan, Jiawei Liu, En-Hua Yang, Cise Unluer, Performance and Microstructure of Calcined Dolomite and Reactive Magnesia-Based Concrete Samples, Journal of Materials in Civil Engineering, 29, 12, (2017), 04017236 https://doi.org/10.1061/(ASCE)MT.1943-5533.0002103
  24. Syukri Arief, Defina Nasmiati, Studi Membran Anorganik Berbahan Dasar dari Alam serta Potensinya sebagai Filter, Prosiding SEMIRATA FMIPA Universitas Lampung, 1, 1, (2013), 401-405
  25. Lidiane Pereira Bessa, Natália Mazzarioli Terra, Vicelma Luiz Cardoso, Miria Hespanhol Miranda Reis, Macro-porous dolomite hollow fibers sintered at different temperatures toward widened applications, Ceramics International, 43, 18, (2017), 16283-16291 https://doi.org/10.1016/j.ceramint.2017.08.214
  26. Mahmud Mahmud, Penurunan Warna Dan Zat Organik pada Pengolahan Air Gambut Menggunakan Membran Ultrafiltrasi, Info-Teknik, 4, 2, (2003), 72-80
  27. Subriyer Nasir, Teguh Budi, Idha Silviaty, Aplikasi Filter Keramik Berbasis Tanah Liat Alam Dan Zeolit Pada Pengolahan Air Limbah Hasil Proses Laundry, Bumi Lestari, 13, 1, (2013), 45-51
  28. Ghufran H. Faisal, Ali J. Jaeel, Thaar S. Al-Gasham, BOD and COD reduction using porous concrete pavements, Case Studies in Construction Materials, 13, (2020), e00396 https://doi.org/10.1016/j.cscm.2020.e00396

Last update:

  1. SURFACE MODIFICATION OF FLY ASH FROM ASAM-ASAM COAL POWER PLANT USING STEARIC ACID AS HYDROPHOBIC INORGANIC MATERIAL

    Tety Wahyuningsih Manurung, Siti Unvaresi Misonia Beladona, Muh. Supwatul Hakim, Lidya Tesalonika, Risfa Aliya Al-Hadi, Rendy Muhamad Iqbal. Jurnal Kimia Riset, 9 (1), 2024. doi: 10.20473/jkr.v9i1.57370

Last update: 2024-12-25 19:13:41

No citation recorded.