DOI: https://doi.org/10.14710/jksa.24.6.200-205

MgO-supported Ni-Sn Catalysts: Characterization and Catalytic Properties for Aqueous-phase Catalytic Reforming of Glycerol

1Research Center for Chemistry, National Research and Innovation Agency (BRIN), Serpong, Tangerang, Indonesia

2Research Center for Chemistry, National Research and Innovation Agency Republic of Indonesia (BRIN), Kawasan Puspiptek, Serpong, South Tangerang, Indonesia

3Indonesian Agency for Agricultural Research and Development, Indonesian Ministry of Agriculture, Jakarta, Indonesia

Received: 2 Jun 2021; Revised: 29 Jul 2021; Accepted: 26 Aug 2021; Published: 31 Aug 2021.
Open Access Copyright 2021 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Abstract

The aqueous phase reforming (APR) of glycerol into value-added products, including H2 and alkanes, is environmentally green. In this work, the conversion of glycerol into syngas was demonstrated using MgO-supported Ni-Sn catalysts. Ni species is known for its capability of converting glycerol, but the activity towards water gas shift (WGS) reaction has not been satisfied. Loading Ni-Sn onto MgO has increased the catalyst basicity, which promotes a positive effect in WGS reaction. A series of bimetallic catalysts, impregnated Ni-Sn on MgO support, was prepared with various Ni-Sn loading amounts. To better understand the behavior of prepared catalysts, they were evaluated physio-chemically through XRD, BET, and FTIR. The catalytic activity test was performed for APR in a continuous flow reactor with aqueous glycerol 10 v-% as a feedstock at a reaction temperature of 250°C. As a result, the maximum hydrogen selectivity was obtained at about 73 v-%.

Fulltext View|Download
Keywords: Glycerol; aqueous-phase catalytic reforming; syngas; bi-metallic catalyst
Funding: Lembaga Ilmu Pengetahuan Indonesia

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
The Coated-Wire Ion-Selective Electrode (CWISE) of Tartrazine Using Chitosan as an Ionophore TiO2-PDMS Super Hydrophilic Coating with Self-Cleaning and Antimicrobial Properties Facile Synthesis of ZnO Nanoparticles for the Photodegradation of Rhodamine-B More recent articles
Most cited articles
Lempung Terpilar Silika untuk Penghilangan Fenol dalam Air Synthesis of Alginate-Chitosan Polyelectrolyte Complex (PEC) Membrane and Its Physical-Mechanical Properties Pengaruh Perlakuan Asam dan Kalium Permanganat terhadap Karakter Zeolit Tasik New Chemicals and Routes for the Preparation of Gelatin/HA Composites using the Wet Precipitation Method Sintesis Porous Carbon dari Sukrosa Menggunakan Silica Template pada Temperatur Kamar More cited articles
  1. Mandana Akia, Farshad Yazdani, Elahe Motaee, Dezhi Han, Hamidreza Arandiyan, A review on conversion of biomass to biofuel by nanocatalysts, Biofuel Research Journal, 1, 1, (2014), 16-25 https://doi.org/10.18331/BRJ2015.1.1.5
  2. Arif Rahmanulloh, Indonesia Biofuels Annual Report 2019, USDA Foreign Agricultural Service, 2019
  3. Gheorghiţa Mitran, Octavian Dumitru Pavel, Mihaela Florea, Daniel G. Mieritz, Dong-Kyun Seo, Hydrogen production from glycerol steam reforming over molybdena–alumina catalysts, Catalysis Communications, 77, (2016), 83-88 https://doi.org/10.1016/j.catcom.2016.01.029
  4. Priscilla A. Selembo, Joe M. Perez, Wallis A. Lloyd, Bruce E. Logan, High hydrogen production from glycerol or glucose by electrohydrogenesis using microbial electrolysis cells, International Journal of Hydrogen Energy, 34, 13, (2009), 5373-5381 https://doi.org/10.1016/j.ijhydene.2009.05.002
  5. Andrea Fasolini, Daniele Cespi, Tommaso Tabanelli, Raffaele Cucciniello, Fabrizio Cavani, Hydrogen from Renewables: A Case Study of Glycerol Reforming, Catalysts, 9, 9, (2019), 722 https://doi.org/10.3390/catal9090722
  6. Agus Praditya Tampubolon, Hapsari Damayanti, Idoan Marciano, Pamela Simamora, Abdilla Alfath, Indonesia Clean Energy Outlook 2020, Institute for Essential Services Reform, Jakarta, 2020
  7. D. Cespi, R. Cucciniello, M. Ricciardi, C. Capacchione, I. Vassura, F. Passarini, A. Proto, A simplified early stage assessment of process intensification: glycidol as a value-added product from epichlorohydrin industry wastes, Green Chemistry, 18, 16, (2016), 4559-4570 http://dx.doi.org/10.1039/C6GC00882H
  8. M. S. Ardi, M. K. Aroua, N. Awanis Hashim, Progress, prospect and challenges in glycerol purification process: A review, Renewable and Sustainable Energy Reviews, 42, (2015), 1164-1173 https://doi.org/10.1016/j.rser.2014.10.091
  9. C. Italiano, K. Bizkarra, V. L. Barrio, J. F. Cambra, L. Pino, A. Vita, Renewable hydrogen production via steam reforming of simulated bio-oil over Ni-based catalysts, International Journal of Hydrogen Energy, 44, 29, (2019), 14671-14682 https://doi.org/10.1016/j.ijhydene.2019.04.090
  10. R. R. Davda, J. W. Shabaker, G. W. Huber, R. D. Cortright, J. A. Dumesic, A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts, Applied Catalysis B: Environmental, 56, 1, (2005), 171-186 https://doi.org/10.1016/j.apcatb.2004.04.027
  11. Ivna O. Cruz, Nielson F. P. Ribeiro, Donato A. G. Aranda, Mariana M. V. M. Souza, Hydrogen production by aqueous-phase reforming of ethanol over nickel catalysts prepared from hydrotalcite precursors, Catalysis Communications, 9, 15, (2008), 2606-2611 https://doi.org/10.1016/j.catcom.2008.07.031
  12. J. W. Shabaker, G. W. Huber, R. R. Davda, R. D. Cortright, J. A. Dumesic, Aqueous-Phase Reforming of Ethylene Glycol Over Supported Platinum Catalysts, Catalysis Letters, 88, 1, (2003), 1-8 https://doi.org/10.1023/A:1023538917186
  13. A. Iriondo, V. L. Barrio, J. F. Cambra, P. L. Arias, M. B. Güemez, R. M. Navarro, M. C. Sánchez-Sánchez, J. L. G. Fierro, Hydrogen Production from Glycerol Over Nickel Catalysts Supported on Al2O3 Modified by Mg, Zr, Ce or La, Topics in Catalysis, 49, 1, (2008), 46 https://doi.org/10.1007/s11244-008-9060-9
  14. D. L. Trimm, Coke formation and minimisation during steam reforming reactions, Catalysis Today, 37, 3, (1997), 233-238 https://doi.org/10.1016/S0920-5861(97)00014-X
  15. X. Chu, J. Liu, Minghua Qiao, J. Zhuang, Keyu Fan, Xuan Zhang, Baoning Zong, Aqueous-Phase Reforming of Ethylene Glycol to H2 on Sn-Modified Rapidly Quenched Skeletal Ni-Mo Catalyst, Chinese Journal of Catalysis, 30, (2009), 595-600
  16. Guoxiang Pan, Zheming Ni, Feng Cao, Xiaonian Li, Hydrogen production from aqueous-phase reforming of ethylene glycol over Ni/Sn/Al hydrotalcite derived catalysts, Applied Clay Science, 58, (2012), 108-113 https://doi.org/10.1016/j.clay.2012.01.023
  17. G. W. Huber, J. W. Shabaker, J. A. Dumesic, Raney Ni-Sn Catalyst for H2 Production from Biomass-Derived Hydrocarbons, Science, 300, 5628, (2003), 2075-2077 https://doi.org/10.1126/science.1085597
  18. J. W. Shabaker, G. W. Huber, J. A. Dumesic, Aqueous-phase reforming of oxygenated hydrocarbons over Sn-modified Ni catalysts, Journal of Catalysis, 222, 1, (2004), 180-191 https://doi.org/10.1016/j.jcat.2003.10.022
  19. L. F. Bobadilla, A. Penkova, F. Romero-Sarria, M. A. Centeno, J. A. Odriozola, Influence of the acid–base properties over NiSn/MgO–Al2O3 catalysts in the hydrogen production from glycerol steam reforming, International Journal of Hydrogen Energy, 39, 11, (2014), 5704-5712 https://doi.org/10.1016/j.ijhydene.2014.01.136
  20. J. W. Shabaker, D. A. Simonetti, R. D. Cortright, J. A. Dumesic, Sn-modified Ni catalysts for aqueous-phase reforming: Characterization and deactivation studies, Journal of Catalysis, 231, 1, (2005), 67-76 https://doi.org/10.1016/j.jcat.2005.01.019
  21. Kiky Corneliasari Sembiring, Anis Kristiani, Fauzan Aulia, Luthfiana Nurul Hidayati, Silvester Tursiloadi, Precious Metals Supported on Alumina and Their Application for Catalytic Aqueous Phase Reforming of Glycerol, Indonesian Journal of Chemistry, 15, 3, (2015), 269-273 https://doi.org/10.22146/ijc.21195
  22. Farzad Bastan, Mohammad Kazemeini, Afsanehsadat Larimi, Hesam Maleki, Production of renewable hydrogen through aqueous-phase reforming of glycerol over Ni/Al2O3MgO nano-catalyst, International Journal of Hydrogen Energy, 43, 2, (2018), 614-621 https://doi.org/10.1016/j.ijhydene.2017.11.122
  23. V. R. Choudhary, B. S. Uphade, A. S. Mamman, Large enhancement in methane-to-syngas conversion activity of supported Ni catalysts due to precoating of catalyst supports with MgO, CaO or rare-earth oxide, Catalysis Letters, 32, 3, (1995), 387-390 https://doi.org/10.1007/BF00813233
  24. Afsaneh Sadat Larimi, Mohammad Kazemeini, Farhad Khorasheh, Highly selective doped PtMgO nano-sheets for renewable hydrogen production from APR of glycerol, International Journal of Hydrogen Energy, 41, 39, (2016), 17390-17398 https://doi.org/10.1016/j.ijhydene.2016.08.006
  25. Simoní Da Ros, Matthew D. Jones, Davide Mattia, Jose C. Pinto, Marcio Schwaab, Fabio B. Noronha, Simon A. Kondrat, Tomos C. Clarke, Stuart H. Taylor, Ethanol to 1,3-Butadiene Conversion by using ZrZn-Containing MgO/SiO2 Systems Prepared by Co-precipitation and Effect of Catalyst Acidity Modification, ChemCatChem, 8, 14, (2016), 2376-2386 https://doi.org/10.1002/cctc.201600331
  26. R. Bouarab, S. Bennici, C. Mirodatos, A. Auroux, Hydrogen Production from the Water-Gas Shift Reaction on Iron Oxide Catalysts, Journal of Catalysts, 2014, (2014), 612575 https://doi.org/10.1155/2014/612575
  27. Mohammad Zangouei, Abdolsamad Zarringhalam Moghaddam, Mehdi Arasteh, The influence of nickel loading on reducibility of NiO/Al2O3 catalysts synthesized by sol-gel method, Chemical Engineering Research Bulletin, 14, 2, (2010), 97-102 https://doi.org/10.3329/cerb.v14i2.5052
  28. J. I. Di Cosimo, V. K. Díez, C. Ferretti, C. R. Apesteguía, Chapter 1 Basic catalysis on MgO: generation, characterization and catalytic properties of active sites, in: Catalysis: Volume 26, The Royal Society of Chemistry, 2014, http://dx.doi.org/10.1039/9781782620037-00001
  29. Mansur Moulavi, Kaluram Kanade, Dinesh Amalnerkar, Amanullah Fatehmulla, Abdullah M. Aldhafiri, M. Aslam Manthrammel, Synergistic surface basicity enhancement effect for doping of transition metals in nanocrystalline MgO as catalysts towards one pot Wittig reaction, Arabian Journal of Chemistry, 14, 5, (2021), 103134 https://doi.org/10.1016/j.arabjc.2021.103134
  30. Alberto José Reynoso, Jose Luis Ayastuy, Unai Iriarte-Velasco, Miguel Ángel Gutiérrez-Ortiz, Bimetallic Pt-Co Catalysts for the Liquid-Phase WGS, Catalysts, 10, 8, (2020), 830 https://doi.org/10.3390/catal10080830
  31. D. Mendes, A. Mendes, L. M. Madeira, A. Iulianelli, J. M. Sousa, A. Basile, The water-gas shift reaction: from conventional catalytic systems to Pd-based membrane reactors—a review, Asia-Pacific Journal of Chemical Engineering, 5, 1, (2010), 111-137 https://doi.org/10.1002/apj.364

Last update:

No citation recorded.

Last update: 2024-11-04 09:51:46

No citation recorded.