DOI: https://doi.org/10.14710/jksa.26.2.39-49

Eco-Friendly Chitosan-Based Biodiesel Heterogeneous Catalyst Support Membrane

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

Received: 27 Oct 2022; Revised: 21 Dec 2022; Accepted: 20 Jan 2023; Published: 28 Feb 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
A chitosan-polyvinyl pyrrolidone K-30 (Cs-PVP.K30) membrane was prepared as a heterogeneous catalyst supporting membrane in the transesterification process in the production of biodiesel from palm oil and methanol through the blend reaction between chitosan (Cs) and polyvinyl pyrrolidone K-30 polymer (PVP K-30). Several membranes were characterized by their physicochemical and catalytic properties. Based on physicochemical data, it was found that including the carbonyl group from PVP K-30 into the chitosan framework correlated with an increase in porosity, hydrophilicity, water absorption, and the degree of swelling of the membrane. The results of the analysis using Fourier Transmittance Infra-red (FTIR) showed the spectra of carbonyl (-C=O) and hydroxyl (-OH) groups at wavenumbers 1648 cm-1 and 3363 cm-1, which shows that the reaction of chitosan alloy with PVP K-30 has been successfully carried out. The catalytic site of the Cs-PVP K30-NaOH membrane in the biodiesel production process was studied under several conversion conditions. It was found that the conversion of biodiesel reached 93.90% with a reaction time of 90 minutes, a temperature of 65°C, and an oil/methanol mole ratio of 1:7.
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Keywords: Chitosan; polyvinyl pyrrolidone K-30; transesterification; biodiesel conversion
Funding: Universitas Diponegoro

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Section: Research Articles
Language : EN
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  1. Thalles A. Andrade, Mariano Martín, Massimiliano Errico, Knud V. Christensen, Biodiesel production catalyzed by liquid and immobilized enzymes: Optimization and economic analysis, Chemical Engineering Research and Design, 141, (2019), 1-14 https://doi.org/10.1016/j.cherd.2018.10.026
  2. Nisakorn Saengprachum, Dongren Cai, Mantian Li, Ling Li, Xiaocheng Lin, Ting Qiu, Acidic chitosan membrane as an efficient catalyst for biodiesel production from oleic acid, Renewable Energy, 143, (2019), 1488-1499 https://doi.org/10.1016/j.renene.2019.05.101
  3. Man Kee Lam, Keat Teong Lee, Abdul Rahman Mohamed, Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: a review, Biotechnology Advances, 28, 4, (2010), 500-518 https://doi.org/10.1016/j.biotechadv.2010.03.002
  4. Retno Ariadi Lusiana, Rahma Wahyu Widyastuti, Nurwarrohman Andre Sasongko, Ayub Indra, Ahmad Suseno, Membran Kitosan-Sitrat sebagai Katalis Heterogen dalam Produksi Biodiesel dari Minyak Kelapa, Analit: Analytical and Environmental Chemistry, 6, 1, (2021), 92-100
  5. Changshen Ye, Zhaoyang Qi, Dongren Cai, Ting Qiu, Design and synthesis of ionic liquid supported hierarchically porous Zr metal–organic framework as a novel Brønsted–Lewis acidic catalyst in biodiesel synthesis, Industrial & Engineering Chemistry Research, 58, 3, (2018), 1123-1132 https://doi.org/10.1021/acs.iecr.8b04107
  6. Zo-Ee Tang, Steven Lim, Yean-Ling Pang, Hwai-Chyuan Ong, Keat-Teong Lee, Synthesis of biomass as heterogeneous catalyst for application in biodiesel production: State of the art and fundamental review, Renewable and Sustainable Energy Reviews, 92, (2018), 235-253 https://doi.org/10.1016/j.rser.2018.04.056
  7. Avinash Alagumalai, Omid Mahian, Frank Hollmann, Wuyuan Zhang, Environmentally benign solid catalysts for sustainable biodiesel production: A critical review, Science of The Total Environment, 768, (2021), 144856 https://doi.org/10.1016/j.scitotenv.2020.144856
  8. Amarajothi Dhakshinamoorthy, Manju Jacob, Nagamalai Sakthi Vignesh, Perumal Varalakshmi, Pristine and modified chitosan as solid catalysts for catalysis and biodiesel production: A minireview, International Journal of Biological Macromolecules, 167, (2021), 807-833 https://doi.org/10.1016/j.ijbiomac.2020.10.216
  9. Mohammadtaghi Vakili, Shubo Deng, Tong Li, Wei Wang, Wenjing Wang, Gang Yu, Novel crosslinked chitosan for enhanced adsorption of hexavalent chromium in acidic solution, Chemical Engineering Journal, 347, (2018), 782-790 https://doi.org/10.1016/j.cej.2018.04.181
  10. Benqiao He, Yixuan Shao, Mengzhu Liang, Jianxin Li, Yu Cheng, Biodiesel production from soybean oil by guanidinylated chitosan, Fuel, 159, (2015), 33-39 https://doi.org/10.1016/j.fuel.2015.06.038
  11. H. N. Chamidy, Riniati, The use of heterogeneous catalysts of chitosan sulfonate bead on the esterification reaction of oleic acid and methanol, IOP Conference Series: Materials Science and Engineering, 2017
  12. https://doi.org/10.1088/1757-899X/202/1/012017
  13. Derya Unlu, Aynur Hacioglu, Nilufer D. Hilmioglu, Biodiesel synthesis by using the smart catalytic membrane, in: Exergetic, Energetic and Environmental Dimensions, Elsevier, 2018, https://doi.org/10.1016/B978-0-12-813734-5.00048-2
  14. Ritesh Kumar, Indrani Mishra, Gulshan Kumar, Synthesis and evaluation of mechanical property of chitosan/PVP blend through nanoindentation-a nanoscale study, Journal of Polymers and the Environment, 29, 11, (2021), 3770-3778 https://doi.org/10.1007/s10924-021-02143-0
  15. Slamet Sudarmadji, H. Bambang, Prosedur Analisa Bahan Makanan dan Pertanian, Liberty, Yogyakarta, 2003
  16. Marcus Frederick Charles Ladd, Introduction to Physical Chemistry, Cambridge University Press, 1998
  17. B. Smitha, S. Sridhar, A. A. Khan, Synthesis and characterization of poly (vinyl alcohol)‐based membranes for direct methanol fuel cell, Journal of Applied Polymer Science, 95, 5, (2005), 1154-1163 https://doi.org/10.1002/app.20982
  18. Retno Ariadi Lusiana, Vivi Dia A. Sangkota, Nurwarrohman Andre Sasongko, Gunawan Gunawan, Anugrah Ricky Wijaya, Sri Juari Santosa, Dwi Siswanta, Mudasir Mudasir, Muhammad Nidzhom Zainol Abidin, Sumarni Mansur, Permeability improvement of polyethersulfone-polietylene glycol (PEG-PES) flat sheet type membranes by tripolyphosphate-crosslinked chitosan (TPP-CS) coating, International Journal of Biological Macromolecules, 152, (2020), 633-644 https://doi.org/10.1016/j.ijbiomac.2020.02.290
  19. Alinda Megagita Nurratri, Khabibi Khabibi, Retno Ariadi Lusiana, Abdul Haris, Rahmad Nuryanto, Pembuatan Dan Karakterisasi Membran Paduan Kitosan-Polietilenglikol6000, Media Bina Ilmiah, 14, 9, (2020), 3261-3270
  20. Joana T. Martins, Miguel A. Cerqueira, António A. Vicente, Influence of α-tocopherol on physicochemical properties of chitosan-based films, Food Hydrocolloids, 27, 1, (2012), 220-227 https://doi.org/10.1016/j.foodhyd.2011.06.011
  21. Luc Avérous, Eric Pollet, Biodegradable polymers, in: Environmental silicate nano-biocomposites, Springer, London, 2012, https://doi.org/10.1007/978-1-4471-4108-2_2
  22. Ewa Rudnik, Compostable Polymer Materials, Second edition ed., Newnes, 2019
  23. S. Ketaren, Pengantar teknologi minyak dan lemak pangan, UI-Press, Jakarta, 1986
  24. Martin Mittelbach, Claudia Remschmidt, Biodiesel: the comprehensive handbook, Martin Mittelbach, 2004 https://doi.org/10.1002/biot.200690003
  25. Ayhan Demirbas, Progress and recent trends in biodiesel fuels, Energy conversion and management, 50, 1, (2009), 14-34 https://doi.org/10.1016/j.enconman.2008.09.001

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