skip to main content

Synthesis and Characterization of Gambas (Luffa acutangula) Peel–Based Bioplastic Reinforced by Silica

Department of Chemical Engineering, Faculty of Engineering, Universitas Muhammadiyah Surakarta, Surakarta, Indonesia

Received: 4 Apr 2023; Revised: 10 Jun 2023; Accepted: 15 Jun 2023; Published: 30 Jun 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

Gambas (Luffa acutangula) plants contain a relatively high carbohydrate of 68.2%, whereas its peel contains 38.94% of carbohydrates and 20.6% of fibers. Gambas peels are rarely utilized and are typically discarded as food waste. Silica can be used as a filler and reinforcement material to improve the physical and mechanical properties. This study discussed synthesizing and characterizing bioplastics from Gambas peel reinforced by silica using polyvinyl alcohol (PVA) as a plasticizer with a mass of 8 g and 9 g and vinegar as a compatibilizer with volumes of 7 mL and 8 mL. The gelatinization temperature was adjusted at 85°C and 95°C. The synthesized bioplastics have improved mechanical characteristics due to the addition of PVA. The addition of vinegar as a compatibilizer revealed a homogenous mixture in surface morphological analysis. The highest performance of bioplastic samples was obtained from sample 7 with 8 mL vinegar, 9 g of PVA, and at 85°C of gelatinization temperature. The results showed that the maximum tensile strength reached 0.034 N/mm2, the elongation was 225%, the value of Young’s modulus was 0.015 N/mm2, the thermal stability reached 74.34% weight loss by heating up to 400°C, and the melting temperature reached at 220°C, the absorption of water was 37.61%, and the weight loss was 20.3% after ten days of soil burial.

Fulltext View|Download
Keywords: Bioplastic; Gambas Peel; Silica; Polyvinyl Alcohol; Vinegar
Funding: Universitas Muhammadiyah Surakarta

Article Metrics:

  1. E. H. Song, J. Shang, D. M. Ratner, 9.08 - Polysaccharides, in: K. Matyjaszewski, M. Möller (Eds.) Polymer Science: A Comprehensive Reference, Elsevier, Amsterdam, 2012, https://doi.org/10.1016/B978-0-444-53349-4.00246-6
  2. Arifa Shafqat, Nabil Al-Zaqri, Arifa Tahir, Ali Alsalme, Synthesis and characterization of starch based bioplatics using varying plant-based ingredients, plasticizers and natural fillers, Saudi Journal of Biological Sciences, 28, 3, (2021), 1739-1749 https://doi.org/10.1016/j.sjbs.2020.12.015
  3. M. P. Swetha, S. P. Muthukumar, Characterization of nutrients, amino acids, polyphenols and antioxidant activity of Ridge gourd (Luffa acutangula) peel, Journal of Food Science and Technology, 53, (2016), 3122-3128 https://doi.org/10.1007/s13197-016-2285-x
  4. Bassey E. Nyong, Obo Okokon Ita, Precious Okokon Ita, Moses Eso Bassey Eka, Proximate Composition of Luffa Acutangula (Sponge Gourd) Fruit, Journal of Innovation and Sustainability, 3, (2021), 93-97
  5. Ali Esmail Al-Snafi, A review on Luffa acutangula: A potential medicinal plant, IOSR Journal of Pharmacy, 9, 9, (2019), 56-67
  6. Jayachandra Yaradoddi, Vinay Patil, Sharanabasava Ganachari, Nagaraj Banapurmath, Anand Hunashyal, Ashok Shettar, Biodegradable plastic production from fruit waste material and its sustainable use for green applications, International Journal of Pharmaceutical Research & Allied Sciences, 5, 4, (2016), 56-66
  7. R. Reshmy, Eapen Philip, P. H. Vaisakh, Shibin Raj, Sherly Annie Paul, Aravind Madhavan, Raveendran Sindhu, Parameswaran Binod, Ranjna Sirohi, Arivalagan Pugazhendhi, Ashok Pandey, Development of an eco-friendly biodegradable plastic from jack fruit peel cellulose with different plasticizers and Boswellia serrata as filler, Science of The Total Environment, 767, (2021), 144285 https://doi.org/10.1016/j.scitotenv.2020.144285
  8. R. J. Southard, X. Li, E. A. Eisen, K. E. Pinkerton, Silica, Crystalline, in: P. Wexler (Ed.) Encyclopedia of Toxicology (Third Edition), Elsevier, Oxford, 2014, https://doi.org/10.1016/B978-0-12-386454-3.00061-0
  9. Devadas Bhat Panemangalore, Rajashekhara Shabadi, David Tingaud, Matthieu Touzin, Gang Ji, Biocompatible silica-based magnesium composites, Journal of Alloys and Compounds, 772, (2019), 49-57 https://doi.org/10.1016/j.jallcom.2018.09.060
  10. Beata Podkościelna, Mateusz Gargol, Marta Goliszek, Tomasz Klepka, Olena Sevastyanova, Degradation and flammability of bioplastics based on PLA and lignin, Polymer Testing, 111, (2022), 107622 https://doi.org/10.1016/j.polymertesting.2022.107622
  11. Ika Zuwanna, Medyan Riza, Sri Aprilia, Yanna Syamsuddin, Rozanna Dewi, Preparation and characterization of silica from rice husk ash as a reinforcing agent in whey protein isolate biocomposites film, South African Journal of Chemical Engineering, 44, (2023), 337-343 https://doi.org/10.1016/j.sajce.2023.03.005
  12. Xuefei Wang, Lingling Wu, Haiwen Yu, Tongliang Xiao, Huaming Li, Jun Yang, Modified silica-based isoprene rubber composite by a multi-functional silane: Preparation and its mechanical and dynamic mechanical properties, Polymer Testing, 91, (2020), 106840 https://doi.org/10.1016/j.polymertesting.2020.106840
  13. Aswathy Jayakumar, K. V. Heera, T. S. Sumi, Meritta Joseph, Shiji Mathew, G. Praveen, Indu C. Nair, E. K. Radhakrishnan, Starch-PVA composite films with zinc-oxide nanoparticles and phytochemicals as intelligent pH sensing wraps for food packaging application, International Journal of Biological Macromolecules, 136, (2019), 395-403 https://doi.org/10.1016/j.ijbiomac.2019.06.018
  14. Tomáš Remiš, Petr Bělský, Tomáš Kovářík, Jaroslav Kadlec, Mina Ghafouri Azar, Rostislav Medlín, Veronika Vavruňková, Kalim Deshmukh, Kishor Kumar Sadasivuni, Study on structure, thermal behavior, and viscoelastic properties of nanodiamond-reinforced poly (vinyl alcohol) nanocomposites, Polymers, 13, 9, (2021), 1426 https://doi.org/10.3390/polym13091426
  15. Sharmila Patil, Ashok Kumar Bharimalla, Archana Mahapatra, Jyoti Dhakane-Lad, A. Arputharaj, Manoj Kumar, A. S. M. Raja, Nishant Kambli, Effect of polymer blending on mechanical and barrier properties of starch-polyvinyl alcohol based biodegradable composite films, Food Bioscience, 44, (2021), 101352 https://doi.org/10.1016/j.fbio.2021.101352
  16. Ruowen Tan, Feng Li, You Zhang, Zihui Yuan, Xuefei Feng, Wansong Zhang, Ting Liang, Jiwen Cao, Cornelis F De Hoop, Xiaopeng Peng, Xingyan Huang, High-performance biocomposite polyvinyl alcohol (PVA) films modified with cellulose nanocrystals (CNCs), tannic acid (TA), and chitosan (CS) for food packaging, Journal of Nanomaterials, 2021, (2021), 4821717 https://doi.org/10.1155/2021/4821717
  17. Siti Nuurul Huda Mohammad Azmin, Mohd Shukri Mat Nor, Development and characterization of food packaging bioplastic film from cocoa pod husk cellulose incorporated with sugarcane bagasse fibre, Journal of Bioresources and Bioproducts, 5, 4, (2020), 248-255 https://doi.org/10.1016/j.jobab.2020.10.003
  18. Layung Sari, Endaruji Sedyadi, Irwan Nugraha, Didik Krisdiyanto, The Effect of Stocking Temperature on Biodegradable Plastic Characteristics of Suweg Tuber (Amorphophallus campanulatus) with Addition of Glycerol and CMC (Carboxy Methyl Cellulose), Proceeding International Conference on Science and Engineering, 2019 https://doi.org/10.14421/icse.v2.87
  19. María Alonso-González, Manuel Felix, Antonio Guerrero, Alberto Romero, Rice bran-based bioplastics: Effects of the mixing temperature on starch plastification and final properties, International Journal of Biological Macromolecules, 188, (2021), 932-940 https://doi.org/10.1016/j.ijbiomac.2021.08.043
  20. Mari Pau Balaguer, Joaquin Gomez-Estaca, Josep Pasqual Cerisuelo, Rafael Gavara, Pilar Hernandez-Munoz, Effect of thermo-pressing temperature on the functional properties of bioplastics made from a renewable wheat gliadin resin, LWT-Food Science and Technology, 56, 1, (2014), 161-167 https://doi.org/10.1016/j.lwt.2013.10.035
  21. N. H. Zakaria, N. Muhammad, A. V. Sandu, M. M. A. B. Abdullah, Effect of mixing temperature on characteristics of thermoplastic potato starch film, IOP Conference Series: Materials Science and Engineering, 2018 https://doi.org/10.1088/1757-899X/374/1/012083
  22. MohammanAsaduzzaman Chowdhury, Nayem Hossain, Tauhidul Islam Noman, Ali Hasan, Alam Shafiul, Kashem Mohammod Abul, Biodegradable, physical and microbial analysis of tamarind seed starch infused eco-friendly bioplastics by different percentage of Arjuna powder, Results in Engineering, 13, (2022), 100387 https://doi.org/10.1016/j.rineng.2022.100387
  23. Md. Ruhul Amin, Mohammad Asaduzzaman Chowdhury, Md. Arefin Kowser, Characterization and performance analysis of composite bioplastics synthesized using titanium dioxide nanoparticles with corn starch, Heliyon, 5, 8, (2019), e02009 https://doi.org/10.1016/j.heliyon.2019.e02009
  24. Yuni Kusumastuti, Nur Rofiqoh Eviana Putri, Daniel Timotius, Muh Wahyu Syabani, Effect of chitosan addition on the properties of low-density polyethylene blend as potential bioplastic, Heliyon, 6, 11, (2020), e05280 https://doi.org/10.1016/j.heliyon.2020.e05280
  25. Ana Isabel Quilez-Molina, José Alejandro Heredia-Guerrero, Andrea Armirotti, Uttam C. Paul, Athanassia Athanassiou, Ilker S. Bayer, Comparison of physicochemical, mechanical and antioxidant properties of polyvinyl alcohol films containing green tealeaves waste extracts and discarded balsamic vinegar, Food Packaging and Shelf Life, 23, (2020), 100445 https://doi.org/10.1016/j.fpsl.2019.100445
  26. Jéssica N. N. Bueno, Elisangela Corradini, Paulo R. de Souza, Vicente de S. Marques, Eduardo Radovanovic, Edvani C. Muniz, Films based on mixtures of zein, chitosan, and PVA: Development with perspectives for food packaging application, Polymer Testing, 101, (2021), 107279 https://doi.org/10.1016/j.polymertesting.2021.107279
  27. Aanchal Mittal, Sangeeta Garg, Shailendra Bajpai, Thermal decomposition kinetics and properties of grafted barley husk reinforced PVA/starch composite films for packaging applications, Carbohydrate Polymers, 240, (2020), 116225 https://doi.org/10.1016/j.carbpol.2020.116225
  28. Henry C. Oyeoka, Chinomso M. Ewulonu, Iheoma C. Nwuzor, Chizoba M. Obele, Joseph T. Nwabanne, Packaging and degradability properties of polyvinyl alcohol/gelatin nanocomposite films filled water hyacinth cellulose nanocrystals, Journal of Bioresources and Bioproducts, 6, 2, (2021), 168-185 https://doi.org/10.1016/j.jobab.2021.02.009
  29. Nilgün Özdemir, Hojjat Pashazadeh, Oscar Zannou, Ilkay Koca, Phytochemical content, and antioxidant activity, and volatile compounds associated with the aromatic property, of the vinegar produced from rosehip fruit (Rosa canina L.), LWT, 154, (2022), 112716 https://doi.org/10.1016/j.lwt.2021.112716
  30. Sina Ebnesajjad, Surface and material characterization techniques, in: Handbook of Adhesives and Surface Preparation, Elsevier, 2011,
  31. Yasir Arafat, Ammar Altemimi, Anubhav Pratap-Singh, Laxmikant S. Badwaik, Active biodegradable films based on sweet lime peel residue and its effect on quality of fish fillets, Polymers, 13, 8, (2021), 1240 https://doi.org/10.3390/polym13081240
  32. Ana Priscila M. Silva, Ana Vitória Oliveira, Sheyliane M. A. Pontes, Men de sá M. Souza Filho, André L. S. Pereira, Morsyleide F. Rosa, Henriette M. C. Azeredo, Mango kernel starch films as affected by starch nanocrystals and cellulose nanocrystals, Carbohydrate Polymers, 211, (2019), 209-216 https://doi.org/10.1016/j.carbpol.2019.02.013
  33. Nur Athirah Huzaisham, Noraini Marsi, Utilization of banana (Musa paradisiaca) peel as bioplastic for planting bag application, International Journal of Advanced Research in Engineering and Technology, 11, 4, (2020), 108-118
  34. Hossein Haghighi, Maria Gullo, Salvatore La China, Frank Pfeifer, Heinz Wilhelm Siesler, Fabio Licciardello, Andrea Pulvirenti, Characterization of bio-nanocomposite films based on gelatin/polyvinyl alcohol blend reinforced with bacterial cellulose nanowhiskers for food packaging applications, Food Hydrocolloids, 113, (2021), 106454 https://doi.org/10.1016/j.foodhyd.2020.106454
  35. Mohammad Asaduzzaman Chowdhury, Nayem Hossain, M. D. Badrudduza, Md. Masud Rana, Development and characterization of natural sourced bioplastic for food packaging applications, Heliyon, 9, 2, (2023), e13538 https://doi.org/10.1016/j.heliyon.2023.e13538
  36. Abdulrahman A. B. A. Mohammed, Zaimah Hasan, Abdoulhdi A. Borhana Omran, Abdulhafid M. Elfaghi, Yasir Hassan Ali, Norie A. A. Akeel, R. A. Ilyas, S. M. Sapuan, Effect of sugar palm fibers on the properties of blended wheat starch/polyvinyl alcohol (PVA)-based biocomposite films, Journal of Materials Research and Technology, 24, (2023), 1043-1055 https://doi.org/10.1016/j.jmrt.2023.02.027

Last update:

No citation recorded.

Last update: 2024-12-26 10:17:01

No citation recorded.