DOI: https://doi.org/10.14710/jksa.26.6.211-216

The Synthesis and Characterization of Pahae Natural Zeolite-Coal Bottom Ash Adsorbent for Fe and Mn Purifier in Well Water

1Department of Physics, Faculty of Mathematics and Natural Science, Universitas Sumatera Utara, Medan 20155, Indonesia

2Research Center for Biomass and Bioproducts, National Research and Innovation Agency of Indonesia (BRIN), Cibinong 16911, Indonesia

Received: 28 Apr 2023; Revised: 18 Aug 2023; Accepted: 22 Aug 2023; Published: 30 Sep 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

Zeolite is a porous crystalline mineral alumina silica tetrahydrate that has an open three-dimensional framework structure that has channels and cavities filled with metal ions, while Bottom ash is also known to have high porosity and surface area. Thus, both zeolite and bottom ash can be used as adsorbents. This study aims to make an adsorbent based on Pahae natural zeolite with a mixture of bottom ash from coal as an adsorbent for iron (Fe) and manganese (Mn) metals in well water. Adsorbent made from Natural Zeolite Pahae-Coal Bottom Ash with a size of 200 mesh (74 µm) which has been chemically activated with 1 M NaOH solution, was prepared with various compositions of (100:0)%, (95:5)%, (90:10)%, (85:15)%, (80:20)%, (75:25)% respectively, then mold using a hydraulic press with a load of 6 tons of weight for 10 minutes. The mold samples were then physically activated with temperature variations of 600°C, 700°C, and 800°C for 4 hours, respectively. The addition of coal bottom ash filler is known to increase the porosity of the adsorbent with the composition of (75:25)% with an activated temperature of 800°C by 10%. The results of the AAS test showed that the adsorbent made from Natural Zeolite Pahae-Coal Bottom Ash reduced the content of Fe and Mn metals by 92.37% and 53.49% in well water, respectively.

Fulltext View|Download
Keywords: Adsorbent; Pahae Natural Zeolite; Coal Bottom Ash; Fe and Mn

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Isolation, Identification, and Antibacterial Testing of Essential Oil from Green Betel Leaf (Piper Betle L.) Using Well Diffusion Method The Synthesis and Characterization of Pahae Natural Zeolite-Coal Bottom Ash Adsorbent for Fe and Mn Purifier in Well Water Isolation, Structure Determination, and Cytotoxic Activity of Steroid Compound from The Stem Bark of Aglaia cucullata (Meliaceae) More recent articles
Most cited articles
Chitosan succinate/PVA-PEG Membrane: Preparation, Characterization and Permeation Ability Test on Creatinine Sintesis Zeolit A dan Kemungkinan Penggunaannya Sebagai Penukar Kation Antioxidant Activity of Daemonorops draco Resin Pirolisis Kulit Biji Jambu Mete (Anacardium occidentale L.) dengan Katalis Ni-Ag/Zeolit Profil Kandungan Protein dan Tekstur Tahu Akibat Penambahan Fitat pada Proses Pembuatan Tahu More cited articles
  1. Anna Fadliah Rusydi, Shin-Ichi Onodera, Mitsuyo Saito, Seiichiro Ioka, Rizka Maria, Iwan Ridwansyah, Robert M. Delinom, Vulnerability of groundwater to iron and manganese contamination in the coastal alluvial plain of a developing Indonesian city, SN Applied Sciences, 3, (2021), 399 https://doi.org/10.1007/s42452-021-04385-y
  2. Saiful, A. Gani, A. Ulim, Surface water quality analysis and monitoring in Aceh Jaya district, Indonesia, IOP Conference Series: Earth and Environmental Science, 2019 https://doi.org/10.1088/1755-1315/364/1/012037
  3. Mega Fia Lestari, Muhammad Ilham Al’Wahid, Muhammad Ikram Nur Fuady, Yusriadi, Baiq Amelia Riyandari, Devi Nur Anisa, Analysis of mineral water quality based on SNI 3553: 2015 and its consequences from legal perspectives, IOP Conference Series: Earth and Environmental Science, 2023 https://doi.org/10.1088/1755-1315/1190/1/012041
  4. Vinod R. Bhagwat, Safety of Water Used in Food Production, in: Food Safety and Human Health, Elsevier, 2019, https://doi.org/10.1016/B978-0-12-816333-7.00009-6
  5. Bright Kwakye-Awuah, Baah Sefa-Ntiri, Elizabeth Von-Kiti, Isaac Nkrumah, Craig Williams, Adsorptive Removal of Iron and Manganese from Groundwater Samples in Ghana by Zeolite Y Synthesized from Bauxite and Kaolin, Water, 11, 9, (2019), 1912 https://doi.org/10.3390/w11091912
  6. Abdul Khaleque, Md Masruck Alam, Mozammel Hoque, Shuvodip Mondal, Jahid Bin Haider, Bentuo Xu, M. A. H. Johir, Aneek Krishna Karmakar, J. L. Zhou, Mohammad Boshir Ahmed, Mohammad Ali Moni, Zeolite synthesis from low-cost materials and environmental applications: A review, Environmental Advances, 2, (2020), 100019 https://doi.org/10.1016/j.envadv.2020.100019
  7. Tessema Derbe, Shewaye Temesgen, Mamaru Bitew, A Short Review on Synthesis, Characterization, and Applications of Zeolites, Advances in Materials Science and Engineering, 2021, (2021), 6637898 https://doi.org/10.1155/2021/6637898
  8. Venkataraman Sivasankar, Thiagarajan Ramachandramoorthy, Water softening behaviour of sand materials—Mimicking natural zeolites in some locations of Rameswaram Island, India, Chemical Engineering Journal, 171, 1, (2011), 24-32 https://doi.org/10.1016/j.cej.2011.03.032
  9. F. Mukarrom, R. Karsidi, E. Gravitiani, F. Astuti, W. Maharditya, The assessment of claystone, quartz and coconut shell charcoal for adsorbing heavy metals ions in acid mine drainage, IOP Conference Series: Materials Science and Engineering, 2020 https://doi.org/10.1088/1757-899X/858/1/012040
  10. Gustri Nurliati, Y. K. Krisnandi, R. Sihombing, Zainus Salimin, Studies of Modification of Zeolite by Tandem Acid-Base Treatments and its Adsorptions Performance Towards Thorium, Atom Indonesia, 41, 2, (2015), 87-95 http://dx.doi.org/10.17146/aij.2015.382
  11. Shaobin Wang, Yuelian Peng, Natural zeolites as effective adsorbents in water and wastewater treatment, Chemical Engineering Journal, 156, 1, (2010), 11-24 https://doi.org/10.1016/j.cej.2009.10.029
  12. Young-Kyu Hong, Jin-Wook Kim, Hyuck-Soo Kim, Sang-Phil Lee, Jae-E Yang, Sung-Chul Kim, Bottom Ash Modification via Sintering Process for Its Use as a Potential Heavy Metal Adsorbent: Sorption Kinetics and Mechanism, Materials, 14, 11, (2021), 3060 https://doi.org/10.3390/ma14113060
  13. Kedsarin Pimraksa, Prinya Chindaprasirt, Tanwalak Huanjit, Clarence Tang, Tsugio Sato, Cement mortars hybridized with zeolite and zeolite-like materials made of lignite bottom ash for heavy metal encapsulation, Journal of Cleaner Production, 41, (2013), 31-41 https://doi.org/10.1016/j.jclepro.2012.10.003
  14. Hongxu Zhou, Rabin Bhattarai, Yunkai Li, Buchun Si, Xinxin Dong, Tengfei Wang, Zhitong Yao, Towards sustainable coal industry: Turning coal bottom ash into wealth, Science of The Total Environment, 804, (2022), 149985 https://doi.org/10.1016/j.scitotenv.2021.149985
  15. Susilawati, Yuan Alfinsyah Sihombing, Siti Utari Rahayu, Lilik Waldiansyah, Yuni Yati Br Sembiring, The Effectiveness of Pahae Natural Zeolite–Cocoa Shell Activated Charcoal Nanofilter as a Water Adsorbent in Bioethanol Purification, ACS Omega, 7, 43, (2022), 38417-38425 https://doi.org/10.1021/acsomega.2c03614
  16. Susilawati, Yuan Alfinsyah Sihombing, Siti Utari Rahayu, Yuni Yati Br Sembiring, Lilik Waldiansyah, Mutia Irma, Filter material based on zeolite-activated charcoal from cocoa shells as ammonium adsorbent in greywater treatment, South African Journal of Chemical Engineering, 43, (2023), 266-272 https://doi.org/10.1016/j.sajce.2022.11.006
  17. Jingyang Gao, Li Zhang, Qunyu Gao, Lei Wu, Erjuan Zhang, A study on physicochemical properties and adsorption performance of modified porous maize starch, Materials Research Express, 5, 12, (2018), 125303 https://doi.org/10.1088/2053-1591/aae0b4
  18. Marta Trzaskowska, Vladyslav Vivcharenko, Agata Przekora, The Impact of Hydroxyapatite Sintering Temperature on Its Microstructural, Mechanical, and Biological Properties, International Journal of Molecular Sciences, 24, 6, (2023), 5083 https://doi.org/10.3390/ijms24065083
  19. Mirzan T. Razzak, Thamzil Las, Priyambodo, The Characterization of Indonesian's Natural Zeolite For Water Filtration System, Jurnal Kimia Valensi, 3, 2, (2013), 129-137 https://doi.org/10.15408/jkv.v3i2.518
  20. Reza Shoja Razavi, Mohammad Reza Loghman-Estarki, Synthesis and Characterizations of Copper Oxide Nanoparticles Within Zeolite Y, Journal of Cluster Science, 23, (2012), 1097-1106 https://doi.org/10.1007/s10876-012-0502-y
  21. Navdeep Singh, Shehnazdeep, Anjani Bhardwaj, Reviewing the role of coal bottom ash as an alternative of cement, Construction and Building Materials, 233, (2020), 117276 https://doi.org/10.1016/j.conbuildmat.2019.117276
  22. Cheng Wang, Huidong Guo, Jiale Yu, Kai Feng, Jianfeng Huang, Micro/nanostructural silica/alkali-treated natural zeolite coated fabrics for oil-water separation and heavy metal ions removal, Microporous and Mesoporous Materials, 327, (2021), 111430 https://doi.org/10.1016/j.micromeso.2021.111430
  23. Eduardo Pérez-Botella, Susana Valencia, Fernando Rey, Zeolites in adsorption processes: State of the art and future prospects, Chemical Reviews, 122, 24, (2022), 17647-17695 https://doi.org/10.1021/acs.chemrev.2c00140
  24. Ewout Kemner, Ignatz M. de Schepper, Gordon J. Kearley, How van der Waals bonds orient molecules in zeolites, Chemical Communications, 23, (2001), 2466-2467 https://doi.org/10.1039/B105611P
  25. Samuela Guida, Chris Potter, Bruce Jefferson, Ana Soares, Preparation and evaluation of zeolites for ammonium removal from municipal wastewater through ion exchange process, Scientific Reports, 10, (2020), 12426 https://doi.org/10.1038/s41598-020-69348-6
  26. Mei Hong, Lingyun Yu, Yanding Wang, Jian Zhang, Zhuwen Chen, Lei Dong, Qijie Zan, Ruili Li, Heavy metal adsorption with zeolites: The role of hierarchical pore architecture, Chemical Engineering Journal, 359, (2019), 363-372 https://doi.org/10.1016/j.cej.2018.11.087

Last update:

No citation recorded.

Last update: 2024-05-04 23:23:59

No citation recorded.