DOI: https://doi.org/10.14710/jksa.28.3.122-129

Zeolite/Hydrilla verticillata Composite for the Adsorption of Naphthol Blue Black Dye

1Chemistry Study Program, Faculty of Science, Universitas Islam Negeri Sultan Maulana Hasanuddin Banten, Banten, Indonesia

2Physics Study Program, Faculty of Science, Universitas Islam Negeri Sultan Maulana Hasanuddin Banten, Banten, Indonesia

3Biology Study Program, Faculty of Science, Universitas Islam Negeri Sultan Maulana Hasanuddin Banten, Banten, Indonesia

Received: 31 Dec 2024; Revised: 28 Mar 2025; Accepted: 8 Apr 2025; Published: 30 Apr 2025.
Open Access Copyright 2025 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
In this study, a zeolite/Hydrilla verticillata composite adsorbent was prepared and characterized, and its performance was evaluated for the adsorption of Naphtol Blue Black (NBB) dye. Natural zeolite sourced from Bayah, Banten, was used as the base material. The composite was synthesized using the wet impregnation technique. Characterization was conducted using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). FTIR analysis showed absorption bands at 2919 cm-1, 514 cm- 1, and 1014 cm-1, indicating the successful formation of the zeolite/Hydrilla verticillata composite. XRD results revealed that the Bayah natural zeolite contains modernite and heulandite crystal phases, with an average crystallite size of 9.3 nm calculated using the Scherrer equation. SEM images indicated that the zeolite surface was largely covered by Hydrilla verticillata particles. The adsorption experiment showed that the composite adsorbent achieved a 34.07% removal efficiency of NBB dye. The adsorption process followed the Freundlich isotherm model, with an R2 value of 0.9995 and a maximum adsorption capacity of 13.59 mg/g.
Fulltext View|Download
Keywords: adsorption; Hydrilla verticillata; composite; zeolite
Funding: UIN Sultan Maulana Hasanuddin Banten under contract Rector’s Decree Number 1508 of 2024

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Zeolite/Hydrilla verticillata Composite for the Adsorption of Naphthol Blue Black Dye The Potency of Noni Leaves Extract (Morinda citrifolia L.) as a Bioreductor in the Synthesis of Copper Nanoparticles and Its Effectiveness as an Antibacterial against Streptococcus pyogenes Unraveling the Density and Hardness of Sintered Hydroxyapatite: A Conclusive Comparison of Laboratory-Synthesized Versus Commercial Variants More recent articles
Most cited articles
Pengaruh Serbuk Kaca dan Variasi Suhu Pembakaran pada Pembuatan Genteng Lempung Sedimentasi Banjir Kanal Timur Kota Semarang terhadap Kuat Tekan serta Daya Serapnya terhadap Air Pengelolaan Alat Bahan dan Laboratorium Kimia Pengaruh Konsentrasi Substrat Maltosa terhadap Potensial Listrik Baterai Lactobacillus bulgaricus (MFC) Isolasi Bakteri Termofilik Sumber Air Panas Gedongsongo dengan Media Pengaya Minimal YT (Yeast Tripton) serta Identifikasi Genotipik dan Fenotipik Preparasi Katalis Zeolit Alam Asam sebagai Katalis dalam Proses Pirolisis Katalitik Polietilena More cited articles
  1. Sheilatina Sheilatina, Fathurrahmi Fathurrahmi, Fathur Robbani, Adsorption of Naphtol Blue Black (NBB) Dye over Immobilized Chitosan from Shrimp Shells onto Glass Plate, Journal of Pharmaceutical and Sciences, 5, 1, (2022), 21-32 https://doi.org/10.36490/journal-jps.com.v5i1.93
  2. Anugrah Alief, Mohamad Hanif Hawari, Otniel Jenifer, Fahrezi Muhammad Reza, Radian Muhamad, Siswajanthy Farahdinny, Analisis Industri Tekstil Di Jawa Barat Sebelum Dan Setelah Krisis Ekonomi, Doktrin: Jurnal Dunia Ilmu Hukum dan Politik, 2, 2, (2024), 118-135 https://doi.org/10.59581/doktrin.v2i2.2579
  3. Hanane Afanga, Hicham Zazou, Fatima Ezzahra Titchou, Jamila El Gaayda, Flamur Sopaj, Rachid Ait Akbour, Mohamed Hamdani, Electrochemical oxidation of Naphthol Blue Black with different supporting electrolytes using a BDD /carbon felt cell, Journal of Environmental Chemical Engineering, 9, 1, (2021), 104498 https://doi.org/10.1016/j.jece.2020.104498
  4. Ponnusamy Senthil Kumar, Sunita J. Varjani, Subburaj Suganya, Treatment of dye wastewater using an ultrasonic aided nanoparticle stacked activated carbon: Kinetic and isotherm modelling, Bioresource Technology, 250, (2018), 716-722 https://doi.org/10.1016/j.biortech.2017.11.097
  5. Zilfa, Rahmayeni, B. Arifin, V. Sisca, E. S. Putri, Photolysis of Naphthol Blue-Black from Kubang Weaving Waste Using TiO2/Zeolite as a Catalyst, Rasayan Journal of Chemistry, 14, 2, (2021), 1247-1254 http://dx.doi.org/10.31788/RJC.2021.1426099
  6. Valerie Atirza, Prayatni Soewondo, Penyisihan Zat Warna Naphthol pada Limbah Cair Batik dengan Metode Adsorpsi Menggunakan Adsorben Tanah Liat dan Regenerasinya, Jurnal Teknik Lingkungan, 24, 1, (2018), 93-106 https://doi.org/10.5614/j.tl.2018.24.1.7
  7. Novita Santalia Nika, Imanuel Gauru, Luther Kadang, Theodore Y. K. Lulan, Adsorpsi Zat Warna Naphtol Menggunakan Adsorben Kulit Buah Kakao (Theobroma Cacao L.), Jurnal Fisika: Fisika Sains dan Aplikasinya, 7, 1, (2022), 101-108
  8. Sekar Wangi Retno Pembayun, Maya Rahmayanti, Efektivitas Biji Asam Jawa Sebagai Koagulan Alami dalam Menurunkan Konsentrasi Zat Warna Remazol red dan Nilai COD, JST (Jurnal Sains dan Teknologi), 9, 2, (2020), 162-169 https://doi.org/10.23887/jstundiksha.v9i2.28171
  9. M. S. K. Amal, F. Febiyanto, A. Soleh, M. Afif, Elektrodekolorisasi Limbah Cair Pewarna Batik Dengan Memanfaatkan Batang Karbon Dari Limbah Baterai Bekas, Indonesian Journal of Mathematics and Natural Sciences, 39, 2, (2016), 135-142
  10. Hemant Kumar, Arun Giri, Amit Rai, Photocatalytic degradation of naphthol blue black dye using undoped and Al-doped cobalt ferrite nanoparticles, Kuwait Journal of Science, 51, 2, (2024), 100208 https://doi.org/10.1016/j.kjs.2024.100208
  11. Laura Dwi Rha Hayu, Edi Nasra, Minda Azhar, Sri Benti Etika, Adsorpsi Zat Warna Methylene Blue Menggunakan Karbon Aktif dari Kulit Durian (Durio zibethinus Murr.), Periodic, 10, 2, (2022), 8-13 https://doi.org/10.24036/p.v11i1.113349
  12. Surya Lubis, Sheilatina Sheilatina, Vicky Praja Putra, Adsorption of Naphthol Blue Black Dye onto Acid Activated Titania Pillared Bentonite: Equilibrium Study, Oriental Journal of Chemistry, 32, 4, (2016), 1789-1797 http://dx.doi.org/10.13005/ojc/320407
  13. Andi Nafis An Naafi, Rachmat Triandi Tjahjanto, Yuniar Ponco Prananto, Effect of NaOH Concentration Toward the Characteristics of Activated Natural Zeolite from Blitar – East Java, Jurnal Kimia Sains dan Aplikasi, 26, 2, (2023), 50-56 https://doi.org/10.14710/jksa.26.2.50-56
  14. Mohamad Hakiki, Mohamad Makiyi, Nuryoto Nuryoto, Rahmayetty Rahmayetty, Indar Kustiningsih, Teguh Kurniawan, Pengaruh Lokasi Zeolit Alam Bayah terhadap Adsorpsi Amonium: Studi Kinetika dan Kesetimbangan, Jurnal Teknologi Lingkungan, 22, 1, (2021), 018-028
  15. Indar Kustiningsih, Denni Kartika Sari, Uji Adsorbsi Zeolit Alam Bayah dan Pengaruh Sinar Ultraviolet Terhadap Degradasi Limbah Methylene Blue, Teknika: Jurnal Sains dan Teknologi, 13, 1, (2017), 25-32
  16. Nuryoto Nuryoto, Ghani Naufal, Raffli Nurmuhammad, Teguh Kurniawan, Studi penjerapan ammonia menggunakan zeolit alam bayah tanpa aktivasi pada tambak ikan, Jurnal Integrasi Proses, 9, 2, (2020), 21-26 https://dx.doi.org/10.36055/jip.v9i2.9172
  17. Iwan Setiawan, Leny M. Estiaty, Dewi Fatimah, Sri Indarto, Lediyantje Lintjewas, Andri Alkausar, Aryo D. Handoko, Anita Yuliyanti, Jakah Jakah, Geologi dan Petrokimia Endapan Zeolit Daerah Bayah dan Sukabumi, Riset Geologi dan Pertambangan, 30, 1, (2020), 39-54 http://dx.doi.org/10.14203/risetgeotam2020.v30.1048
  18. Muchamad Ismettulloh, Fajar Gumelar, Nuryoto Nuryoto, Teguh Kurniawan, Modifikasi Zeolit Alam Bayah Menggunakan Asam dan Pengaplikasiannya Dalam Pengurangan Amonium Pada Kolam Ikan Bandeng, Jurnal Integrasi Proses, 8, 1, (2019), 07-13 https://dx.doi.org/10.36055/jip.v8i1.5506
  19. Charissa Dini Sofith, Sri Rahmadaniati Effendi, Fatimah, Kinerja Aktivasi dan Impregnasi Zeolit Alam sebagai Adsorben, Jurnal Teknik Kimia USU, 9, 2, (2020), 75-79 https://doi.org/10.32734/jtk.v9i2.3764
  20. Yulius Dala Ngapa, Yasinta Embu Ika, Potensi Zeolit Alam Ende Sebagai Media Adsorben Kompetitif Pewarna Biru Metilena dan Metil Oranye, Cakra Kimia (Indonesian E- Journal of Applied Chemistry), 8, 2, (2020), 105-113
  21. Neni Damajanti, Anwar Ma’ruf, Hanafi Khafid Nugraha, Aplikasi Zeolit Alam Aktif Wonosari Sebagai Adsorben Zat Warna Remazol Yellow Fg, Proceedings Series on Physical & Formal Sciences, 1, (2021), 80-87 https://doi.org/10.30595/pspfs.v1i.138
  22. Muhammad Al Muttaqii, David Candra Birawidha, Kusno Isnugroho, Muhammad Yamin, Yusup Hendronursito, Amila Dini Istiqomah, Diego Putra Dewangga, Pengaruh aktivasi secara kimia menggunakan larutan asam dan basa terhadap karakteristik zeolit alam, Jurnal Riset Teknologi Industri, 13, 2, (2019), 266-271
  23. Laura Bulgariu, Dumitru Bulgariu, Enhancing Biosorption Characteristics of Marine Green Algae (Ulva lactuca) for Heavy Metals Removal by Alkaline Treatment, Journal of Bioprocessing & Biotechniques, 4, 1, (2014), 1000146 https://doi.org/10.4172/2155-9821.1000146
  24. Saravanan Narayanan, Rathika Govindasamy, Kinetic and Equilibrium Studies of Malachite Green Adsorption by Low Cost Adsorbent, International Journal of Chemical Sciences, 15, 4, (2017), 189
  25. Rakesh Kumar Vij, V. Aruna Janani, Deepalakshmi Subramanian, Chintan R. Mistry, Gokul Devaraj, Sivakumar Pandian, Equilibrium, kinetic and thermodynamic studies for the removal of Reactive Red dye 120 using Hydrilla verticillata biomass: A batch and column study, Environmental Technology & Innovation, 24, (2021), 102009 https://doi.org/10.1016/j.eti.2021.102009
  26. R. Rajeshkannan, M. Rajasimman, N. Rajamohan, Removal of malachite green from aqueous solution using hydrilla verticillata-optimization, equilibrium and kinetic studies, International Journal of Civil and Environmental Engineering, 2, 4, (2010), 222-229
  27. Yohana Puji Lestari, Tien Aminatun, Efektivitas variasi biomassa tanaman Hydrilla verticillata dalam fitoremediasi limbah batik, Kingdom: The Journal of Biological Studies, 7, 4, (2018), 233-241 https://doi.org/10.21831/kingdom.v7i4.12542
  28. C. A. I. Raju, N. V. R. Nethi, Congo Red Dye Removal using Hydrilla Verticillata Powder and Optimization through Box Behnken Design, International Journal for Research in Applied Science & Engineering Technology, 6, 3, (2018), 1506-1521 http://doi.org/10.22214/ijraset.2018.3233
  29. Ade Irmadiki Agipa, Roza Ruspita, Muhamad Fajar Muarif, Al Baasiqot Shoffia Nur Jannah, Penurunan Kadar COD Pada Limbah Cair Laboratorium Menggunakan Sorben Hydrilla Verticillata, Jurnal Ilmiah Teknik Kimia, 8, 1, (2024), 24-31 https://doi.org/10.32493/jitk.v8i1.36188
  30. Anang Takwanto, Maryanty Yanty, Mustikarini Anugrah Windy, Sari Dina Wulan, Juliansyah Rizki Kurnia, Komposit Zeolit-Polivinil Alkohol sebagai Adsorben untuk Menurunkan Kesadahan Air Tanah, Jurnal Riset Kimia, 14, 2, (2023), 131-144 https://doi.org/10.25077/jrk.v14i2.597
  31. Ahmed Hamd, Asmaa Ragab Dryaz, Mohamed Shaban, Hamad AlMohamadi, Khulood A. Abu Al-Ola, Nofal Khamis Soliman, Sayed A. Ahmed, Fabrication and Application of Zeolite/Acanthophora Spicifera Nanoporous Composite for Adsorption of Congo Red Dye from Wastewater, Nanomaterials, 11, 9, (2021), 2441 https://doi.org/10.3390/nano11092441
  32. Ahmed Hamd, Mohamed Shaban, Ghadah M. Al-Senani, Mashael N. Alshabanat, Azza Al-Ghamdi, Asmaa Ragab Dryaz, Sayed A. Ahmed, Refat El-Sayed, N. K. Soliman, Comprehensive evaluation of zeolite/marine alga nanocomposite in the removal of waste dye from industrial wastewater, Scientific Reports, 13, 1, (2023), 8082 https://doi.org/10.1038/s41598-023-34094-y
  33. Ahmed Hamd, Mohamed Shaban, Hamad AlMohamadi, Asmaa Ragab Dryaz, Sayed A. Ahmed, Khulood A. Abu Al-Ola, Hamada R. Abd El-Mageed, Nofal K. Soliman, Novel Wastewater Treatment by Using Newly Prepared Green Seaweed–Zeolite Nanocomposite, ACS Omega, 7, 13, (2022), 11044-11056 https://doi.org/10.1021/acsomega.1c06998
  34. Gökmen T. Şanlı, Elçin Demirhan, Preparation and characterization of chitosan/zeolite composites for Reactive Orange 122 dye removal from aqueous media: isotherm and kinetic studies, Biomass Conversion and Biorefinery, 15, 3, (2025), 3653-3662 https://doi.org/10.1007/s13399-024-05284-z
  35. Amany G. Braish, Asaad F. Hassan, Shimaa A. El-Essawy, Mohsen M. T. El-Tahawy, Fabrication of nanozeolite-Y/chitosan composite based on rice husks for efficient adsorption of methylene blue dye: kinetic and thermodynamic studies, Adsorption, 30, 7, (2024), 1643-1661 https://doi.org/10.1007/s10450-024-00527-x
  36. Ismat Ara Eti, Marufa Khatun, Most. Afroza Khatun, Md. Owaleur Rahman, K. M. Anis-Ul-Haque, Md. Jahangir Alam, Removal of Dye from Wastewater Using a Novel Composite Film Incorporating Nanocellulose, Advances in Polymer Technology, 2023, 1, (2023), 4431941 https://doi.org/10.1155/2023/4431941
  37. N. K. Soliman, Mohamed Shaban, Sayed A. Ahmed, Asmaa Ragab ryaz, H. R. Abd El-Mageed, Refat El-Sayed, Esam S. Allehyani, Hamed M. Al-Saidi, Khaled N. M. lsayed, Ahmed Hamd, Low-cost Liagora farinosa/zeolite nanoporous composite for Congo red removal from wastewater, Desalination and Water Treatment, 267, (2022), 266-282 https://doi.org/10.5004/dwt.2022.28688
  38. Catherina Manukpadang Bijang, Yustinus Thobias Male, Shielda Natalia Joris, Chrismenda Kartini Wattimena, Application of Acid Activated Ouw’s Natural Clay (ONC) on Adsorption of Methylene Blue Dye, Jurnal Kimia Sains dan Aplikasi, 27, 3, (2024), 121-127 https://doi.org/10.14710/jksa.27.3.121-127
  39. Irving Langmuir, The constitution and fundamental properties of solids and liquids. Part II.—Liquids, Journal of the Franklin Institute, 184, 5, (1917), 721 https://doi.org/10.1016/S0016-0032(17)90088-2
  40. Herbert Freundlich, Über die Adsorption in Lösungen, 1907, ^ https://doi.org/10.1515/zpch-1907-5723
  41. Sadiq Kadhum Lafta Alzurfi, Mustafa Abd Alkadhum Rabeea, Jaafar B. Algburi, Nour Najah Ibrahimi, Mohammed Jawad Salih Al-Haidarey, Identification Lipid compounds of Aquatic plant Hydrilla verticillata (Linn. F.) Royal, Research Journal of Pharmacy and Technology, 12, 11, (2019), 5621-5626 http://dx.doi.org/10.5958/0974-360X.2019.00973.9
  42. Shubha Nigam, Krishna Gopal, Padma S. Vankar, Biosorption of arsenic in drinking water by submerged plant: Hydrilla verticilata, Environmental Science and Pollution Research, 20, 6, (2013), 4000-4008 https://doi.org/10.1007/s11356-012-1342-x
  43. Asmaa Ragab Dryaz, Mohamed Shaban, Hamad AlMohamadi, Khulood A. Abu Al-Ola, Ahmed Hamd, N. K. Soliman, Sayed A. Ahmed, Design, characterization, and adsorption properties of Padina gymnospora/zeolite nanocomposite for Congo red dye removal from wastewater, Scientific Reports, 11, 1, (2021), 21058 https://doi.org/10.1038/s41598-021-00025-y
  44. Wulan Sumarni, Dede Suhendar, Eko Prabowo Hadisantoso, Rekristalisasi natrium klorida dari larutan natrium klorida dalam beberapa minyak yang dipanaskan, al Kimiya: Jurnal Ilmu Kimia dan Terapan, 4, 2, (2017), 100-104 https://doi.org/10.15575/ak.v4i2.5090
  45. Eka Kurniasih, Produksi Biodiesel Berbahan Baku Crude Palm Oil Off Grade: Komparasi Temperatur Pengembanan Zeolite/KI, Prosiding Seminar Nasional Politeknik Negeri Lhokseumawe, 2019
  46. Yulius Dala Ngapa, Study of The Acid-Base Effect on Zeolite Activation and Its Characterization as Adsorbent of Methylene Blue Dye, JKPK (Jurnal Kimia dan Pendidikan Kimia), 2, 2, (2017), 90-96 https://doi.org/10.20961/jkpk.v2i2.11904
  47. Paryanto Paryanto, Muhammad Fadilah Arsyad, Muhammad Fardan Ibnu Aji, Penentuan nilai kesetimbangan adsorbsi zat warna alami kulit mahoni ke dalam kain dengan proses batch, Jurnal Inovasi Teknik Kimia, 3, 2, (2018), 1-7 https://doi.org/10.31942/inteka.v3i2.2482
  48. Rifki Husnul Khuluk, Ali Rahmat, Buhani Buhani, Suharso Suharso, Removal of Methylene Blue by Adsorption onto Activated Carbon From Coconut Shell (Cocous Nucifera L.), Indonesian Journal of Science and Technology, 4, 2, (2019), 229-240
  49. Buhani, Narsito, Nuryono, Eko Sri Kunarti, Suharso, Adsorption competition of Cu(II) ion in ionic pair and multi-metal solution by ionic imprinted amino-silica hybrid adsorbent, Desalination and Water Treatment, 55, 5, (2015), 1240-1252 https://doi.org/10.1080/19443994.2014.924880
  50. Shams Kalam, Sidqi A. Abu-Khamsin, Muhammad Shahzad Kamal, Shirish Patil, Surfactant Adsorption Isotherms: A Review, ACS Omega, 6, 48, (2021), 32342-32348 https://doi.org/10.1021/acsomega.1c04661
  51. Ahmad Fitriansyah, Hermansyah Amir, Elvinawati Elvinawati, Karakterisasi Adsorben Karbon Aktif dari Sabut Pinang (Areca catechu) Terhadap Kapasitas Adsorpsi Zat Warna Indigosol Blue 04-B, ALOTROP, 5, 1, (2021), 42-54 https://doi.org/10.33369/atp.v5i1.16485

Last update:

No citation recorded.

Last update: 2025-05-03 00:01:55

No citation recorded.