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Synthesis of Alginate-Chitosan Polyelectrolyte Complex (PEC) Membrane and Its Physical-Mechanical Properties

1Chemistry Department, Faculty of Mathematics and Natural Sciences, Mataram University, Indonesia

2Chemistry Department, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Indonesia

3Chemo and Biosensor Group, Faculty of Pharmacy, University of Jember, Indonesia

Received: 30 Sep 2018; Revised: 4 Jan 2019; Accepted: 7 Jan 2019; Published: 31 Jan 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under

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Synthesis of alginate-chitosan polyelectrolyte membrane and the determination of the physical-mechanical properties were carried out. Alginate-chitosan polyelectrolyte complex membrane can be made by mixing hydrosol alginate and chitosan hydrosol with a ratio of 1: 1 at pH 5.28. Membranes of alginate-chitosan polyelectrolyte complexes produced have physical-mechanical properties including load, elongation and elasticity, water absorption and resistance better than the constituent polymers. The results of FTIR spectroscopy analysis showed that there was an electrostatic interaction between alginate and chitosan through protonated amine groups of chitosan and carboxylic groups from alginate. Surface analyses by SEM showed that morphology of alginate-chitosan polyelectrolyte complex membrane was different with single membrane morphology
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Keywords: membrane; alginate–chitosan; polyelectrolyte; physical–mechanical properties
Funding: Kemenristekdikti

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  1. Mayur G. Sankalia, Rajashree C. Mashru, Jolly M. Sankalia and Vijay B. Sutariya, Reversed chitosan–alginate polyelectrolyte complex for stability improvement of alpha-amylase: Optimization and physicochemical characterization, European Journal of Pharmaceutics and Biopharmaceutics, 65, 2, (2007) 215-232
  2. J. Berger, M. Reist, J. M. Mayer, O. Felt, N. A. Peppas and R. Gurny, Structure and interactions in covalently and ionically crosslinked chitosan hydrogels for biomedical applications, European Journal of Pharmaceutics and Biopharmaceutics, 57, 1, (2004) 19-34
  3. Soichi Yabuki, Polyelectrolyte Complex Membranes for Immobilizing Biomolecules, and Their Applications to Bio-analysis, Analytical Sciences, 27, 7, (2011) 695-695
  4. Gerhard A. De Ruiter and Brian Rudolph, Carrageenan biotechnology, Trends in Food Science & Technology, 8, 12, (1997) 389-395
  5. Magdolna Bodnar, John F. Hartmann and Janos Borbely, Preparation and Characterization of Chitosan-Based Nanoparticles, Biomacromolecules, 6, 5, (2005) 2521-2527
  6. Ping Li, Ya-Ni Dai, Jun-Ping Zhang, Ai-Qin Wang and Qin Wei, Chitosan-alginate nanoparticles as a novel drug delivery system for nifedipine, International journal of biomedical science (IJBS), 4, 3, (2008) 221-228
  7. Dominika Kulig, Anna Zimoch-Korzycka, Andrzej Jarmoluk and Krzysztof Marycz, Study on Alginate–Chitosan Complex Formed with Different Polymers Ratio, Polymers, 8, 5, (2016) 167
  8. Chengling Jiang, Zhiliang Wang, Xueqin Zhang, Xiaoqun Zhu, Jun Nie and Guiping Ma, Crosslinked polyelectrolyte complex fiber membrane based on chitosan–sodium alginate by freeze-drying, RSC Advances, 4, 78, (2014) 41551-41560
  9. Anurag Verma and Ankita Verma, Polyelectrolyte complex–An overview, International Journal of Pharmaceutical Sciences and Research, 4, 5, (2013) 1684-1691
  10. Jamaran Kaban, Hakim Bangun, Asteria K. Dawolo and Daniel, Pembuatan Membran Kompleks Polielektrolit Alginat Kitosan, Jurnal Sains Kimia, 10, 1, (2006) 10-16
  11. Xia Wang, Ke-Xue Zhu and Hui-Ming Zhou, Immobilization of glucose oxidase in alginate-chitosan microcapsules, International journal of molecular sciences, 12, 5, (2011) 3042-3054
  12. Chao Song, Hao Yu, Min Zhang, Yanyan Yang and Guren Zhang, Physicochemical properties and antioxidant activity of chitosan from the blowfly Chrysomya megacephala larvae, International Journal of Biological Macromolecules, 60, (2013) 347-354
  13. Sang-Hoon Lim and Samuel M. Hudson, Synthesis and antimicrobial activity of a water-soluble chitosan derivative with a fiber-reactive group, Carbohydrate Research, 339, 2, (2004) 313-319
  14. Moacir Fernandes Queiroz, Karoline Rachel Teodosio Melo, Diego Araujo Sabry, Guilherme Lanzi Sassaki and Hugo Alexandre Oliveira Rocha, Does the use of chitosan contribute to oxalate kidney stone formation?, Marine drugs, 13, 1, (2014) 141-158
  15. Jing Han, Ziyou Zhou, Ruixue Yin, Dongzhi Yang and Jun Nie, Alginate–chitosan/hydroxyapatite polyelectrolyte complex porous scaffolds: Preparation and characterization, International Journal of Biological Macromolecules, 46, 2, (2010) 199-205
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