DOI: https://doi.org/10.14710/presipitasi.v18i2.349-357

Utilization of Spent Nickel Catalyst as Raw Material for Ni-Rich Cathode Material

Shofirul Sholikhatun Nisa  -  Universitas Sebelas Maret, Indonesia
Anisa Raditya Nurohmah  -  Universitas Sebelas Maret, Indonesia
Cornelius Satria Yudha  -  Universitas Sebelas Maret, Indonesia
Hanida Nilasary  -  PT. Pertamina, Indonesia
Hartoto Nursukatmo  -  PT. Pertamina, Indonesia
Endah Retno Dyartanti  -  Universitas Sebelas Maret, Indonesia
*Agus Purwanto  -  Universitas Sebelas Maret, Indonesia

Citation Format:
Abstract

Spent nickel catalyst will be harmful to the environment if it is not processed or used properly. In fact, this waste still has a high nickel content. The treatment of spent nickel catalysts has been widely reported, but limited to nickel extraction. Since the lithium-ion batteries demand is continued to increase, then nickel is the most sought-after metal. Consequently, nickel from spent nickel catalysts could be developed as secondary source for lithium-ion battery cathode. This study aims to utilize spent nickel catalysts into more valuable materials. Nickel that has been extracted and mixed with Mn and Co has been used as raw material for nickel-rich cathode, namely NMC. Nickel extraction and NMC synthesis were using the acid leaching method followed by co-precipitation[WI1] [SSN2] . Based on the functional test performed in this work, nickel from spent nickel catalyst can be applied to Li-ion batteries. The sintering temperature that gives good characteristics and electrochemistry was found 820oC. The galvanostatic charge-discharge test gave specific capacity results for NMC of 110.4 mAh/g. The cycle test showed that NMC synthesized from spent nickel catalyst can be carried out up to 50 cycles with a capacity retention of 87.18%.

Fulltext View|Download
Keywords: Spent nickel catalyst; NMC; lithium-ion battery
Funding: Indonesia Endowment Fund for Education (LPDP / Lembaga Pengelola Dana Pendidikan) through Pendanaan Riset Inovatif Produk (Rispro) Invitasi grant no.PRJ-6/LPDP/2020.

Article Metrics:

Article Info
Section: Original Research Article
Language : EN
Recent articles
A Brief of Water and Soil Pollution Management (Recent Trend and Economic Perspective) Utilization of Spent Nickel Catalyst as Raw Material for Ni-Rich Cathode Material Electrochemical Peroxidation Method for Reduction of Chemical Oxygen Demand (COD) Carbofuran in Furadan 3GR Pesticides Removal Efficiency of Chemical Oxygen Demand on Greywater using Multi Soil Layering (MSL) Technology Forecasting Greenhouse Gas Emissions from Heavy Vehicles: A Case study of Semarang City Water Quality Index Analysis for Water Drinking and Irrigation in the Sumowono Groundwater Basin Optimization of Waste Management at the Purwosari Material Recovery Facility (MRF) Mijen District, Semarang City More recent articles
Most cited articles
Inventarisasi dan Sebaran Emisi Aktivitas Pelabuhan dengan Aermod View Potensi Chlorella Sp. untuk Menyisihkan COD dan Nitrat dalam Limbah Cair Tahu ANALISIS KUALITAS AIR DAN STRATEGI PENGENDALIAN PENCEMARAN AIR SUNGAI BLUKAR KABUPATEN KENDAL KOMBINASI FEEDING BIOSTARTER DAN AIR DALAM ANAEROBIK DIGESTER PENENTUAN CAMPURAN LUMPUR LAPINDO SEBAGAI SUBSTITUSI PASIR DAN SEMEN DALAM PEMBUATAN PAVING BLOCK RAMAH LINGKUNGAN More cited articles
  1. Aaltonen, M., Peng, C., Wilson, B.P., Lundström, M., 2017. Leaching of metals from spent lithium-ion batteries. Recycling 2
  2. Abdel-Aal, E.A., Rashad, M.M., 2004. Kinetic study on the leaching of spent nickel oxide catalyst with sulfuric acid. Hydrometallurgy 74, 189–194
  3. Bayraktar, O., 2005. Bioleaching of nickel from equilibrium fluid catalytic cracking catalysts. World J. Microbiol. Biotechnol. 21, 661–665
  4. Dobrzański, L.A., Drygała, A., Prokopiuk vel Prokopowicz, M., 2013. Selection of components for photovoltaic system. Arch. Mater. Sci. Eng. 62, 53–59
  5. Drezen, T., Kwon, N.H., Bowen, P., Teerlinck, I., Isono, M., Exnar, I., 2007. Effect of particle size on LiMnPO4 cathodes. J. Power Sources 174, 949–953
  6. Esmaeili, J., Rahimpour, F., 2017. Regeneration of spent nickel catalyst from hydrogenation process of edible oils: Heat treatment with hydrogen injection. Int. J. Hydrogen Energy 42, 24197–24204
  7. Fornalczyk, A., Willner, J., Francuz, K., Cebulski, J., 2013. E-waste as a source of valuable metals. Arch. Mater. Sci. Eng. 63, 87–92
  8. Genchi, G., Carocci, A., Lauria, G., Sinicropi, M.S., Catalano, A., 2020. Nickel: Human health and environmental toxicology. Int. J. Environ. Res. Public Health 17
  9. Haik, O., Leifer, N., Samuk-Fromovich, Z., Zinigrad, E., Markovsky, B., Larush, L., Goffer, Y., Goobes, G., Aurbach, D., 2010. On the Surface Chemistry of LiMO[sub 2] Cathode Materials (M=[MnNi] and [MnNiCo]): Electrochemical, Spectroscopic, and Calorimetric Studies. J. Electrochem. Soc. 157, A1099
  10. Hosseini, S.A., Khalilzadeh, M.A., Jamshidi, A., 2012. Kinetic Study of Spent Nickel Catalyst Dissolution in HCl and Aqua Regia Medium. Chem. Eng. Technol. 35, 729–734
  11. Hsieh, C. Te, Hsu, H.H., Hsu, J.P., Chen, Y.F., Chang, J.K., 2016. Infrared-assisted Synthesis of Lithium Nickel Cobalt Alumina Oxide Powders as Electrode Material for Lithium-ion Batteries. Electrochim. Acta 206, 207–216
  12. Joulié, M., Laucournet, R., Billy, E., 2014. Hydrometallurgical process for the recovery of high value metals from spent lithium nickel cobalt aluminum oxide based lithium-ion batteries. J. Power Sources 247, 551–555
  13. Jung, I., Choi, J., Tak, Y., 2010. Nickel oxalate nanostructures for supercapacitors. J. Mater. Chem. 20, 6164–6169
  14. Khalid, M., Athraa, B., 2017. Experimental Study on Factors Affecting the Recovery of Nickel from Spent
  15. Catalyst. J. Powder Metall. Min. 06, 1–4
  16. Khondabi, V.G., Daneshpour, F., Fazlali, A., 2018. Recovery of precious metals from spent catalysts (solid waste) using electrometallurgy method: A review. 5th Int. Conf. Recent Innov. Chem. Chem. Eng. 1–9
  17. Kong, J.Z., Zhai, H.F., Ren, C., Gao, M.Y., Zhang, X., Li, H., Li, J.X., Tang, Z., Zhou, F., 2013. Synthesis and electrochemical performance of macroporous LiNi 0.5Co0.2Mn0.3O2 by a modified sol-gel method. J. Alloys Compd. 577, 507–510
  18. Langdon, J., Manthiram, A., 2021. A perspective on single-crystal layered oxide cathodes for lithium-ion batteries. Energy Storage Mater. 37, 143–160
  19. Le, N., Thuy, P., Luong, N., Tran, T. Van, Thi, Y., Pham, H., 2017. Recycling nickel from spent catalyst of Phu My fertilizer plant as a precursor for exhaust gas treatment catalysts preparation. J. Mater. Cycles Waste Manag. 0, 0
  20. Liu, X., Li, K., Li, X., 2018. The Electrochemical Performance and Applications of Several Popular Lithium-ion Batteries for Electric Vehicles - A Review. Springer Singapore
  21. Muzayanha, S.U., Yudha, C.S., Nur, A., Widiyandari, H., Haerudin, H., Nilasary, H., Fathoni, F., Purwanto, A., 2019. A fast metals recovery method for the synthesis of lithium nickel cobalt aluminum oxide material from cathode waste. Metals (Basel). 9
  22. Nandiyanto, A.B.D., Oktiani, R., Ragadhita, R., 2019. How to read and interpret ftir spectroscope of organic material. Indones. J. Sci. Technol. 4, 97–118
  23. Nisa, S.S., Nurohmah, A.R., Yudha, C.S., Rahmawati, M., Paramitha, T., Widiyandari, H., Dyartanti, E.R., Purwanto, A., 2021. Preliminary Investigation of NiO Anode for NCA / NiO Battery from Spent Catalyst Recovery. IOP Conf. Ser. Mater. Sci. Eng. 1096
  24. Parhi, P.K., Park, K.H., Senanayake, G., 2013. A kinetic study on hydrochloric acid leaching of nickel from Ni-Al2O3 spent catalyst. J. Ind. Eng. Chem. 19, 589–594
  25. Qiu, Z., Zhang, Y., Dong, P., Xia, S., Yao, Y., 2017. A facile method for synthesis of LiNi0.8Co0.15Al0.05O2 cathode material. Solid State Ionics 307, 73–78
  26. Ramos-Cano, J., González-Zamarripa, G., Carrillo-Pedroza, F.R., Soria-Aguilar, M.D.J., Hurtado-Macías, A., Cano-Vielma, A., 2016. Kinetics and statistical analysis of nickel leaching from spent catalyst in nitric acid solution. Int. J. Miner. Process. 148, 41–47
  27. Ronduda, H., Zybert, M., Szczęsna-Chrzan, A., Trzeciak, T., Ostrowski, A., Szymański, D., Wieczorek, W., Raróg-Pilecka, W., Marcinek, M., 2020. On the sensitivity of the ni-rich layered cathode materials for li-ion batteries to the different calcination conditions. Nanomaterials 10, 1–21
  28. Sahu, K.K., Agarwal, A., Pandey, B.D., 2005. Nickel recovery from spent nickel catalyst. Waste Manag. Res. 23, 148–154
  29. Seo, J.S., Lee, J. won, 2017. Fast growth of the precursor particles of Li(Ni0.8Co0.16Al0.04)O2via a carbonate co-precipitation route and its electrochemical performance. J. Alloys Compd. 694, 703–709
  30. Sharma, M., Bisht, V., Singh, B., Jain, P., Mandal, A.K., 2015. Bioleaching of nickel from spent petroleum catalyst using Acidithiobacillus thiooxidans DSM-11478 53, 388–394
  31. Sinha, N.N., Munichandraiah, N., 2009. The effect of particle size on performance of cathode materials of Li-ion batteries. J. Indian Inst. Sci. 89, 381–392
  32. Xu, L., Zhou, F., Kong, J., Zhou, H., Zhang, Q., Wang, Q., Yan, G., 2018. Influence of precursor phase on the structure and electrochemical properties of Li(Ni0.6Mn0.2Co0.2)O2 cathode materials. Solid State Ionics 324, 49–58
  33. Yudha, C.S., Muzayanha, S.U., Hendri, W., Iskandar, F., Sutopo, W., Purwanto, A., Widiyandari, H., Iskandar, F., Sutopo, W., Purwanto, A., 2019. Synthesis of LiNi0.85Co0.14Al0.01O2 Cathode Material and its Performance in an NCA / Graphite Full-Battery. Energies 12, 1886
  34. Zhang, H., Yang, S., Huang, Y., Xianhua, H., 2020. Synthesis of non-spherical LiNi0.88Co0.09Al0.03O2 Cathode Material for Lithium-ion Batteries. Energy & Fuels 34, 9002–9010

Last update:

  1. Effect of scandium doping on the structural properties and electrochemical performance of nickel-rich cathode precursor of lithium ion-battery

    Vita Ambarwati, Mohammad Zaki Mubarok, Agus Purwanto. Materials Chemistry and Physics, 313 , 2024. doi: 10.1016/j.matchemphys.2023.128726

  2. Synthesis of Fe/Mg-doped NMC6 22 from Spent Nickel Catalyst as Lithium-Ion Battery Cathode

    Endah Retno Dyartanti, Agnestasia Milenia Putri Kurniawan, Arifiah Muflikhati Putri, U.S.F. Arrozi. E3S Web of Conferences, 481 , 2024. doi: 10.1051/e3sconf/202448101006

Last update: 2024-11-18 02:06:23

No citation recorded.