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Synthesis and Characterization of Physically Mixed V2O5.CaO as Bifunctional Catalyst for Methyl Ester Production from Waste Cooking Oil

1Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Semarang, Central Java, 50275, Indonesia

2Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Walisongo, Semarang, Central Java, 50185, Indonesia

Received: 20 Dec 2022; Revised: 28 Jan 2023; Accepted: 5 Feb 2023; Available online: 14 Feb 2023; Published: 15 Mar 2023.
Editor(s): H Hadiyanto
Open Access Copyright (c) 2023 The Author(s). Published by Centre of Biomass and Renewable Energy (CBIORE)
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Citation Format:
Synthesis of the solid bifunctional vanadium-calcium mixed oxides catalyst was accomplished by application of a simple physical mixing approach. In this work, we compared the catalytic activity of CaO and 2%V2O5.CaO catalyst. Various characterization methods, such as X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transform infrared (FTIR), BET surface area, and temperature-programmed desorption (TPD) of CO2 and NH3, were involved in studying the newly synthesized catalysts. The presence of CaO, CaCO3, and Ca(OH)2 compounds in the synthesized catalyst were detected by XRD and FTIR analysis. The existence of 2% V2O5 on the CaO catalyst surface was demonstrated by XRF analysis. From TPD-NH3, TPD-CO2, and BET surface area analysis, it was known that the 2% V2O5-CaO catalyst had a higher total number of acid-base sites and surface area than the CaO catalyst. In the fatty acid methyl esters (FAME) production from waste cooking oil (WCO) with higher free fatty acid (FFA), CaO could only catalyze the transesterification reaction. In contrast, 2%V2O5-CaO could successfully catalyze both the esterification of FFA and the transesterification of triglyceride (TG) simultaneously in a one-step reaction process. Thus, these results prove that 2%V2O5.CaO can act as a bifunctional catalyst in the production of biodiesel from WCO. Moreover, the synthesized 2%V2O5.CaO catalyst could achieve a maximum FAME yield of 51.30% under mild reaction conditions, including a 20:1 methanol to oil molar ratio, 60 °C reaction temperature, 1 wt% of catalyst loading, and 3 hours of reaction time.
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Keywords: physically mixed; bifunctional catalyst; waste cooking oil; simultaneous esterification-transesterification; methyl ester

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  1. Abukhadra, M. R., Ibrahim, S. M., Yakout, S. M., El-Zaidy, M. E., & Abdeltawab, A. A. (2019). Synthesis of Na+ trapped bentonite/zeolite-P composite as a novel catalyst for effective production of biodiesel from palm oil; Effect of ultrasonic irradiation and mechanism. Energy Conversion and Management, 196 (May), 739–750.
  2. Ali, R. M., Elkatory, M. R., & Hamad, H. A. (2020). Highly active and stable magnetically recyclable CuFe2O4 as a heterogenous catalyst for efficient conversion of waste frying oil to biodiesel. Fuel, 268 (February), 117297.
  3. Almeida, T. A., Rodrigues, I. A., Estrela, T. S., Nunes, C. N. F., Machado, L. L., Leão, K. V., Barros, I. C. L., Amorim, F. A. C., & Braga, V. S. (2016). Synthesis of ethyl biodiesel from soybean oil, frying oil and chicken fat, using catalysts based on vanadium pentoxide. Energy, 97, 528–533.
  4. Asikin-mijan, N., Lee, H. V, & Taufiq-yap, Y. H. (2015). Chemical Engineering Research and Design Synthesis and catalytic activity of hydration – dehydration treated clamshell derived CaO for biodiesel production. Chemical Engineering Research and Design, 102, 368–377.
  5. Borah, M. J., Das, A., Das, V., Bhuyan, N., & Deka, D. (2019). Transesterification of waste cooking oil for biodiesel production catalyzed by Zn substituted waste egg shell derived CaO nanocatalyst. Fuel, 242 (May 2018), 345–354.
  6. Borgna, A. (2015). Bifunctional Mo3VOx/H4SiW12O40/Al2O3 Catalysts for One-step Conversion of Glycerol to Acrylic Acid : Catalyst Structural Evolution and Reaction Pathways. Elsevier B.V.
  7. Boro, J., Konwar, L. J., & Deka, D. (2014). Transesterification of non edible feedstock with lithium incorporated egg shell derived CaO for biodiesel production. Fuel Processing Technology, 122, 72–78.
  8. Buasri, A., Ksapabutr, B., Panapoy, M., & Chaiyut, N. (2012). Process Optimization for Ethyl Ester Production in Fixed Bed Reactor Using Calcium Oxide Impregnated Palm Shell Activated Carbon (CaO/PSAC). International Journal of Renewable Energy Development, 1(3), 81-86;
  9. Chary, K. V. R., Reddy, K. R., Kumar, C. P., Naresh, D., Rao, V. V., & Mestl, G. (2004). Characterization and reactivity of molybdenum oxide catalysts supported on Nb2O5-TiO2. Journal of Molecular Catalysis A: Chemical, 223(1–2), 363–369.
  10. Chen, G. Y., Shan, R., Yan, B. B., Shi, J. F., Li, S. Y., & Liu, C. Y. (2016). Remarkably enhancing the biodiesel yield from palm oil upon abalone shell-derived CaO catalysts treated by ethanol. Fuel Processing Technology, 143, 110–117.
  11. Das, H. P., Neeharika, T. S. V. R., Sailu, C., Srikanth, V., Kumar, T. P., & Rani, K. N. P. (2017). Kinetics of amidation of free fatty acids in jatropha oil as a prerequisite for biodiesel production. Fuel, 196, 169–177.
  12. Ezzah-Mahmudah, S., Lokman, I. M., Saiman, M. I., & Taufiq-Yap, Y. H. (2016). Synthesis and characterization of Fe2O3/CaO derived from Anadara Granosa for methyl ester production. Energy Conversion and Management, 126, 124–131.
  13. Faruque, M. O., Razzak, S. A., & Hossain, M. M. (2020). Application of heterogeneous catalysts for biodiesel production from microalgal oil—a review. Catalysts, 10 (9), 1–25.
  14. Hadiyanto, H., Lestari, S. P., & Widayat, W. (2016). Preparation and Characterization of Anadara Granosa Shells and CaCO3 as Heterogeneous Catalyst for Biodiesel Production. Bulletin of Chemical Reaction Engineering & Catalysis, 11(1), 21-26.
  15. Istadi, I., Prasetyo, S. A., & Nugroho, T. S. (2015). Characterization of K2O/CaO-ZnO Catalyst for Transesterification of Soybean Oil to Biodiesel. Procedia Environmental Sciences, 23(Ictcred 2014), 394–399.
  16. Jeon, Y., Chi, W. S., Hwang, J., Kim, D. H., Kim, J. H., & Shul, Y. G. (2019). Core-shell nanostructured heteropoly acid-functionalized metal-organic frameworks: Bifunctional heterogeneous catalyst for efficient biodiesel production. Applied Catalysis B: Environmental, 242, 51–59.
  17. Kaur, N., & Ali, A. (2014). Kinetics and reusability of Zr/CaO as heterogeneous catalyst for the ethanolysis and methanolysis of Jatropha crucas oil. Fuel Processing Technology, 119, 173–184.
  18. Kesserwan, F., Ahmad, M. N., Khalil, M., & El-Rassy, H. (2020). Hybrid CaO/Al2O3 aerogel as heterogeneous catalyst for biodiesel production. Chemical Engineering Journal, 385, 123834.
  19. Krishnamurthy, K. N., Sridhara, S. N., & Ananda Kumar, C. S. (2020). Optimization and kinetic study of biodiesel production from Hydnocarpus wightiana oil and dairy waste scum using snail shell CaO nano catalyst. Renewable Energy, 146, 280–296.
  20. Kung, H. H. (1989). Transition Metal Oxides - Surface Chemistry and Catalysis. In Studies in Surface Science and Catalysis (Vol. 45). Elsevier B.V.
  21. Lee, H.V., Juan, J.C. & Taufiq-Ya, Y. H. (2015). Preparation and application of binary acid-base CaO-La2O3 catalyst for biodiesel production. Renewable Energy, 74, 124–132.
  22. Li, J., Xu, H., Fei, Z. A., Liu, H., Qiao, D. R., & Cao, Y. (2012). CaO/NaA combined with enzymatic catalyst for biodiesel transesterification. Catalysis Communications, 28, 52–57.
  23. Li, X., Liu, S., Na, Z., Lu, D., & Liu, Z. (2013). Adsorption, concentration, and recovery of aqueous heavy metal ions with the root powder of Eichhornia crassipes. Ecological Engineering, 60, 160–166.
  24. Maneerung, T., Kawi, S., Dai, Y., & Wang, C. H. (2016). Sustainable biodiesel production via transesterification of waste cooking oil by using CaO catalysts prepared from chicken manure. Energy Conversion and Management, 123, 487–497.
  25. Mansir, N., Hwa Teo, S., Lokman Ibrahim, M., & Yun Hin, T. Y. (2017). Synthesis and application of waste egg shell derived CaO supported W-Mo mixed oxide catalysts for FAME production from waste cooking oil: Effect of stoichiometry. Energy Conversion and Management, 151, 216–226.
  26. Mulyatun, M., & Prasetyoko, D. (2011). Vanadium Contribution to the Surface Modification of Titanium Silicalite for Conversion of Benzene to Phenol. IPTEK The Journal for Technology and Science, 22(2).
  27. Ngaosuwan, K., Chaiyariyakul, W., Inthong, O., Kiatkittipong, W., Wongsawaeng, D., & Assabumrungrat, S. (2021). La2O3/CaO catalyst derived from eggshells: Effects of preparation method and La content on textural properties and catalytic activity for transesterification. Catalysis Communications, 149, 106247.
  28. Piker, A., Tabah, B., Perkas, N., & Gedanken, A. (2016). A green and low-cost room temperature biodiesel production method from waste oil using egg shells as catalyst. Fuel, 182, 34–41.
  29. Rabiah Nizah, M. F., Taufiq-Yap, Y. H., Rashid, U., Teo, S. H., Shajaratun Nur, Z. A., & Islam, A. (2014). Production of biodiesel from non-edible Jatropha curcas oil via transesterification using Bi2O3-La2O3 catalyst. Energy Conversion and Management, 88, 1257–1262.
  30. Rahman, N. J. A., Ramli, A., Jumbri, K., & Uemura, Y. (2019). Tailoring the surface area and the acid–base properties of ZrO2 for biodiesel production from Nannochloropsis sp. Scientific Reports, 9(1), 1–12.
  31. Rezania, S., Oryani, B., Park, J., Hashemi, B., Yadav, K. K., Kwon, E. E., Hur, J., & Cho, J. (2019). Review on transesterification of non-edible sources for biodiesel production with a focus on economic aspects, fuel properties and by-product applications. Energy Conversion and Management, 201(July), 112155.
  32. Roy, T., Sahani, S., & Chandra Sharma, Y. (2020). Study on kinetics-thermodynamics and environmental parameter of biodiesel production from waste cooking oil and castor oil using potassium modified ceria oxide catalyst. Journal of Cleaner Production, 247, 119166.
  33. Shatesh Kumar, Shamsuddin, M. R., Farabi, M. S. A., Saiman, M. I., Zainal, Z., & Taufiq-Yap, Y. H. (2020). Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst. Energy Conversion and Management, 226 (May), 113366.
  34. Shobhana-Gnanaserkhar, Asikin-Mijan, N., AbdulKareem-Alsultan, G., Sivasangar-Seenivasagam, Izham, S. M., & Taufiq-Yap, Y. H. (2020). Biodiesel production via simultaneous esterification and transesterification of chicken fat oil by mesoporous sulfated Ce supported activated carbon. Biomass and Bioenergy, 141, 105714.
  35. Soltani, S., Rashid, U., Al-Resayes, S. I., & Nehdi, I. A. (2017). Recent progress in synthesis and surface functionalization of mesoporous acidic heterogeneous catalysts for esterification of free fatty acid feedstocks: A review. Energy Conversion and Management, 141, 183–205.
  36. Sun, Q., Fang, D., Wang, S., Shen, J., & Auroux, A. (2007). Structural, acidic and redox properties of V2O5/NbP catalysts. Applied Catalysis A: General, 327(2), 218–225.
  37. Syamsuddin, Y., & Hameed, B. H. (2016). Synthesis of glycerol free-fatty acid methyl esters from Jatropha oil over Ca-La mixed-oxide catalyst. Journal of the Taiwan Institute of Chemical Engineers, 58, 181–188.
  38. Wan Omar, W. N. N., & Amin, N. A. S. (2011). Biodiesel production from waste cooking oil over alkaline modified zirconia catalyst. Fuel Processing Technology, 92 (12), 2397–2405.
  39. Wang, A., Li, H., Zhang, H., Pan, H., & Yang, S. (2018). Efficient catalytic production of biodiesel with acid-base bifunctional rod-like Ca-B oxides by the sol-gel approach. Materials, 12(1).
  40. Wen, Z., Yu, X., Tu, S. T., Yan, J., & Dahlquist, E. (2010). Biodiesel production from waste cooking oil catalyzed by TiO2-MgO mixed oxides. Bioresource Technology, 101(24), 9570–9576.
  41. Widayat, W., Hadiyanto, H., Wardani, P. W. A., Zuhra, U. A., & Prameswari, J. (2020). Preparation of KI/hydroxyapatite catalyst from phosphate rocks and its application for improvement of biodiesel production. Molecules, 25(11).
  42. Widiarti, N., Bahruji, H., Holilah, H., Ni’mah, Y. L., Ediati, R., Santoso, E., Jalil, A. A., Hamid, A., & Prasetyoko, D. (2021). Upgrading catalytic activity of NiO/CaO/MgO from natural limestone as catalysts for transesterification of coconut oil to biodiesel. Biomass Conversion and Biorefinery.
  43. Xie, W., & Zhao, L. (2013). Production of biodiesel by transesterification of soybean oil using calcium supported tin oxides as heterogeneous catalysts. Energy Conversion and Management, 76, 55–62.
  44. Yadav, G. D., & Nair, J. J. (1999). Sulfated zirconia and its modified versions as promising catalysts for industrial processes. Microporous and Mesoporous Materials, 33(1–3), 1–48.
  45. Zhao, X., Yan, Y., Mao, L., Fu, M., Zhao, H., Sun, L., Xiao, Y., & Dong, G. (2018). A relationship between the V4+/V5+ ratio and the surface dispersion, surface acidity, and redox performance of V2O5-WO3/TiO2 SCR catalysts. RSC Advances, 8(54), 31081–31093.
  46. Zul, N. A., Ganesan, S., Hamidon, T. S., Oh, W. Da, & Hussin, M. H. (2021). A review on the utilization of calcium oxide as a base catalyst in biodiesel production. Journal of Environmental Chemical Engineering, 9(4), 105741.

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