skip to main content

Multi-Feedstocks Biodiesel Production from Esterification of Calophyllum inophyllum Oil, Castor Oil, Palm Oil and Waste Cooking Oil

1Department of Chemical Engineering, Diponegoro University, Jl Prof. Soedharto, SH, Tembalang, Semarang 50275, Indonesia

2School of Postgraduate Studies, Diponegoro University, Jl Imam Bardjo, SH, Semarang 50275, Indonesia

3Center of Biomass and RenewableEnergy (C-BIORE), Diponegoro University, Jl Prof. Soedharto, SH, Tembalang, Semarang 50275, Indonesia

4 Faculty of Engineering, Dian Nuswantoro University, Semarang, Indonesia

5 Department of Chemical Engineering, Gadjah MadaUniversity, Yogyakarta, Indonesia

6 Department of Chemical Engineering, Sepuluh November Institute of Technology, Surabaya, Indonesia

View all affiliations
Received: 19 Oct 2019; Revised: 22 Dec 2019; Accepted: 21 Jan 2020; Available online: 15 Feb 2020; Published: 18 Feb 2020.
Editor(s): Anh Tuan Hoang
Open Access Copyright (c) 2020 The Authors. Published by Centre of Biomass and Renewable Energy (CBIORE)
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Citation Format:
Abstract
Biodiesel can be produced from various vegetable oils and animal fat. Abundant sources of vegetable oil in Indonesia, such as Calophyllum inophyllum, Ricinus communis, palm oil, and waste cooking oil, were used as raw materials. Multi-feedstock biodiesel was used to increase the flexibility operation of biodiesel production. This study was conducted to determine the effect of a combination of vegetable oils on biodiesel characteristics. Degumming and two steps of esterification were applied for high free fatty acid feedstock before trans-esterification in combination with other vegetable oils. Potassium hydroxide was used as a homogenous catalyst and methanol as another raw material. The acid value of C. inophyllum decreased from 54 mg KOH/gr oil to 2.15 mg KOH/gr oil after two steps of esterification. Biodiesel yield from multi-feedstock was 87.926% with a methanol-to-oil molar ratio of 6:1, temperature of 60 ℃, and catalyst of 1%wt. ©2020. CBIORE-IJRED. All rights reserved
Fulltext View|Download
Keywords: Multi-feedstock biodiesel; trans-esterification; calophyllum inophyllum; palm oil; waste cooking oil

Article Metrics:

  1. Andyna, J.Y., Nurin. (2009). Pembuatan Biodiesel dari Minyak Biji Nyamplung (Calophyllum inophylum L). Bandung: FMIPA Institut Teknologi Bandung
  2. Angelovic, M., Zdenko Tkac & Juraj Jablonicky. 2014. Determination Model for Cetane Number of Biodiesel at Different Fatty Acid Composition: A Review. Scientific Papers : Animal Science and Biotechnologies. 47 (1)
  3. Ali, E.N.; Tay, C.I. (2013). Characterization of biodiesel produced from palm oil via base catalyzed transesterification. Procedia Eng. 53, 7–12
  4. Aranda, D. A. G., Santos, R.T.P. Tapanes, N.C.O., Ramos, A.L.D., Antunes, O.A.C. 2008. Acid-Catalyzed Homogeneous Esterification Reaction for Biodiesel Production from Palm Fatty Acids. Catalysis Letters. 122:20-25
  5. Aworanti, O.A., Agarry, S.E., Ajani, A.O. 2012. A laboratory Study of the Effect of Temperature on Densities and Viscosities of Binary and Ternary Blends of Soybean Oil, Soybean Biodiesel and Petroleum Diesel Oil. Advances in Chemical Engineering and Science, 2, 444-452
  6. Bladt, D., Murray, S., Gitch, B., Trout, H., and Liberko, C., 2010. Acid-Catalyzed Preparation of Biodiesel from Waste Vegetable Oil: An Experiment for the Undergraduate Organic Chemistry Laboratory. Journal of Chemical Education. 88, 2
  7. Doll, K.M., Sharma, B.K., Suarez, P.A.Z., Erhan, S.Z. 2008. Comparing Biofuels Obtained from pyrolysis of soybean oil or soapstock, with traditional soybean biodiesel: density, kinematic viscosity, and surface tensions. Energy & Fuels, 22, 2061-2066
  8. El-Araby, R., Amin, A., El Morsi, A.K., El-Ibiari, N.N., El-Diwani, G.I. Study on the characteristics of palm oil-biodiesel-diesel fuel blend. Egyptian Journal of Petroleum. Vol 27, 2. 2018
  9. Ganjehkaviri, A., Jaafar, M.N.M., Hosseini, S. E., and Musthaa, A. B. 2016. Performance Evaluation of Palm Oil-Based Biodiesel Combustion in an Oil Burner. Energies, 9, 97
  10. Gokdogan, O., Eryilmaz, T., and Yesilyurt, M.K, Thermophysical Properties of Castor Oil (Ricinus Communis L.) Biodiesel and Its Blends, Journal of Oil, Gas, and Alternative Energy Sources 6, 1, 2015
  11. Hadiyanto, H., Inaya Yuliandaru, I., Hapsari, R.(2018). Production of Biodiesel from Mixed Waste Cooking and Castor Oil. MATEC Web of Conferences 156, 03056
  12. Jahirul, M.I., Brown, M.J., W. Senadeera, W., Ashwat, N., Rasul, M.G., Rahman, M.M., Hossain, F.M., Moghaddam, L., Islam, M.A., O’Hara, I.M. Physio-chemical assessment of beauty leaf (Calophyllum inophyllum) as second-generation biodiesel feedstock.. Energy Report, 1,204-215
  13. Thaiyasuit, P., Pianthong, K., and Worapun, I. 2012. Acid Esterification-Alkaline Transesterification Process for Methyl Ester Production from Crude Rubber Seed Oil. Journal of Oleo Sci. 61 (2) 81-88 (2012)
  14. Tong, D., Hu, C., Jiang K., Li, Y. 2011. Cetane Number Prediction of Biodiesel from the Composition of Fatty Acid Methyl Ester. J. Am Oil Chem Soc. 88: 415-423
  15. Valente, O.S., Pasa, V.M.D., Belchior, C.R.P., Sodre, J.R. 2011. Physical–chemical properties of waste cooking oil biodiesel and castor oil biodiesel blends. Fuel. 90
  16. Wang, T. (2018). Global biodiesel production by country 2017, Statisca, 2018

Last update:

  1. Preparation of MgO-CaO/SiO2 catalyst from dolomite and geothermal solid waste for biodiesel production

    Widayat Widayat, Nadia Taradissa Maheswari, Wahyu Fitriani, Luqman Buchori, Hantoro Satriadi, K Kusmiyati, Norzita Ngadi. International Journal of Renewable Energy Development, 12 (3), 2023. doi: 10.14710/ijred.2023.51573
  2. Life cycle assessment for evaluating the energy balance of the multi-feedstock biodiesel production process in Indonesia

    Yoyon Wahyono, H. Hadiyanto, Shabbir H. Gheewala, Mochamad Arief Budihardjo, Joni Adiansyah, Widayat Widayat, Marcelinus Christwardana. International Journal of Ambient Energy, 44 (1), 2023. doi: 10.1080/01430750.2023.2171485
  3. Understanding Fuel Saving and Clean Fuel Strategies Towards Green Maritime

    Van Nhanh Nguyen, Krzysztof Rudzki, Marek Dzida, Nguyen Dang Khoa Pham, Minh Tuan Pham, Phuoc Quy Phong Nguyen, Phuong Nguyen Xuan. Polish Maritime Research, 30 (2), 2023. doi: 10.2478/pomr-2023-0030
  4. Emissions Characteristics and Engine Performance from the Interaction Effect of EGR and Diesel-Ethanol Blends in Diesel Engine

    Mohammed Ali Fayad, Moafaq Kaseim Al-Ghezi, Sanaa A Hafad, Slafa I Ibrahim, Marwa K Abood, Hind A Al-Salihi, Louay A Mahdi, Miqdam Tariq Chaichan, Hayder Abed Dhahad. International Journal of Renewable Energy Development, 11 (4), 2022. doi: 10.14710/ijred.2022.45051
  5. Metal-organic frameworks as potential catalysts for biodiesel production and biomass conversion: Mechanism and characteristics

    Thanh Tuan Le, Prabhakar Sharma, Huu Son Le, Huu Cuong Le, Duc Trong Nguyen Le, Dao Nam Cao, Thanh Hai Truong, Viet Dung Tran. Industrial Crops and Products, 211 , 2024. doi: 10.1016/j.indcrop.2024.118232
  6. Effect of Compression Ratio on Performance and Emission Characteristics of Dual Spark Plug Ignition Engine Fueled With n-Butanol as Additive Fuel

    Ravikumar Ramegouda, Antony Alappath Joseph. International Journal of Renewable Energy Development, 10 (1), 2021. doi: 10.14710/ijred.2021.32364
  7. Biodiesel production process without glycerol by-product with base catalyst: effect of reaction time and type of catalyst on kinetic energy and solubility

    E D Daryono, I N G Wardana, C Cahyani, N Hamidi. IOP Conference Series: Materials Science and Engineering, 1053 (1), 2021. doi: 10.1088/1757-899X/1053/1/012058
  8. Evaluating the environmental impacts of the multi-feedstock biodiesel production process in Indonesia using life cycle assessment (LCA)

    Yoyon Wahyono, Hadiyanto Hadiyanto, Shabbir H. Gheewala, Mochamad Arief Budihardjo, Joni Safaat Adiansyah. Energy Conversion and Management, 266 , 2022. doi: 10.1016/j.enconman.2022.115832
  9. Biodiesel production from crude palm oil (CPO) through variation steps of esterification-transesterification and its evaluations

    Juwono Hendro, Harmaini Safana Zahra. THE FOURTH AL-NOOR INTERNATIONAL CONFERENCE FOR SCIENCE AND TECHNOLOGY (4NICST2022), 3079 , 2024. doi: 10.1063/5.0206695
  10. Effect of alcohol additives on diesel engine performance: a review

    Tan Trung Truong, Xuan Phuong Nguyen, Van Viet Pham, Van Vang Le, Anh Tuan Le, Van Tam Bui. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2021. doi: 10.1080/15567036.2021.2011490
  11. Evaluating the Environmental Impacts at the End Point Level of the Biodiesel Production Process from Multiple Feedstocks in Indonesia Through Life Cycle Assessment Methodology

    Yoyon Wahyono, Hadiyanto Hadiyanto, Shabbir H. Gheewala, Mochamad Arief Budihardjo, Joni Safaat Adiansyah, Widayat Widayat, Marcelinus Christwardana. Waste and Biomass Valorization, 14 (9), 2023. doi: 10.1007/s12649-023-02040-8
  12. A Review on the Recent Breakthrough Methods and Influential Parameters in the Biodiesel Synthesis and Purification

    S. Silviana, Didi Dwi Anggoro, H. Hadiyanto, Cantika Aulia Salsabila, Kevin Aprilio, Anisa Widia Utami, Afriza Ni'matus Sa'adah, Febio Dalanta. International Journal of Renewable Energy Development, 11 (4), 2022. doi: 10.14710/ijred.2022.43147
  13. Production of biodiesel (isopropyl ester) from coconut oil by microwave assisted transesterification: parametric study and optimization

    Rheinanda Rachmaditasari, Muhamad Irfaid Darojat, Mahfud Mahfud. International Journal of Renewable Energy Development, 13 (4), 2024. doi: 10.61435/ijred.2024.60174
  14. Experimental analysis of performance and emission of a turbocharged diesel engine operated in dual-fuel mode fueled with bamboo leaf-generated gaseous and waste palm oil biodiesel/diesel fuel blends

    Biswajeet Nayak, Thingujam Jackson Singh, Anh Tuan Hoang. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2021. doi: 10.1080/15567036.2021.2009595
  15. Nanotechnology-based biodiesel: A comprehensive review on production, and utilization in diesel engine as a substitute of diesel fuel

    Thanh Tuan Le, Minh Ho Tran, Quang Chien Nguyen, Huu Cuong Le, Van Quy Nguyen, Dao Nam Cao, Prabhu Paramasivam. International Journal of Renewable Energy Development, 13 (3), 2024. doi: 10.61435/ijred.2024.60126
  16. Influence of injection timing on performance and combustion characteristics of compression ignition engine working on quaternary blends of diesel fuel, mixed biodiesel, and t-butyl peroxide

    Swarup Kumar Nayak, Sandro Nižetić, Van Viet Pham, Zuohua Huang, Aykut I. Ölçer, Van Ga Bui, Kanit Wattanavichien, Anh Tuan Hoang. Journal of Cleaner Production, 333 , 2022. doi: 10.1016/j.jclepro.2021.130160
  17. The Production of Biodiesel and Related Fuel Additives

    Shilpa Pande, Shekhar Gahane. 2024. doi: 10.2174/9789815196740124060012
  18. Catalyst-Based Synthesis of 2,5-Dimethylfuran from Carbohydrates as a Sustainable Biofuel Production Route

    Anh Tuan Hoang, Ashok Pandey, Zuohua Huang, Rafael Luque, Kim Hoong Ng, Agis M. Papadopoulos, Wei-Hsin Chen, Sakthivel Rajamohan, H. Hadiyanto, Xuan Phuong Nguyen, Van Viet Pham. ACS Sustainable Chemistry & Engineering, 10 (10), 2022. doi: 10.1021/acssuschemeng.1c06363
  19. Inedible oil feedstocks for biodiesel production: A review of production technologies and physicochemical properties

    Yuvarajan Devarajan, Dinesh Babu Munuswamy, Ganesan Subbiah, Suresh Vellaiyan, Beemkumar Nagappan, Edwin Geo Varuvel, Jeyaseelan Thangaraja. Sustainable Chemistry and Pharmacy, 30 , 2022. doi: 10.1016/j.scp.2022.100840
  20. Advances in limitations and opportunities of clean biofuel production to promote decarbonization

    Ali Sarosh Khawaja, Muhammad Ayman Zaheer, Ali Ahmad, Asif Ali Mirani, Zulfiqar Ali. Fuel, 342 , 2023. doi: 10.1016/j.fuel.2023.127662

Last update: 2024-11-21 07:21:50

  1. Effect of Compression Ratio on Performance and Emission Characteristics of Dual Spark Plug Ignition Engine Fueled With n-Butanol as Additive Fuel

    Ravikumar Ramegouda, Antony Alappath Joseph. International Journal of Renewable Energy Development, 10 (1), 2021. doi: 10.14710/ijred.2021.32364