Pirolisis Kulit Biji Jambu Mete (Cashew Nut Shell) dengan Katalis Ag/Zeolit

Rimby Puji Astuti  -  Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
*Linda Suyati scopus  -  Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
Rahmad Nuryanto scopus  -  Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
Published: 1 Dec 2012.
Open Access Copyright 2012 Jurnal Kimia Sains dan Aplikasi
License URL: http://creativecommons.org/licenses/by-sa/4.0

Citation Format:
Abstract
Tanaman jambu mete, Anacardium occidentale L. merupakan salah satu komoditi perkebunan yang memiliki nilai ekonomi cukup tinggi. Kulit biji jambu mete mengandung 50% minyak yang terdiri dari senyawa fenolat berupa 90% asam anakardat dan 10% berupa kardol dan kardanol. Penelitian ini bertujuan untuk mensintesis dan mengkarakterisasi katalis Ag/zeolit, melakukan pirolisis kulit jambu mete, mengetahui pengaruh temperatur pirolisis terhadap produk cair pirolisis dan membandingkan produk cair hasil pirolisis yang menggunakan katalis zeolit dan Ag/zeolit. Penelitian dilakukan beberapa tahap yaitu pembuatan katalis Ag/Zeolit dan pirolisis kulit biji jambu mete. Pirolisis dilakukan dengan katalis Ag/zeolit pada temperatur 200, 250, 300, 350, dan 400°C. Karakterisasi katalis menggunakan Surface Area Analyzer, AAS, uji keasaman dan GC-MS untuk produk cair pirolisis. Hasil penelitian diperoleh katalis Ag/zeolit yang mengalami penurunan luas permukaan spesifik sebesar 70,28%, volume total pori sebesar 70,19%. Nilai keasaman katalis Ag/zeolit mengalami kenaikan sebesar 50%, mengandung logam Ag sebesar 0,6326%. Hasil analisis GC-MS produk cair pirolisis pada temperatur 400°C dengan katalis Ag/zeolit diperoleh senyawa 3-octylphenol dengan kelimpahan sebesar 72,28%, dengan katalis zeolit alam teraktivasi dihasilkan senyawa 3-(pentadec-8-enyl)phenol dengan kelimpahan sebesar 77,04%.
Keywords: pirolisis; kulit biji jambu mete; Ag/Zeolit

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Section: Research Articles
Language: ID
In Vol 15, No 3 (2012): Volume 15 Issue 3 Year 2012
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  1. Alberto J. Tsamba, Weihong Yang, Wlodzimierz Blasiak, Pyrolysis characteristics and global kinetics of coconut and cashew nut shells, Fuel Processing Technology, 87, 6, (2006) 523-530 http://dx.doi.org/10.1016/j.fuproc.2005.12.002
  2. IN Simpen, Isolasi Cashew Nut Shell Liqiud dari kulit biji mete (Anacardium occidentale L) dan kajian beberapa sifat fisiko kimianya, Jurusan Kimia, Universitas Udayana, Jimbaran, Bali
  3. DN Mallikappa, RanaPratap Reddy, Ch SN Murthy, Performance and emission characteristics of stationary CI engine with cardnol bio fuel blends, International Journal of Scientific & Engineering Research, 2, 4, (2011) 104
  4. Jian Qi, Tianbo Zhao, Fengyan Li, Guida Sun, Xin Xu, Ce Miao, Haiwang Wang, Xiaoman Zhang, Study of cracking of large molecules over a new type meso-ZSM-5 composite zeolite, Journal of Porous Materials, 17, 2, (2010) 177-184 http://dx.doi.org/10.1007/s10934-009-9278-3
  5. Bruce C Gates, James R Katzer, George CA Schuit, Chemistry of catalytic processes, McGraw-Hill New York, 1979
  6. Pullur Anil Kumar, Maddigapu Pratap Reddy, Bae Hyun-Sook, Ha Heon Phil, Influence of Mg addition on the catalytic activity of alumina supported Ag for C3H6-SCR of NO, Catalysis letters, 131, 1-2, (2009) 85-97 http://dx.doi.org/10.1007/s10562-009-9895-0
  7. Zhenping Qua, Mojie Cheng, Chuan Shi, Xinhe Bao, Influence of pretreatment on the interaction of oxygen with silver and the catalytic activity of Ag/SiO2 catalysts for CO selective oxidation in H2, Journal of Natural Gas Chemistry, 14, 1, (2005) 4-12
  8. Harim Jeong, Misook Kang, Hydrogen production from butane steam reforming over Ni/Ag loaded MgAl 2 O 4 catalyst, Applied Catalysis B: Environmental, 95, 3, (2010) 446-455 http://dx.doi.org/10.1016/j.apcatb.2010.01.026

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