Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor

Muhamad Abduh Hasibuan; Didik Setiyo Widodo; Retno Ariadi Lusiana

doi:10.14710/jksa.21.2.59-63

DOI: https://doi.org/10.14710/jksa.21.2.59-63

Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor

Muhamad Abduh Hasibuan , Didik Setiyo Widodo

, Retno Ariadi Lusiana

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

Received: 22 Apr 2018; Published: 30 Apr 2018.

BibTex Citation Data :

@article{JKSA18635,
    author = {Muhamad Hasibuan and Didik Widodo and Retno Lusiana},
    title = {Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {21},
    number = {2},
    year = {2018},
    keywords = {Remazol black B; modified Fenton method; PbO2; decolorization; scaled up sample size; COD},
    abstract = { Study on decolourization of remazol black B (RBB) solution has been performed in a scale up reactor. As an artificial waste, the dye sample that contains azo groups is difficult to decompose under ordinary environmental conditions so it requires further treatment before discharging to open aquatic system. Many efforts have been reported and further developed toward other azo dyes. One of an outstanding approach is Fenton method. This study modified the method with PbO 2  rather than Fe 2+ . In this modification, the dyestuff was degraded by radical  • OH resulting from reaction between H 2 O 2  and Pb 2+  ion generated from PbO 2 . In Preliminary works, decolourization was performed and optimized in lab-scaled. Analysis were conducted and the best condition was applied to decolorize the sample in a scale-up size. Characteristics of the reactor was also determined. Results showed that at optimum condition, 100 mL of 50 ppm remazol black B was decolorized up to 98.82 % within 15 minutes. On scale up to 1 L-sized reactor, within the time highest percentages of remazol black B decolourization was reached 82.02 % by addition of 10 % H 2 O 2  and COD decrease to 98.96 %. In the 1 L reactor, RBB sample with concentration of 50 ppm, PbO 2  1 gram and H 2 O 2  10 % obey the proposed decolourization equation of D = -0,0011x 2  + 0.5705x – 0.6788 with x = volume peroxide (in mL), D = percent of decolourization. },
   issn = {2597-9914},   pages = {59--63}  doi = {10.14710/jksa.21.2.59-63},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/18635}
}

Citation Format:

Abstract

Study on decolourization of remazol black B (RBB) solution has been performed in a scale up reactor. As an artificial waste, the dye sample that contains azo groups is difficult to decompose under ordinary environmental conditions so it requires further treatment before discharging to open aquatic system. Many efforts have been reported and further developed toward other azo dyes. One of an outstanding approach is Fenton method. This study modified the method with PbO₂rather than Fe²⁺. In this modification, the dyestuff was degraded by radical ^•OH resulting from reaction between H₂O₂ and Pb²⁺ ion generated from PbO₂. In Preliminary works, decolourization was performed and optimized in lab-scaled. Analysis were conducted and the best condition was applied to decolorize the sample in a scale-up size. Characteristics of the reactor was also determined. Results showed that at optimum condition, 100 mL of 50 ppm remazol black B was decolorized up to 98.82 % within 15 minutes. On scale up to 1 L-sized reactor, within the time highest percentages of remazol black B decolourization was reached 82.02 % by addition of 10 % H₂O₂ and COD decrease to 98.96 %. In the 1 L reactor, RBB sample with concentration of 50 ppm, PbO₂ 1 gram and H₂O₂ 10 % obey the proposed decolourization equation of D = -0,0011x² + 0.5705x – 0.6788 with x = volume peroxide (in mL), D = percent of decolourization.

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Keywords: Remazol black B; modified Fenton method; PbO2; decolorization; scaled up sample size; COD

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Section: Research Articles

Language : EN

In Vol 21, No 2 (2018): Volume 21 Issue 2 Year 2018

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Last update: 2024-12-24 03:26:03

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