skip to main content

Conversion of Wood Waste to be a Source of Alternative Liquid Fuel Using Low Temperature Pyrolysis Method

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Indonesia

Received: 25 Sep 2018; Revised: 16 Jan 2019; Accepted: 23 Jan 2019; Published: 31 Jan 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

Conversion of wood waste into bio-oil with low temperature pyrolysis method has been successfully carried out using tubular transport reactors. Pyrolysis carried out at temperatures of 250-300°C without using N2 gas. Bio-oil purified by a fractionation distillation method to remove water and light fraction compounds. The materials obtained from different types of wood waste, namely: Randu wood (Ceiba pentandra), Sengon wood (Paraserianthes falcataria), Coconut wood (Cocos nucifera), Bangkirei wood (Shorea laevis Ridl), Kruing wood (Dipterocarpus) and Meranti wood (Shorea leprosula). Bio-oil products are analyzed for their properties and characteristics, namely the nature of density, acidity, high heat value (HHV), and elements contained in bio-oil such as carbon, nitrogen and sulfur content based on SNI procedures, while bio-oil chemical compositions are investigated using Gas Chromatography Mass Spectroscopy (GC-MS). The maximum yield of bio-oil products occurs at 300°C by 40%. Bio-oil purification by fractional distillation method can produce purity of 16-31% wt. The characterization results of the chemical content of bio-oil showed that bio-oil of methyl formate, 2,6-dimetoxy phenol, 1,2,3 trimethoxy benzene, levoglucosan, 2,4-hexadienedioic acid and 1,2- benzenediol.

Fulltext View|Download
Keywords: Wood waste; pyrolysis; bio-oil; characterization
Funding: The Directorate General of Higher Education, Indonesia under the 2018 Research Grant Research Institute (Contract No: 474 / UN27.21 / PP / 2018)

Article Metrics:

  1. Aryadi Suwono, Indonesia's Potential Contribution of Biomass in Sustainable Energy Development, Asian Pacific Confederation of Chemical Engineering congress program and abstracts, Japan, (2004)
  2. Sevgi Şensöz, Slow pyrolysis of wood barks from Pinus brutia Ten. and product compositions, Bioresource Technology, 89, 3, (2003) 307-311 https://doi.org/10.1016/S0960-8524(03)00059-2
  3. O. K. Mahadwad, D. D. Wagh and P. L. Kokil, Formation, analysis and characterization of wood pyrolyzed oil, IOP Conference Series: Materials Science and Engineering, 206, (2017) 012012 http://doi.org/10.1088/1757-899x/206/1/012012
  4. Q. M. K. Waheed, M. A. Nahil and P. T. Williams, Pyrolysis of waste biomass: investigation of fast pyrolysis and slow pyrolysis process conditions on product yield and gas composition AU - Waheed, Q M K, Journal of the Energy Institute, 86, 4, (2013) 233-241 http://doi.org/10.1179/1743967113Z.00000000067
  5. Mohammad Amir Firdaus Mazlan, Yoshimitsu Uemura, Noridah B. Osman and Suzana Yusup, Fast pyrolysis of hardwood residues using a fixed bed drop-type pyrolyzer, Energy Conversion and Management, 98, (2015) 208-214 https://doi.org/10.1016/j.enconman.2015.03.102
  6. Y. L. Tan, A. Z. Abdullah and B. H. Hameed, Fast pyrolysis of durian (Durio zibethinus L) shell in a drop-type fixed bed reactor: Pyrolysis behavior and product analyses, Bioresource Technology, 243, (2017) 85-92 https://doi.org/10.1016/j.biortech.2017.06.015
  7. George W. Huber, Sara Iborra and Avelino Corma, Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering, Chemical Reviews, 106, 9, (2006) 4044-4098 http://doi.org/10.1021/cr068360d
  8. Sait Yorgun and Derya Yıldız, Slow pyrolysis of paulownia wood: Effects of pyrolysis parameters on product yields and bio-oil characterization, Journal of Analytical and Applied Pyrolysis, 114, (2015) 68-78 https://doi.org/10.1016/j.jaap.2015.05.003
  9. Laidy E Hernandez-Mena, Arai AB Pécoraa and Antonio L Beraldob, Slow pyrolysis of bamboo biomass: Analysis of biochar properties, Chemical Engineering Transactions, 37, (2014) 115-120 http://doi.org/10.3303/CET1437020
  10. Dinesh Mohan, Charles U. Pittman and Philip H. Steele, Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review, Energy & Fuels, 20, 3, (2006) 848-889 10.1021/ef0502397
  11. Edmund C Okoroigwe, Zhenglong Li, Shantanu Kelkar, Christopher Saffron and Samuel Onyegegbu, Bio-oil yield potential of some tropical woody biomass, Journal of Energy in Southern Africa, 26, 2, (2015) 33-41
  12. Peter McKendry, Energy production from biomass (part 1): overview of biomass, Bioresource Technology, 83, 1, (2002) 37-46 https://doi.org/10.1016/S0960-8524(01)00118-3
  13. P. M. Mortensen, J. D. Grunwaldt, P. A. Jensen, K. G. Knudsen and A. D. Jensen, A review of catalytic upgrading of bio-oil to engine fuels, Applied Catalysis A: General, 407, 1, (2011) 1-19 https://doi.org/10.1016/j.apcata.2011.08.046

Last update:

  1. Fast pyrolysis of Dipterocarpus alatus Roxb and rubber wood in a free-fall reactor

    Koson Rueangsan, Somsuk Trisupakitti, Watchara Senajuk, John Morris. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 44 (1), 2022. doi: 10.1080/15567036.2019.1649760
  2. Fast pyrolysis ofDipterocarpus alatus Roxband rubber wood in a free-fall reactor

    Koson Rueangsan, Somsuk Trisupakitti, Watchara Senajuk, John Morris. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 44 (1), 2022. doi: 10.1080/15567036.2019.1649760
  3. Fast pyrolysis of Dipterocarpus alatus Roxb and rubber wood in a free-fall reactor

    Koson Rueangsan, Somsuk Trisupakitti, Watchara Senajuk, John Morris. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 44 (1), 2022. doi: 10.1080/15567036.2019.1649760

Last update: 2024-11-03 12:27:53

  1. Fast pyrolysis of Dipterocarpus alatus Roxb and rubber wood in a free-fall reactor

    Koson Rueangsan, Somsuk Trisupakitti, Watchara Senajuk, John Morris. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 44 (1), 2022. doi: 10.1080/15567036.2019.1649760